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利用放电等离子SPS烧结工艺制备得到Zn、Pr共掺的In2O3多晶陶瓷材料。通过研究材料的热电传输性能和微观结构,发现共掺工艺对SPS烧结的In2O3陶瓷材料的传输性能有着显著的影响,其结构为多孔结构。低浓度共掺的样品在测试温度范围内能够得到较高的电导率(约100S/m)和热电势(约200μV/K)。其中试样In1.92(Pr,Zn)0.08O3的热导率973K最低为2.5W/(m.K),该样品可获得最高的热电功率因子3.5×10-4 W/(m.K2),对应其热电优值0.10。其性能表明利用放电等离子SPS烧结工艺制备的In2O3基陶瓷作为n型高温热电材料具有很好的潜力。

The polycrystalline In2O3 ceramics co-doped with Zn,Pr were prepared through the spark plasma sintering process.Both thermoelectric transport properties and microstructure of the ceramics were investigated.The co-doped In2O3 by SPS had a remarkable effect on the transport properties.Large electrical conductivity(about100S/m) and thermopower(about 200μV/K) was observed in dilute Co doped sample.The maximum power factor was found in In1.92(Pr,Zn)0.08O3 sample as 3.5 ×10-4 W/(m·K2) at 973 K with the ZT value up to 0.10.It reveals that In2O3 polycrystalline ceramics prepared by a spark plasma sintering thus can be a good candidate for n-type thermoelectric materials.

参考文献

[1] 高敏;张景韶;RoweDM.温差电转换及其应用[M].北京:兵器工业出版社,1996
[2] Rowe D M.CRC Handbook of Thermoelectrics[M].Boca Raton:crc Press,1995
[3] Tani T.;Itahara H.;Xia CT.;Sugiyama J. .Topotactic synthesis of highly-textured thermoelectric cobaltites[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2003(8):1865-1867.
[4] Ito M;Seo W S;Koumoto K .[J].Journal of Materials Research,1999,14:209.
[5] Walsh A;Da Silva J L F;Wei S H et al.[J].Physical Review Letters,2008,100(16):167402.
[6] Marezio M .[J].Acta Crystallographica,1966,20:723.
[7] Chopra K L;Major S;Pandia D K .[J].Thin Solid Films,1983,102:1.
[8] Hamberg I;Granqvist C G;Berggren K F et al.[J].Physical Review B:Condensed Matter,1984,30:3240.
[9] Shigesato Y;Takaki S;Haranoh T .[J].Journal of Applied Physics,1992,71:3356.
[10] Sreenivas K;Rao T S;Mansingh A .[J].Journal of Applied Physics,1985,57:384.
[11] Tamaki J.;Naruo C.;Yamamoto Y.;Matsuoka M. .Sensing properties to dilute chlorine gas of indium oxide based thin film sensors prepared by electron beam evaporation[J].Sensors and Actuators, B. Chemical,2002(1/3):190-194.
[12] Berardan D;Guilmeau E;Maignan A;Raveau B .In2O3 : Ge, a promising n-type thermoelectric oxide composite[J].Solid State Communications,2008(1/2):97-101.
[13] Guilmeau E;Berardan D;Simon Ch et al.[J].Journal of Applied Physics,2009,106:053715.
[14] Liu Y;Lin Y H;Zhang B P et al.[J].Journal of the American Ceramic Society,2009,92:934.
[15] Hugria T;Galy J;Castro A .[J].Advances in Engineering Materials,2009,11:615.
[16] LiuY;Lin Y H;Zhang B P et al.[J].Journal of the American Ceramic Society,2009,92:934.
[17] Hugria T;Galy J;Castro A .[J].Advances in Engineering Materials,2009,11:615.
[18] Gong W;Yun H;Ning Y B et al.[J].Journal of Solid State Chemistry,1991,90:320.
[19] Webman I;Jortner J;Morrel H C .[J].Physical Review B:Condensed Matter,1977,16:2559.
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