通过添加不同有机模板,采用水热均相沉淀法制备了晶须状羟基磷灰石纳米材料.通过扫描电子显微分析( SEM)和X射线衍射分析(XRD)研究了羟基磷灰石晶须的形貌、长径比以及相组成等.结果表明,以乙二胺四乙酸(EDTA)、十六烷基三甲基溴化铵(CTAB)、山梨醇为有机模板,均能制备出晶须状羟基磷灰石,其中以EDTA为有机模板制备的羟基磷灰石晶须纯度最高,以山梨醇为模板制备的晶须具有较高的长径比和均一的形貌.
参考文献
[1] | Susmita Bose;Ashis Banerjee;Sudip Dasgupta .Synthesis, Processing, Mechanical, and Biological Property Characterization of Hydroxyapatite Whisker-Reinforced Hydroxyapatite Composites[J].Journal of the American Ceramic Society,2009(2):323-330. |
[2] | Roeder RK;Converse GL;Leng HJ;Yue WM .Kinetic effects on hydroxyapatite whiskers synthesized by the chelate decomposition method[J].Journal of the American Ceramic Society,2006(7):2096-2104. |
[3] | E. ADOLFSSON;L. HERMANSSON .Phase stability aspects of various apatite-aluminium oxide composites[J].Journal of Materials Science,2000(22):5719-5723. |
[4] | Park K;Sundaresan S;Vasilos T et al.SiC whisker-and C fiber-reinforced calcium phosphate composites[J].Journal of Materials Research,1994,9(10):2476. |
[5] | Suchanek WL.;Yoshimura M. .Preparation of fibrous, porous hydroxyapatite ceramics from hydroxyapatite whiskers[J].Journal of the American Ceramic Society,1998(3):765-767. |
[6] | Suchanek W.;Kakihana M.;Yoshimura M.;Yashima M. .PROCESSING AND MECHANICAL PROPERTIES OF HYDROXYAPATITE REINFORCED WITH HYDROXYAPATITE WHISKERS[J].Biomaterials,1996(17):1715-1723. |
[7] | Converse GL;Conrad TL;Merrill CH;Roeder RK .Hydroxyapatite whisker-reinforced polyetherketoneketone bone ingrowth scaffolds.[J].Acta biomaterialia,2010(3):856-863. |
[8] | Zhang X;Vecchio KS .Hydrothermal synthesis of hydroxyapatite rods[J].Journal of Crystal Growth,2007(1):133-140. |
[9] | Neira IS;Guitian F;Taniguchi T;Watanabe T;Yoshimura M .Hydrothermal synthesis of hydroxyapatite whiskers with sharp faceted hexagonal morphology[J].Journal of Materials Science,2008(7):2171-2178. |
[10] | A.Cuneyt Tas .Molten Salt Synthesis of Calcium Hydroxyapatite Whiskers[J].Journal of the American Ceramic Society,2001(2):295-300. |
[11] | Zhang H Q;Wang Y F;Yan Y H et al.Precipitation of biocompatible hydroxyapatite whiskers from moderately acid solution[J].Ceramics International,2003,29(04):413. |
[12] | Zhang H;Darvell BW .Synthesis and characterization of hydroxyapatite whiskers by hydrothermal homogeneous precipitation using acetamide.[J].Acta biomaterialia,2010(8):3216-3222. |
[13] | Hongquan Zhang;Ming Zhang .Phase and thermal stability of hydroxyapatite whiskers precipitated using amine additives[J].CERAMICS INTERNATIONAL,2011(1):279-286. |
[14] | Renlong Xin;Fuzeng Ren;Yang Leng .Synthesis and characterization of nano-crystalline calcium phosphates with EDTA-assisted hydrothermal method[J].Materials & design,2010(4):1691-1694. |
[15] | Li Yan;Yadong Li;Zhao-Xiang Deng;Jin Zhuang;Xiaoming Sun .Surfactant-assisted hydrothermal synthesis of hydroxyapatite nanorods[J].International journal of inorganic materials,2001(7):633-637. |
[16] | 黄志良,张联盟,刘羽,何前军,陈伟.有机模板诱导/均相沉淀法对羟基磷灰石(HAP)晶体形貌的控制生长[J].人工晶体学报,2006(02):261-264. |
[17] | Liu JB;Li KW;Wang H;Zhu MK;Yan H .Rapid formation of hydroxyapatite nanostructures by microwave irradiation[J].Chemical Physics Letters,2004(4-6):429-432. |
[18] | ZHANG Hai-bin,ZHOU Ke-chao,LI Zhi-you,HUANG Su-ping,ZHAO Yan-zhong.Morphologies of hydroxyapatite nanoparticles adjusted by organic additives in hydrothermal synthesis[J].中南大学学报(英文版),2009(06):871-875. |
[19] | 温喜梅,郭进武,张军,马兰,宋邦才,彭伟涛.山梨醇辅助下羟基磷灰石晶须的水热制备[J].无机盐工业,2008(11):21-23. |
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