将芳基苄醚树枝配体酞菁锌四-3,5-(二-4-羧基苯甲氧基)-苯甲氧基]酞菁锌(DZnPc)与氨基化单壁碳纳米管(SWNTs-NH2)通过酰胺缩合反应合成了一种新型芳基苄醚树枝配体酞菁锌-单壁碳纳米管复合物(SWNTs-DZnPc).通过透射电镜(TEM)、热重分析(TGA)和拉曼光谱对SWNTs-DZnPc的结构进行了表征.采用紫外-可见吸收光谱(UV-Vis)和荧光光谱法研究了SWNTs-DZnPc的光物理性质.结果表明,DZnPc是以共价键方式修饰在SWNTs-NH2表面;在光诱导下,纳米复合物发生分子内电子转移,电子从DZnPc传递到SWNTs.
参考文献
| [1] | 陈进,张海燕,王晓刚,李健健,王超,李敏.酸处理对碳纳米管电子自旋共振谱的研究[J].人工晶体学报,2013(01):177-180,185. |
| [2] | DIRK M.GULDI;G.M.A.RAHMAN;FRANCESCO ZERBETTO;MAURIZIO PRATO .Carbon Nanotubes in Electron Donor-Acceptor Nanocomposites[J].Accounts of Chemical Research,2005(11):871-878. |
| [3] | 胡雅婷,周硕,马晓兰,李华.单壁碳纳米管储氢过程的GULP模拟[J].人工晶体学报,2012(01):215-220. |
| [4] | Stampfer C;Helbling T;Obergfell D;Schoberle B;Tripp MK;Jungen A;Roth S;Bright VM;Hierold C .Fabrication of single-walled carbon-nanotube-based pressure sensors[J].Nano letters,2006(2):233-237. |
| [5] | Li J;Wang YB;Qiu JD;Sun D;Xia XH .Biocomposites of covalently linked glucose oxidase on carbon nanotubes for glucose biosensor[J].Analytical and bioanalytical chemistry,2005(6):918-922. |
| [6] | Durairaj Baskaran;Jimmy W.Mays;X.Peter Zhang;Matthew S.Bratcher .Carbon Nanotubes with Covalently Linked Porphyrin Antennae:Photoinduced Electron Transfer[J].Journal of the American Chemical Society,2005(19):6916-6917. |
| [7] | Beatriz Ballesteros;Gema de la Torre;Christian Ehli;G. M. Aminur Rahman;F. Agullo-Rueda;Dirk M. Guldi;Tomas Torres .Single-Wall Carbon Nanotubes Bearing Covalently Linked Phthalocyanines - Photoinduced Electron Transfer[J].Journal of the American Chemical Society,2007(16):5061-5068. |
| [8] | 吴克勤,刘静,马冬冬,贸丹丹,陈婉玲,林秋云,邱燕珠,彭亦如.树枝酞菁锌-单壁碳纳米管复合体系的合成[J].厦门大学学报（自然科学版）,2011(z1):70-73. |
| [9] | Wadzanai Chidawanyika;Tebello Nyokong .Characterization of amine-functionalized single-walled carbon nanotube-low symmetry phthalocyanine conjugates[J].Carbon: An International Journal Sponsored by the American Carbon Society,2010(10):2831-2838. |
| [10] | Campidelli S;Ballesteros B;Filoramo A;Diaz DD;de la Torre G;Torres T;Rahman GMA;Ehli C;Kiessling D;Werner F .Facile decoration of functionalized single-wall carbon nanotubes with phthalocyanines via "Click Chemistry"[J].Journal of the American Chemical Society,2008(34):11503-11509. |
| [11] | Jeffrey L. Bahr;Jiping Yang;Dmitry V. Kosynkin;Michael J. Bronikowski;Richard E.Smalley;James M. Tour .Functionalization of Carbon Nanotubes by Electrochemical Reduction of Aryl Diazonium Salts: A Bucky Paper Electrode[J].Journal of the American Chemical Society,2001(27):6536-6542. |
| [12] | Dillon, E.P.;Crouse, C.A.;Barron, A.R. .Synthesis, characterization, and carbon dioxide adsorption of covalently attached polyethyleneimine-functionalized single-wall carbon nanotubes[J].ACS nano,2008(1):156-164. |
| [13] | M.S.Dresselhaus;G.Dresselhaus;A.Jorio .Raman Spectroscopy of Carbon Nanotubes in 1997 and 2007[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2007(48):17887-17893. |
| [14] | Le Ho, K.H.;Rivier, L.;Jousselme, B.;Jégou, P.;Filoramo, A.;Campidelli, S. .Zn-porphyrin/Zn-phthalocyanine dendron for SWNT functionalisation[J].Chemical communications,2010(46):8731-8733. |
| [15] | Campidelli S;Sooambar C;Diz EL;Ehli C;Guldi DM;Prato M .Dendrimer-functionalized single-wall carbon nanotubes: Synthesis, characterization, and photoinduced electron transfer[J].Journal of the American Chemical Society,2006(38):12544-12552. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%