反渗透膜在海水淡化、超纯水制备、污水处理、制药及生物技术等领域得到了广泛应用.目前,最成功的反渗透膜是通过界面聚合方法制备的以交联聚酰胺为分离皮层的复合膜.交联聚酰胺皮层的结构和性质对最终反渗透膜的分离性能起关键作用.本文简要介绍了界面聚合复合膜的形成过程和结构、新型界面聚合功能单体、界面聚合反应添加剂、纳米杂化反渗透复合膜、高耐氯氧化性反渗透膜,以及反渗透复合膜表征方法创新等方面的研究进展和发展趋势.
参考文献
[1] | 高从堦,杨尚保.反渗透复合莫技术进展和展望[J].膜科学与技术,2011(03):1-4. |
[2] | 李磊 .新型反渗透、纳滤复合膜材料的制备与性能[D].中国科学院长春应用化学研究所,2009. |
[3] | Kim KJ.;Matsuura T.;Chowdhury G. .Low pressure reverse osmosis performances of sulfonated poly(2,6-dimethyl-1,4-phenylene oxide) thin film composite membranes: effect of coating conditions and molecular weight of polymer[J].Journal of Membrane Science,2000(1/2):43-52. |
[4] | Sofrea M L;Nunes S .Composite nanofiltration membranes prepared by in situ polycondensationof amines in a poly(ethylene oxide-b-amide) layer[J].Journal of Membrane Science,1977,135:179-186. |
[5] | Yoshihiro Ito;Yasushi Ochiai;Yong Soon Park .pH-Sensitive Gating by Conformational Change of a Polypeptide Brush Grafted onto a Porous Polymer Membrane[J].Journal of the American Chemical Society,1997(7):1619-1623. |
[6] | Morgan P W.Condensation polymers:By interfacial and solution methods[M].New York:John Wiley and Sons,Inc,1965 |
[7] | Morgan P W.In encyclopedia of polymer science and engineering[M].New York:John Wiley and Sons,Inc,1985-8:221. |
[8] | Hoffmann K;Tieke B .Layer-by-layer assembled membranes containing hexacyclen-hexaacetic acid and polyethyleneimine N-acetic acid and their ion selective permeation behaviour[J].Journal of Membrane Science,2009,341:261267. |
[9] | William A. Phillip;Brandon O'Neill;Marc Rodwogin .Self-Assembled Block Copolymer Thin Films as Water Filtration Membranes[J].ACS applied materials & interfaces,2010(3):847-853. |
[10] | Morgan P W;Kwolek S L .Interfacial polycondensation.Ⅱ.Fundamen polymer formation at liquid interfaces[J].Journal of Polymer Science,1959,XL:299-327. |
[11] | MacRitchie F .Mechanism of interfacial polycondensation[J].Transactions of the Faraday Society,1968,65:2503-2507. |
[12] | Karode SK.;Suresh AK.;Mashelkar RA.;Kulkarni SS. .New insights into kinetics and thermodynamics of interfacial polymerization[J].Chemical Engineering Science,1998(15):2649-2663. |
[13] | S. K. Yadav;Kartic C. Khilar;A. K. Suresh .Microencapsulation in Polyurea Shell: Kinetics and Film Structure[J].AIChE Journal,1996(9):2616-2626. |
[14] | Ji J.;Dickson J.M. .Mathematical Model for the Formation of Thin-Film Composite Membranes by Interfacial Polymerizaiton: Porous and Dense Films[J].Macromolecules,2000(2):624-633. |
[15] | 于型伟 .界面聚合法制备分离CO2复合膜及成膜过程研究[D].天津大学,2010. |
[16] | Yuan F;Wang Z;Yu X et al.Visualization of the formation of interfacially polymerized fill by an optical contact angle measuring device[J].Journal of Physical Chemistry C,2012,116:11496-11506. |
[17] | Wamser C C;Gilbert M I .Detection of surface functional group asymmetry inInterfacially-polymerized films by contact angle titrations[J].Langmuir,1992,8:1608-1614. |
[18] | Freger V.;Srebnik S. .Mathematical model of charge and density distributions in interfacial polymerization of thin films[J].Journal of Applied Polymer Science,2003(5):1162-1169. |
[19] | Pacheco F A;Pinnau I;Reinhard M et al.Characterization of isolated polyamide thin films of RO and NF membranes using novel TEM techniques[J].Journal of Membrane Science,2010,358:51-59. |
[20] | Orlando Coronell;Benito J. Marinas;David G. Cahill .Depth Heterogeneity of Fully Aromatic Polyamide Active Layers in Reverse Osmosis and Nanofiltration Membranes[J].Environmental Science & Technology: ES&T,2011(10):4513-4520. |
[21] | 俞三传.界面聚合反渗透复合膜材料及其表面修饰[J].膜科学与技术,2011(03):172-175. |
[22] | Yong Zhou;Sanchuan Yu;Meihong Liudeg;Congjie Gao .Preparation and characterization of polyamide-urethane thin-film composite membranes[J].Desalination: The International Journal on the Science and Technology of Desalting and Water Purification,2005(1/3):189-196. |
[23] | Liu L;Yu S;Gao C et al.Study on a novel polyamide-urea reverse osmosis composite membrane (ICIC MPD) (Ⅰ),Preparation and characterization of ICIC MPDmembrane[J].Journal of Membrane Science,2006,281:88-94. |
[24] | Yu S;Liu M;Gao C et al.Aromatic-cycloaliphatic polyamide thin-film composite membrane with improved chlorine resistance prepared from m-phenylenediamine-4-methyl and cyclohexane-1,3,5-ricarbonylchlo ride[J].Journal of Membrane Science,2009,344:155-164. |
[25] | Lei Li;Suobo Zhang;Xiaosha Zhang;Guodong Zheng .Polyamide thin film composite membranes prepared from 3,4′,5-biphenyl triacyl chloride, 3,3′,5,5′-biphenyl tetraacyl chloride and m-phenylenediamine[J].Journal of Membrane Science,2007(1/2):258-267. |
[26] | Li L;Zhang SB;Zhang XS;Zheng GD .Polyamide thin film composite membranes prepared from isomeric biphenyl tetraacyl chloride and m-phenylenediamine[J].Journal of Membrane Science,2008(1/2):20-27. |
[27] | Li L;Zhang S;Zhang X et al.Preparation and characterization of poly(piperazineamide) composite nanofiltration membrane by interfacial polymerization of 3,3',5,5'-biphenyl tetraacyl chloride and piperazine[J].Journal of Membrane Science,2009,335:133-139. |
[28] | Seung-Yeop Kwak;Soo Gyung Jung;Sung Ho Kim .Structure-motion-performance relationship of flux-enhanced reverse osmosis (RO) membranes composed of aromatic polyamide thin films[J].Environmental Science & Technology: ES&T,2001(21):4334-4340. |
[29] | Meirong Duan;Zhi Wang;Jun Xu .Influence of hexamethyl phosphoramide on polyamide composite reverse osmosis membrane performance[J].Separation and Purification Technology,2010(2):145-155. |
[30] | Kong C;Kanezashi M;Yamomoto T et al.Controlled synthesis of high performance polyarnide membrane with thin dense layer for water desalination[J].Journal of Membrane Science,2010,362:76-80. |
[31] | Byeong-Heon Jeong;Eric M.V. Hoek;Yushan Yan;Arun Subramani;Xiaofei Huang;Gil Hurwitz;Asim K. Ghosh;Anna Jawor .Interfacial polymerization of thin film nanocomposites: A new concept for reverse osmosis membranes[J].Journal of Membrane Science,2007(1/2):1-7. |
[32] | Chunlong Kong;Takuji Shintani;Toshinori Tsuru ."Pre-seeding"-assisted synthesis of a high performance polyamide-zeolite nanocomposite membrane for water purification[J].New Journal of Chemistry,2010(10):2101-2104. |
[33] | Lin Zhang;Guo-Zhong Shi;Shi Qiu;Li-Hua Cheng;Huan-Lin Chen .Preparation of high-flux thin film nanocomposite reverse osmosis membranes by incorporating functionalized multi-walled carbon nanotubes[J].Desalination and water treatment: Science and engineering,2011(1/3):19-24. |
[34] | Alberto Tiraferri;Chad D. Vecitis;Menachem Elimelech .Covalent Binding of Single-Walled Carbon Nanotubes to Polyamide Membranes for Antimicrobial Surface Properties[J].ACS applied materials & interfaces,2011(8):2869-2877. |
[35] | Junwoo P;Kim C W;Hyun S .Enhancement of chlorine resistance in carbon nanotube based nanocomposite reverse osmosis Membranes[J].Desal Water Treat,2010,15:198-204. |
[36] | Kim E-S;Hwang G;El-Din M G et al.Development of nanosilver and multi-walled carbon nanotubes thinfilm nanocomposite membrane for enhanced water treatment[J].Journal of Membrane Science,2012,394-395:37-48. |
[37] | Ho Bum Park;Benny D.Freeman;Zhong-Bio Zhang .Highly Chlorine-Tolerant Polymers for Desalination[J].Angewandte Chemie,2008(32):6019-6024. |
[38] | Kim Y-J;Lee K-S;Jeong M-H et al.Highly chlorine-resistant end-group crosslinked sulfonated-fluorinated poly(arylene ether) for reverse osmosis membrane[J].Journal of Membrane Science,2011,378:512-519. |
[39] | Howard M. Colquhoun;David Chappell;Andrew L. Lewis .Chlorine tolerant, multilayer reverse-osmosis membranes with high permeate flux and high salt rejection[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2010(22):4629-4634. |
[40] | Z. Chen;K. Ito;H. Yanagishita .Correlation Study between Free-Volume Holes and Molecular Separations of Composite Membranes for Reverse Osmosis Processes by Means of Variable-Energy Positron Annihilation Techniques[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2011(37):18055-18060. |
[41] | SUNG HO KIM;SEUNG-YEOP KWAK;TAKENORI SUZUKI .Positron Annihilation Spectroscopic Evidence to Demonstrate the Flux-Enhancement Mechanism in Morphology-Controlled Thin-Film-Composite (TFC) Membrane[J].Environmental Science & Technology: ES&T,2005(6):1764-1770. |
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