分别以乙酰丙酮铁(Fe(acac)3)和氯铂酸(H2PtCl6·6H2O)作为Fe源和Pt源,乙二醇作为还原剂和溶剂,通过多元醇还原法制备出单分散的FePt纳米颗粒,并研究了表面活性剂油酸油胺和CTAB对FePt纳米颗粒形貌和磁性能的影响.通过X射线衍射仪(XRD)、透射电子显微镜(TEM)和振动样品磁强计(VSM)对纳米颗粒进行表征.结果表明,表面活性剂油酸油胺和CTAB修饰的FePt纳米颗粒均为面心立方(FCC)结构,分散性良好,粒径分布较未使用表面活性剂时变窄;油酸油胺修饰的FePt形貌主要是球形,但是有四方形纳米结构出现;而CTAB修饰的FePt形貌有蠕虫状产生.VSM结果显示其矫顽力都趋近于零,呈现超顺磁性.
参考文献
[1] | Seo W S;Kim S M;Kim Y M et al.Synthesis of ultrasmall ferromagnetic face-centered tetragonal FePt-graphite core-shell nanocrystals[J].NIH Public Acc,2008,4(11):1968. |
[2] | Min Chen;Jaemin Kim;J.P.Liu;Hongyou Fan;Shouheng Sun .Synthesis of FePt Nanocubes and Their Oriented Self-Assembly[J].Journal of the American Chemical Society,2006(22):7132-7133. |
[3] | Sun S H;Murry C;Well Er D et al.Monodisperse FePt nanoparticles and ferromagnetic FePt nanocrystal superlattices[J].Science,2000,287(5460):1989. |
[4] | Elkins K;Li D;Poudyal N;Nandwana V;Jin ZQ;Chen KH;Liu JP .Monodisperse face-centred tetragonal FePt nanoparticles with giant coercivity[J].Journal of Physics, D. Applied Physics: A Europhysics Journal,2005(14):2306-2309. |
[5] | Sun, SH .Recent advances in chemical synthesis, self-assembly, and applications of FePt nanoparticles[J].Advanced Materials,2006(4):393-403. |
[6] | Liu C;Wu X W;Timothy K et al.Polyol process synthesis of monodispersed FePt nanoparticles[J].journal of Physical Chemistry B,2004,108(20):6121. |
[7] | Luciano E.M.Howard;H.Loc Nguyen;Sean R.Giblin;Brian K.Tanner;Ian Terry;Andrew K.Hughes;John S.O.Evans .A Synthetic Route to Size-Controlled fcc and fct FePt Nanoparticles[J].Journal of the American Chemical Society,2005(29):10140-10141. |
[8] | Soichiro Saita;Shinya Maenosono .Formation Mechanism of FePt Nanoparticles Synthesized via Pyrolysis of Iron(III)Ethoxide and Platinum(II)Acetylacetonate[J].Chemistry of Materials,2005(26):6624-6634. |
[9] | 杜雪岩,徐凯,李芳,史世毅,马芬.多元醇还原法制备FePt纳米颗粒[J].应用化工,2011(05):786-788. |
[10] | Colak, L;Hadjipanayis, GC .Chemically synthesized FePt nanoparticles with controlled particle size, shape and composition[J].Nanotechnology,2009(48):485602:1-485602:7. |
[11] | Kan, CX;Wang, CS;Zhu, JJ;Li, HC .Formation of gold and silver nanostructures within polyvinylpyrollidone (PVP) gel[J].Journal of Solid State Chemistry,2010(4):858-865. |
[12] | Vikas Nandwana;Kevin E Elkins;Narayan Poudyal et al.Size and shape control of monodisperse FePt nanoparticle[J].Phys Chem C,2007,111(11):4185. |
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