以易于纺丝的聚乙烯醇(PVA)为纤维基材,添加3-环氧丙基-5,5-二甲基海因改性壳聚糖(CTS-GH),利用静电纺丝法制备出具有高效抗茵效果的纳米纤维.采用扫描电镜、红外光谱、热重分析仪表征和分析了纳米纤维的结构和热性能,考察了纺丝液流量对纳米纤维结构和氯含量的影响.结果表明,纳米纤维的直径随着纺丝速度的加快而减小.利用碘量法测定了纳米纤维的氯含量,说明该纳米纤维经过氯化处理后具有很好的抗茵效果.该纳米纤维可用于抗茵过滤材料、生物医药等方面.
参考文献
[1] | Schiffman JD;Schauer CL .A review: Electrospinning of biopolymer nanofibers and their applications[J].Polymer reviews,2008(2):317-352. |
[2] | Lim S H;Hudson S M .Review of chitosan and its derivatives as antimicrobial agents and their uses as textile chemicals[J].Journal of Macromolecular Science Part C:Polymer Reviews,2003,CA3(02):223. |
[3] | 李明春,许涛,辛梅华.壳聚糖及其衍生物的抗菌活性研究进展[J].化工进展,2011(01):203-209. |
[4] | Alipour, SM;Nouri, M;Mokhtari, J;Bahrami, SH .Electrospinning of poly(vinyl alcohol)-water-soluble quaternized chitosan derivative blend[J].Carbohydrate research,2009(18):2496-2501. |
[5] | Cao Z;Sun Y .N-halamine-based chitosan: preparation, characterization, and antimicrobial function.[J].Journal of biomedical materials research, Part A,2008(1):99-107. |
[6] | Xuehong Ren;Changyun Zhu;Lei Kou .Acyclic N-Halamine Polymeric Biocidal Films[J].Journal of Bioactive and Compatible Polymers,2010(4):392-405. |
[7] | S D Worley;Y Chen;J-W Wang;R Wu;U Cho .Novel N-halamine siloxane monomers and polymers for preparing biocidal coatings[J].Surface Coatings International, Part B. Coatings Transactions: The Science and Technology of Paints, Inks and Related Coatings and their Raw Materials,2005(2):93-99. |
[8] | Yang, X.;Liu, L.;Yang, W. .Direct preparation of monodisperse core-shell microspheres with surface antibacterial property by using bicationic viologen surfmer[J].Polymer: The International Journal for the Science and Technology of Polymers,2012(11):2190-2196. |
[9] | Zhao, N.;Zhanel, G.G.;Liu, S. .Regenerability of antibacterial activity of interpenetrating polymeric N-halamine and poly(ethylene terephthalate)[J].Journal of Applied Polymer Science,2011(1):611-622. |
[10] | Rong Li;Pei Hu;Xuehong Ren .Antimicrobial N-halamine modified chitosan films[J].Carbohydrate Polymers: Scientific and Technological Aspects of Industrially Important Polysaccharides,2013(1):534-539. |
[11] | Jia Y T;Gong J;Gu X H et al.Fabrication and characterization of poly (vinyl alcohol)/chitosan blend nanofibers produced by electrospinning method[J].Carbohydrate Polymers,2007,67(03):403. |
[12] | 夏艳杰,邱芯薇,潘志娟,陈立英.静电纺壳聚糖/PVA共混纤维的微细结构[J].南通大学学报(自然科学版),2006(01):34-37,42. |
[13] | Ren XH;Kou L;Kocer HB;Zhu CY;Worley SD;Broughton RM;Huang TS .Antimicrobial coating of an N-halamine biocidal monomer on cotton fibers via admicellar polymerization[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2008(1/3):711-716. |
[14] | Gang Sun;Xiangjing Xu;Julie R. Bickett;Jeffrey F. Williams .Durable and Regenerable Antibacterial Finishing of Fabrics with a New Hydantoin Derivative[J].Industrial & Engineering Chemistry Research,2001(4):1016-1021. |
[15] | Xuehong Ren;Hasan B. Kocer;S.D. Worley .Rechargeable biocidal cellulose: Synthesis and application of 3-(2,3-dihydroxypropyl)-5,5-dimethylimidazolidine-2,4-dione[J].Carbohydrate Polymers: Scientific and Technological Aspects of Industrially Important Polysaccharides,2009(4):683-687. |
[16] | Kumar, S.;Koh, J.;Kim, H.;Gupta, M.K.;Dutta, P.K. .A new chitosan-thymine conjugate: Synthesis, characterization and biological activity[J].International Journal of Biological Macromolecules: Structure, Function and Interactions,2012(3):493-502. |
[17] | Adelaida Avila;Karina Bierbrauer;Graciela Pucci;Mar Lopez-Gonzalez;Miriam Strumia .Study of optimization of the synthesis and properties of biocomposite films based on grafted chitosan[J].Journal of food engineering,2012(4):752-761. |
[18] | Lewandowska, Katarzyna .Miscibility and thermal stability of poly(vinyl alcohol)/chitosan mixtures[J].Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems,2009(1/2):42-48. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%