在讨论无机纳米粒子团聚机理的基础上综述了纳米粒子表面修饰研究进展.表面修饰包括物理和化学修饰,重点综述了表面聚合物修饰最新研究进展.介绍了以化学键在纳米粒子表面接枝聚合物,其主要方法包括在无机纳米粒子表面引入可聚合碳-碳双键合成大分子单体、此大分子单体与相应乙烯基单体共聚在表面生成聚合物;将引发剂"固定"在纳米粒子表面合成大分子引发剂,以此引发剂引发单体聚合物生成表面接枝聚合物;反应型聚合物链与粒子表面活性基团反应将聚合物链接枝到纳米粒子表面.
参考文献
| [1] | C.Sanchez;G.J.de A.A.Soler-Illia;F.Ribot;T.Lalot;C.R.Mayer;V.Cabuil .Designed Hybrid Organic-Inorganic Nancomposites from Functional Nanobuilding Blocks[J].Chemistry of Materials,2001(10):3061-3083. |
| [2] | Gerhard Schottner .Hybrid Sol-Gel-Derived Polymers: Applications of Multifunctional Materials[J].Chemistry of Materials,2001(10):3422-3435. |
| [3] | Jeffrey Pyun;Krzysztof Matyjaszewski .Synthesis of Nanocomposite Organic/Inorganic Hybrid Materails Using Controlled/"Living" Radical Polymerization[J].Chemistry of Materials,2001(10):3436-3448. |
| [4] | 廖凯荣.轻质碳酸钙/聚丙烯共混物中聚丙烯β-晶的成核结晶研究[J].高等学校化学学报,1995(01):143. |
| [5] | Liang J Z .[J].Journal of Applied Polymer Science,2002,83(07):1547-1555. |
| [6] | 张玉德,刘钦甫,伍泽广,沈秀运,李和平.纳米高岭土和白炭黑硫化橡胶复合材料[J].湖南科技大学学报（自然科学版）,2006(02):73-76. |
| [7] | 王训遒,蒋登高.纳米CaCO3/丙烯酸树脂浆液的流变性[J].湖南科技大学学报（自然科学版）,2006(03):85-89. |
| [8] | 张立德;牟季美.纳米材料和纳米结构[M].北京:科学出版社,2001:140. |
| [9] | 罗忠富,黄锐.无机纳米粒子填充聚合物的研究进展[J].功能高分子学报,1998(04):555-560. |
| [10] | Somasundaran P;Krishnakumar S .[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,1997,123-124:491-513. |
| [11] | 李远,陈建国,陈腊琼,王正东.PP／纳米CaCO3分散体系的研究[J].塑料工业,2001(01):16-17,20. |
| [12] | 祖庸;王训;郭晓英 等.[J].涂料工业,1999,29(06):6-8. |
| [13] | 姚超,高国生,林西平,杨绪杰,陆路德,汪信.硅烷偶联剂对纳米二氧化钛表面改性的研究[J].无机材料学报,2006(02):315-321. |
| [14] | 林玉兰,王亭杰,覃操,金涌.钛酸酯偶联剂对包硅铝钛白粉表面的有机改性[J].物理化学学报,2001(02):169-172. |
| [15] | 徐存英,段云彪,张鹏翔,秦亚琴.纳米二氧化钛的表面改性研究[J].云南化工,2000(05):6-7. |
| [16] | Hashimoto K;Fujisawa T;Kobayashi M et al.[J].Journal of Applied Polymer Science,1982,27(12):4529-4539. |
| [17] | Espiard P.;Guyot A. .POLY(ETHYL ACRYLATE) LATEXES ENCAPSULATING NANOPARTICLES OF SILICA .2. GRAFTING PROCESS ONTO SILICA[J].Polymer: The International Journal for the Science and Technology of Polymers,1995(23):4391-4395. |
| [18] | Jethmalani J M;Ford W T .[J].Materials Today,1996,8(08):2138-2146. |
| [19] | Eastmond G C;Nguyen H C;Piret W H .[J].Polymer,1980,21(06):598-603. |
| [20] | Prucker O.;Ruhe J. .Synthesis of poly(styrene) monolayers attached to high surface area silica gels through self-assembled monolayers of azo initiators[J].Macromolecules,1998(3):592-601. |
| [21] | C.Perruchot;M.A.Khan;A.Kamitsi;S.P.Armes .Synthesis of Well-Defined, Polymer-Grafted Silica particles by Aqueous ATRP[J].Langmuir: The ACS Journal of Surfaces and Colloids,2001(15):4479-4481. |
| [22] | Timothy von Werne;Timothy E.Patten .Atom Transfer Radical Polymerization from Nanoparticles: A Tool for the Preparation of Well-Defined Hybrid Nanostructures and for Understanding the Chemistry of Controlled/"Living" Radical Polymerizations from Surfaces[J].Journal of the American Chemical Society,2001(31):7497-7505. |
| [23] | Bartholome C.;Beyou E.;Bourgeat-Lami E.;Chaumont P.;Zydowicz N. .Nitroxide-mediated polymerizations from silica nanoparticle surfaces: "Graft from" polymerization of styrene using a triethoxysilyl-terminated alkoxyamine initiator[J].Macromolecules,2003(21):7946-7952. |
| [24] | Schomaker E;Zwarteveen A J;Challa G et al.[J].Polymer,1988,29(06):158-160. |
| [25] | Michiel L C M O;Arjen S;Arend J S .[J].POLYMER,1992,33(20):4394-4400. |
| [26] | Barkalov I M;Kirukhin D P;Kichigina G A et al.[J].European Polymer Journal,1984,20(10):1013-1017. |
| [27] | Tsubokawa N;Hosoya M;Yanadori K et al.[J].Journal of Macromolecular Sciences Chemistry,1990,27(04):445-457. |
| [28] | Luzinov Igor;Julthongpiput Daungrut .Polystyrene Layers Grafted to Epoxy-Modified Silicon Surfaces[J].Macromolecules,2000(3):1043-1048. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%