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以异佛尔酮二异氰酸酯(IPDI)、2,2-二羟甲基丙酸(DMPA)、大豆油(SOY)、乳酸(LA)为主要原料合成了水性聚氨酯乳液(WPU).通过红外分析(FT-IR)的手段对环氧大豆油-乳酸多元醇的结构进行了表征;利用透射电镜(TEM)、热重分析(TGA)、差示扫描量热法(DSC)及拉伸力学性能测试等方法探讨了水性聚氨酯乳液的形态、稳定性及其涂膜的耐热性能和机械性能.结果表明:利用环氧大豆油-乳酸开环聚酯多元醇合成的水性聚氨酯乳液具有良好的稳定性,粒子形态均一,乳液流平所制得的涂膜耐热性能及力学性能优异.

参考文献

[1] LU Y S;LAROCK R C .New hybrid latexes froma soybean oil-based waterbonre polyurethane and acrylics via emulsion polymerization[J].Biomacromolecules,2007,8(10):3108-3114.
[2] LU Y S;LAROCK R C .Soybean-oil-based watreborne polyurethane dispersios polyurethane dispersions:Effects of polyol functionality and hard segment content on properties[J].Biomacromolecules,2008,9(11):3332-3340.
[3] Kim BS;Kim BK .Enhancement of hydrolytic stability and adhesion of waterborne polyurethanes[J].Journal of Applied Polymer Science,2005(5):1961-1969.
[4] Jhon YK.;Kim JH.;Cheong IW. .Chain extension study of aqueous polyurethane dispersions[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2001(1):71-78.
[5] Coutinho FMB.;Delpech MC. .SOME PROPERTIES OF FILMS CAST FROM POLYURETHANE AQUEOUS DISPERSIONS OF POLYETHER-BASED ANIONOMER EXTENDED WITH HYDRAZINE[J].Polymer Testing,1996(2):103-113.
[6] Kim BK.;Seo JW.;Jeong HM. .Morphology and properties of waterborne polyurethane/clay nanocomposites[J].European Polymer Journal,2003(1):85-91.
[7] Gandini A .Polymers from Renewable Resources: A Challenge for the Future of Macromolecular Materials[J].Macromolecules,2008(24):9491-9504.
[8] BIERMANN U;FRIEDT W;LANG S et al.New syntheses with oils and fats as renewable raw materials for the chemical industry biermann[J].Angewandte Chemite International Edition,2000,39(13):2206-2224.
[9] Williams CK;Hillmyer MA .Polymers from renewable resources: A perspective for a special issue of polymer reviews[J].Polymer reviews,2008(1):1-10.
[10] PETROVIC Z S .Polyurethanes from vegetable oils[J].Polymer Reviews,2008,48(01):109-155.
[11] MEIER M A R;METZQER J O;SCHUBERT U S .Plant oil renewable resources as green alternatives in polymer science[J].Chemical Society Reviews,2007,36(11):1788-1802.
[12] 郭文杰,FU He-qing,傅和青,司徒粤,胡国文,蓝仁华,陈焕钦.环氧大豆油改性水性聚氨酯胶粘剂[J].包装工程,2008(08):1-3,9.
[13] 胡国文,沈慧芳,司徒粤,郭文杰,陈焕钦.羟基化环氧大豆油改性水性聚氨酯-丙烯酸酯涂料的研制[J].涂料工业,2008(11):33-36.
[14] SURESH K I .Rigid polyurethane foams from cardanol:synthesis,structural characterization,and evaluation of polyol and foam properities[J].ACS Sustainable Chemistry & Engineering,2013,1(02):232-242.
[15] LEE S J;KIM B K .Covalent incorporation of starch derivative into waterborne for biodegradability[J].Carbohydrate Polymers,2012,87(02):1803-1809.
[16] Zlatanic A.;Lava C.;Zhang W.;Petrovic ZS. .Effect of structure on properties of polyols and polyurethanes based on different vegetable oils[J].Journal of Polymer Science, Part B. Polymer Physics,2004(5):809-819.
[17] 颜萍,陈文求,徐祖顺.大豆油衍生物的制备及其在涂料中的应用[J].现代涂料与涂装,2013(02):1-4,11.
[18] Zhang, M.;Song, F.;Wang, X.-L.;Wang, Y.-Z..Development of soy protein isolate/waterborne polyurethane blend films with improved properties[J].Colloids and Surfaces, B. Biointerfaces,2012:16-21.
[19] Chang, C.-W.;Lu, K.-T. .Natural castor oil based 2-package waterborne polyurethane wood coatings[J].Progress in Organic Coatings: An International Review Journal,2012(4):435-443.
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