在HAuCl4-葡萄糖-丙酮体系中,丙酮不仅能起光敏剂、加速光化学还原Au(III)离子的反应,还能诱导已形成的金纳米粒子整形。整形过程伴随着明显的可见/近红外吸收光谱变化,并形成一些全新的纳米结构。实验结果表明,金纳米粒子的整形方式与初始金纳米粒子的形貌密切相关,对于球形的金纳米粒子,整形后形成纳米线;而对于锥形纳米粒子则形成金纳米片。
Acetone as a photosensitizer could not only accelerate the photochemical reduction reaction of Au(III), but also induce the reshaping of gold nanoparticles formed in HAuCl4-glucose-acetone solution system. The whole reshaping process was accompanied by the obvious Vis/NIR spectral changes of gold nanopartilces, finally, some new nanostructures were formed. The experimental results showed that the reshaping pattern was closely related to the original morphology of gold nanoparticles. Spherical gold nanoparticles were reshaped to gold nanolines, while gold nano-pyramids to nanodisk.
参考文献
[1] | Peng, G;Tisch, U;Adams, O;Hakim, M;Shehada, N;Broza, YY;Billan, S;Abdah-Bortnyak, R;Kuten, A;Haick, H .Diagnosing lung cancer in exhaled breath using gold nanoparticles[J].Nature nanotechnology,2009(10):669-673. |
[2] | Kim, B.;Han, G.;Toley, B.J.;Kim, C.-K.;Rotello, V.M.;Forbes, N.S. .Tuning payload delivery in tumour cylindroids using gold nanoparticles[J].Nature nanotechnology,2010(6):465-472. |
[3] | El-Sayed I H;Huang X;El-Sayed M A .Selective laser photo-thermal therapy of epithelial carcinoma using anti-EGFR antibody conjugated gold nanoparticles[J].Cancer letters,2006,239:129-135. |
[4] | Huang X;Jain P K;El-Sayed I H et al.Gold nano- particles:interesting optical properties and recent applications in cancer diagnostics and therapy[J].Nanomedicine,2007,2(05):681-693. |
[5] | Huang X;Jain PK;El-Sayed IH;El-Sayed MA .Plasmonic photothermal therapy (PPTT) using gold nanoparticles.[J].Lasers in medical science,2008(3):217-228. |
[6] | Ayyappan S;Srinivasa Gopalan R;Subbanna G N et al.Nanoparticles of Ag,Au,Pd and Cu produced by alcohol reduction of the salts[J].Journal of Materials Research,1997,12(02):398-401. |
[7] | Pastoriza-Santos I.;Liz-Marzan LM. .Formation of PVP-protected metal nanoparticles in DMF[J].Langmuir: The ACS Journal of Surfaces and Colloids,2002(7):2888-2894. |
[8] | Esumi K.;Yamahira A.;Torigoe K.;Suzuki A. .Role of poly(amidoamine) dendrimers for preparing nanoparticles of gold, platinum, and silver[J].Langmuir: The ACS Journal of Surfaces and Colloids,2000(6):2604-2608. |
[9] | Robert G.Shimmin;Andrew B.Schoch;Paul V.Braun .Polymer Size and Concentration Effects on the Size of Gold Nanoparticles Capped by Polymeric Thiols[J].Langmuir: The ACS Journal of Surfaces and Colloids,2004(13):5613-5620. |
[10] | Jae Yong Song;Hyeon-Kyeong Jang;Beom Soo Kim .Biological synthesis of gold nanoparticles using Magnolia kobus and Diopyros kaki leaf extracts[J].Process Bio- chemistry,2009,44(10):1133-1138. |
[11] | K. Badri Narayanan;N. Sakthivel .Coriander leaf mediated biosynthesis of gold nanoparticles[J].Materials Letters,2008(30):4588-4590. |
[12] | Kasthuri J;Veerapandian S;Rajendiran N .Biological synthesis of silver and gold nanoparticles using apiin as reducing agent[J].Colloids and Surfaces, B. Biointerfaces,2009(1):55-60. |
[13] | Ratul Kumar Das .Green synthesis of gold nanoparticles using ethanolic leaf extract of Centella asiatica[J].Materials Letters,2010(13):1445. |
[14] | Xiaohua Huang;Ivan H.El-Sayed;Wei Qian;Mostafa A.El-Sayed .Cancer Cell Imaging and Photothermal Therapy in the Near-Infrared Region by Using Gold Nanorods[J].Journal of the American Chemical Society,2006(6):2115-2120. |
[15] | Dickerson EB;Dreaden EC;Huang X;El-Sayed IH;Chu H;Pushpanketh S;McDonald JF;El-Sayed MA .Gold nanorod assisted near-infrared plasmonic photothermal therapy (PPTT) of squamous cell carcinoma in mice.[J].Cancer letters,2008(1):57-66. |
[16] | Hironobu Takahashi;Yasuro Niidome;Sunao Yamada .Controlled release of plasmid DNA from gold nanorods induced by pulsed near-infrared light[J].Chemical communications,2005(17):2247-2249. |
[17] | Chen CC;Lin YP;Wang CW;Tzeng HC;Wu CH;Chen YC;Chen CP;Chen LC;Wu YC .DNA-gold nanorod conjugates for remote control of localized gene expression by near infrared irradiation[J].Journal of the American Chemical Society,2006(11):3709-3715. |
[18] | 杨辅龙,董守安,王晓娜,方卫,戴云生.葡萄糖溶液中金纳米粒子的光化学合成及其光谱性质研究[J].贵金属,2012(02):10-14. |
[19] | Nikolaides MG;Bausch AR;Hsu MF;Dinsmore AD;Brenner MP;Weitz DA .Electric-field-induced capillary attraction between like-charged particles at liquid interfaces[J].Nature,2002(6913):299-301. |
[20] | Wang Minhua;Li Yongjun;Xie Zhaoxiong et al.Fabrication of large-scale one-dimensional Au nanochain and nanowire networks by interfacial self-assembly[J].Materials Chemistry and Physics,2010,119:153-157. |
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