本文分析了光催化反应器降解有机挥发化合物(VOCs)的特性,提出了反应器总降解常数的概念,提出了一种测量光催化反应器性能参数-传质单元数、反应有效度和总降解常数的方法.管状光催化反应器降解空气中微量甲醛的实验验证了该方法的可行性.实验表明:在空气温度22~24℃,空气湿度40%附近,甲醛的光催化反应在不同浓度区间近似为一次反应,在1.6~12.4 mg/m3浓度区间内其总降解常数最大.
参考文献
[1] | Molhave L .The Sick Buildings and Other Buildings with Indoor Climate Problems[J].环境,1989,15:65-74. |
[2] | Kadosaki M;Terasawa T;Tanino K et al.Exploration of Highly Sensitive Oxide Semiconductor Materials to Indoor-air Pollutants[J].Transactions of the Institute of Electrical Engineers of Japan,1999,119(07):383-389. |
[3] | TIMOTHY N. OBEE;ROBERT T. BROWN .TiO_2 Photocatalysis for Indoor Air Applications: Effects of Humidity and Trace Contaminant Levels on the Oxidation Rates of Formaldehyde, Toluene, and 1,3-Butadiene[J].Environmental Science & Technology: ES&T,1995(5):1223-1231. |
[4] | Dreyer M;G K Newman et al.Enhanced Oxidation of Air Contaminants on an Ultra-low Density uv-Accessible Aerogel Photocatalyst[J].Materials Research Society Symposium Proceedings,1997,454:141-146. |
[5] | TIMOTHY N. OBEE .Photooxidation of Sub-Parts-per-Million Toluene and Formaldehyde Levels on Titania Using a Glass-Plate Reactor[J].Environmental Science & Technology: ES&T,1996(12):3578-3584. |
[6] | 陶跃武 等.空气中有害物质的光催化去除[J].催化学报,1997,18(04):345-347. |
[7] | Hiroshi Yoneyama;Tsukasa Torimoto .Titanium Dioxide/adsorbent Hybrid Photocatalysts for Photodestruction of Organic Substances of Dilute Concentrations[J].Catalysis Today,2000,58:133-140. |
[8] | Zhang Y P;Yang R;Xu Y.A Model of Photocatalytic Air Cleaner for Analyzing the Performance of Removing VOCs in Indoor Air and Its Applications[A].,2002:717-720. |
[9] | Jacoby WA.;Noble RD.;Koval CA.;Blake DM. .KINETICS OF THE OXIDATION OF TRICHLOROETHYLENE IN AIR VIA HETEROGENEOUS PHOTOCATALYSIS[J].Journal of Catalysis,1995(1):87-96. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%