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以玉米淀粉(NCS)为原料,乙酸乙烯酯(VAc)为酰化剂,K2CO3为催化剂,用微波辅助法制备乙酰化玉米淀粉(ACS),用红外光谱(FT-IR)、扫描电镜(SEM)和X-射线衍射(XRD)等手段对其表征,研究了ACS的理化特性,粘附性能和生物降解性.结果表明,ACS的理化性能比NCS有较大的改善:其水合能力增强,溶胀性与糊透明度提高;特性黏度和表观粘度下降,流变性能有所改善;凝沉作用减弱,抗老化性增强.ACS对涤棉纤维的粘附性提高,克服了原淀粉对疏水性合成纤维粘附力不足的缺陷.ACS的BOD5/CODCr比值远高于PVA-205.

参考文献

[1] J.R.Huang,H.A.Schols,Z.Y.Jin,E.Sulmann,A.G.J.Voragen,Characterization of differently sized granule fractions of yellow pea,cowpea and chickpea starches after modification with acetic anhydride and vinyl acetate,Carbohyd.Polym.,76(1),11 (2007)
[2] R.L.Shogren,A.Biswas,Facile Route to Anionic Starches—Acet-ylation of starch with vinyl acetate in imidazolium ionic liquids and characterization of acetate distribution,Carbohyd.Polym.,81(1),149(2010)
[3] Y.J.Wang,L.F.Wang,Characterization of acetylated waxy maize starches prepared under catalysis by different alkali and alkaline-earth hydroxides,Starch-St~irke,54(1),25(2002)
[4] P.D.Mbougueng,D.V.Tenin,J.Scher,C.Tchiegang,Influence of acetylation on physicochemical,functional and thermal properties of potato and cassava starches,J.Food Eng.,108(2),320(2012)
[5] H.A.M.Wickramasinghe,K.Yamamoto,H.Yamauchi,T.Noda,Effect of low level of starch acetylation on physicochemical proper-ties of potato starch,Food Sci.Biotechnol.,18(2),118(2009)
[6] X.Li,W.Y.Gao,Q.Q.Jiang,L.Q.Huang,C.X.Liu,Study on the morphology,crystalline structure,and thermal properties of Fritil-laria ussuriensis Maxim— Starch acetates with different degrees of substitution,Starch-Stirke,63(1),24(2011)
[7] B.Daramola,G.O.Adegoke,Influence of acetylation on physico-chemical,functional and thermal properties of potato and cassava starches,J.Food Agric.Environ.,5(2),50(2007)
[8] C.Fringant,M.Rinaudo,N.Gontard,S.Guilbert,H.Derradji,A biogradable starch based coating to waterproof hydrophilic materi-als,Starch-St(a)rke,50(7),292(1998)
[9] J.Juhanoja,H.Fagerholm,S.Hyvarinen,S.Peltonen,K.Kataja,H.Lampinen,P.Fardim,ToF-SIMS characterization of modified starch on fine and LWC base papers,Nord.Pulp.Pap.Res.J.,22(1),131(2007)
[10] A.V.Singh,L.K.Nath,Evaluation of acetylated moth bean starch as a carrier for controlled drug delivery,Int.J.Biol.Macromol.,50(2),362(2012)
[11] K.P.R.Chowdary,G.V.Radha,Synthesis,characterization and evaluation of starch acetate as microencapsulating agent for con-trolled release of glipizide,Int.J.Biol.Macromol.,23(5),1914(2011)
[12] J.Chen,Q.Wang,Z.Z.Hua,G.C.Du,Research and application of biotechnology in textile industries in China,Enzyme.Microb.Technol.,40(7),1651(2007)
[13] A.V.Singh,L.K.Nath,M.Guha,Microwave assisted synthesis and characterization of Sago starch-g-acrylamide,Starch-St(a)rke,63(11),740(2011)
[14] V.Singh,A.Tiwari,S.Pandey,S.K.Singh,Microwave-accelerated synthesis and characterization of potato starch-g-poly(acrylamide),Starch-St(a)rke,58(10),536(2006)
[15] M.Bushra,X.Y.Xu,X.Y.Pan,Z.Zhang,G.C.Du,Microwave assisted acetylation of mung bean starch and the catalytic activity of potassium carbonate in free-solvent reaction,Starch-St(a)rke,65(3-4),236(2013)
[16] V.D.Athawale,V.Lele,Microwave assisted acetylation of mung bean starch and the catalytic activity of potassium carbonate in free-solvent reaction,Starch-St(a)rke,52(6-7),205(2000)
[17] A.Biswas,R.L.Shogren,G.Selling,J.Salch,J.J.Willett,C.M.Buchanan,Rapid and environmentally friendly preparation of starch esters,Carbohyd.Polym.,74(1),137(2008)
[18] N.Singh,J.Singh,L.Kaur,N.S.Sodhi,B.S.Gill,Morphological,thermal and rheological properties of starches from different botanical sources,Food Chem.,81(2),219(2003)
[19] O.V.López,N.E.Zaritzky,M.A.García,Physicochemical characterization of chemically modified corn starches related to rheological behavior,retrogradation and film forming capacity,J.Food Eng.,100(1),160(2010)
[20] S.Saartrat,C.Puttanlek,V.Rungsardthong,Paste and gel properties of low-substituted acetylated canna starches,Carbohyd.Polym.,61(2),211(2005)
[21] H.Chi,K.Xu,X.L.Wu,Q.Chen,D.H.Xue,C.L.Song,W.D.Zhang,P.X.Wang,Effect of acetylation on the properties of corn starch,Food Chem.,106(3),923(2008)
[22] C.I.K.Diop,L.I.Hailong,B.J.Xie,J.Shi,Effects of acetic acid/acetic anhydride ratios on the properties of corn starch acetates,Food Chem.,126(4),1662(2011)
[23] G.Lewandowicz,T.Jankowski,J.Fomal,Effect of microwave radiation on physico-chemical properties and structure of cereal starches,Carbohyd.Polym.,42(2),193(2000)
[24] N.S.Sodhi,N.Singh,Characteristics of acetylated starches pre-pared using starches separated from different rice cultivars,J.Food Eng.,70(1),117(2005)
[25] J.Singh,L.Kaur,N.Singh,Effect of acetylation on some proper-ties of corn and potato starches,Starch-St(a)rke,56(12),586(2004)
[26] N.Singh,D.Chawla,J.Singh,Influence of acetic anhydride on physicochemical,morphological and thermal properties of corn and potato starch,Food Chem.,86(4),601 (2004)
[27] F.Han,M.Z.Liu,H.H.Gong,S.Y.Lv,B.L.Ni,B.Zhang,Synthesis,characterization and functional properties of low substituted acetylated corn starch,Int.J.Biol.Macromol.,50(4),1026(2012)
[28] Z.F.Zhu,M.L.Li,E.Q.Jin,Effect of an allyl pretreatment of starch on the grafting efficiency and properties of allyl starch-g-poly(aerylic acid),J.Appl.Polym.Sci.,112(5),2822(2009)
[29] WANG Jiankun,HAN Dawei,LV Hairong,Graft modification of starch by rheological phase method based on damping characteristic,Chinese Journal of Materials Research,24(4),348(2010)(王建坤,韩大伟,吕海荣,基于阻尼特性的淀粉流变相接枝改性,材料研究学报,24(4),348(2010)
[30] N.Teramoto,T.Motoyama,R.Yosomiya,M.Shibata,Synthesis,thermal properties,and biodegradability of propyl-etherified starch,Eur.Polym.J.,39(2),255(2003)
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