首次合成了(脯氨酸-N-甲基膦酸-磷酸氢)锆(α-ZPMPP)层状晶体,以正丁胺为客体分子首次合成了α-ZPMPP-正丁胺超分子插层复合物.研究了α-ZPMPP在常温下对正丁胺的插层性能,用元素分析、红外光谱、X射线衍射、TG-DSC热分析对α-ZPMPP及其插层复合物进行了表征.研究表明,正丁胺的插入使层间距增大从1.52nm增加到1.97nm,插入的正丁胺在150~250℃可被脱除,正丁胺客体分子在主体底物中形成单分子层.
参考文献
[1] | Colon Jorge L;Yang Chao-Yeuh;clearfield Abraham et al.[J].Journal of Physical Chemistry,1990,94:874-882. |
[2] | Gary B Hix;Simon J Kitchin;Kenneth D M Harris.[J].Journal of the Chemical Society Dalton Transactions,1998:2315-2319. |
[3] | Tsuyoshi Kijima;Seiichi Ueno;Masaru Goto.[J].Journal of the Chemical Society,Faraday Transactions,1982:2499-2503. |
[4] | Dugald J MacLachlan;Keith R Morgan .[J].Journal of Physical Chemistry,1992,96:3458-3464. |
[5] | Tsuyoshi Kijima;Katsuhiro Sakoh;Machida .[J].Journal of the Chemical Society Dalton Transactions,1996,1245-1248 |
[6] | Umberto Costantino.[J].Journal of the Chemical Society Dalton Transactions,1979:402-405. |
[7] | Naoki Mikami;Minoru Sasaki;Tatsuya Yasunaga et al.[J].Journal of Physical Chemistry,1984,88:3229-3233. |
[8] | 傅相锴;罗必奎;雷庆英 .[J].应用化学,1991,8(05):6. |
[9] | Kurt Moedritzer;Riyad R Irani.[J].Journal of Organic Chemistry,1966:1603-1607. |
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