欢迎登录材料期刊网

材料期刊网

高级检索

The molecular interaction volume model (MIVM) for a general ternary system was deduced in detail for further clarifying and understanding its general multicomponent expression. Both MIVM and the unified interaction parameterformalism (UIPF) can be used to predict the activities of solutes and solvents in the Fe-Cr-Ni liquid alloys. But the former employs only the infinite dilute activity coefficients, and the later is not applicable without the dilute binary and ternary interaction parameters. MIVM has a certain physical meaning from the viewpoint of statistical thermodynamics, so it is an alternative for the estimation of activity coefficients of the solutes and solvents in a dilute or finite concentration metal solution where the interaction parameters are absent or their accuracies are questionable.

参考文献

[1] C Wagner.Thermodynamics of Alloys[M].Addison-Wesley,Reading,MA,1952:51.
[2] C H P Lupis.Chemical Thermodynamics of Materials[M].Elsevier Science Publishing Co.Inc.,Amsterdam,1983:524.
[3] Steelmaking Data Sourcebook,Japanese Society for the Promotion of Science[A].Gordon Breach Science Publishers,Switzerland,1988:273.
[4] S Srikanth;K T Jacob .[J].Metallurgical and Materials Transactions B:Process Metallurgy and Materials Processing Science,1988,19B:269.
[5] A D Pelton;C W Bale .[J].Metallurgical and Materials Transactions A:Physical Metallurgy and Materials Science,1986,17:1211.
[6] C W Bale;A D Pelton .[J].Metallurgical and Materials Transactions A:Physical Metallurgy and Materials Science,1990,21:1997.
[7] D P Tao .[J].Thermochimica Acta,2000,363:105.
[8] D P Tao .[J].Metallurgical and Materials Transactions B:Process Metallurgy and Materials Processing Science,2001,32:1205.
[9] J M Prausnitz;R N Lichtenthaler;E G D Azevedo.Molecular Thermodynamics of Fluid-Phase Equilibria[M].Prentice-Hall Inc,Englewood Cliffs,NJ,1986:328,308.
[10] R Schuhmann .[J].Metallurgical and Materials Transactions B:Process Metallurgy and Materials Processing Science,1985,16:807.
[11] M Z Sukiennik;R W Olesinski .[J].Metallurgical and Materials Transactions B:Process Metallurgy and Materials Processing Science,1984,15:677.
[12] S W Gilby;G R St Pierre .[J].TMS-AIME,1969,245:1749.
[13] T Iida;R I L Guthrie.The Physical Properties of Liquid Metals[M].Clarendon Press,Oxford,1988:19.
[14] R C Evans.An Introduction to Crystal Chemistry[M].London:Cambridge University Press,1976:87.
[15] J Hinze;H H Jaffe .[J].Journal of the American Chemical Society,1962,84:540.
[16] S M Walas.Phase Equilibira in Chemical Engineering[M].Butterworth Publishers,Boston,1985:209.
[17] A D Pelton;N Sano;W K Lu;P.V.Riboud.Advanced Physical Chemistry for Process Metallurgy[M].Academic Press,San Diego,1997:87.
[18] J P Hajra .[J].Metallurgical and Materials Transactions B:Process Metallurgy and Materials Processing Science,1991,22:583.
[19] P J Flory.[J].Journal of Chemical Physics,1941(09):660.
[20] M L Huggins.[J].Journal of Physical Chemistry,1941(09):440.
[21] D P Tao;D F Li;B Yang.[J].Thermochimica Acta,2002(383):45.
[22] D P Tao;B Yang;D F Li .[J].Fluid Phase Equilibria,2002,193:167.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%