利用低介电改性剂对氰酸酯树脂进行改性,制备了石英纤维/改性氰酸酯树脂复合材料,利用SEM表征了树脂及其复合材料的断面,并对改性氰酸酯树脂的耐热性能、力学性能、复合材料的力学性能及透波性能进行了研究.结果表明,改性氰酸酯树脂的玻璃化转变温度达到200℃以上,树脂拉伸破坏表现为韧性断裂,拉伸强度、弯曲强度和压缩强度分别在27MPa、69MPa和148MPa以上;改性氰酸酯树脂和纤维的界面结合良好,复合材料的拉伸强度、弯曲强度和压缩强度分别达到447MPa、461MPa和259MPa以上;在0.5~18GHz范围内,介电常数为3.1~3.3,4mm试样的S21小于-1.6dB.
参考文献
[1] | HAMERTON I;HAY J N .Recent developments in the chemistry of cyanate esters[J].Polymer International,1998,47(4):465-473. |
[2] | Robbe.A new look at the use of glass fiber-reinforced plastic piping[J].Materials Performance,1990(6):29-35. |
[3] | A S Chiu.FRP line pipe for oil and gas production[J].Materials Performance,1989(8):64-69. |
[4] | 蓝立文.氰酸酯树脂[J].玻璃钢/复合材料,1996(6):29-44. |
[5] | Tim J W;Simmi Abrol;Jeffrey M H.Thermal,mechanical,and conductivity Properties of cyanate ester composite[J].COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING,2004:75-82. |
[6] | Shimp D A;Christenson J R;Ising S J.Cyanate esters:an emerging family of versatile Composite resins[A].,1989:222-233. |
[7] | 钟翔屿,洪义强,包建文,陈祥宝.氰酸酯树脂体系的流变特性研究[J].玻璃钢/复合材料,2006(04):38-40,19. |
[8] | Srinivasan SA.;McGrath JE. .Amorphous phenolphthalein-based poly(arylene ether) modified cyanate ester networks: 1. Effect of molecular weight and backbone chemistry on morphology and toughenability[J].Polymer: The International Journal for the Science and Technology of Polymers,1998(12):2415-2427. |
[9] | Srinivasan SA.;Kranbeuhl D.;Ward TC.;Mcgrath JE.;Joardar SS. .AMORPHOUS PHENOLPHTHALEIN-BASED POLY(ARYLENE ETHER)-MODIFIED CYANATE ESTER NETWORKS - MICROWAVE PROCESSING[J].Journal of Applied Polymer Science,1997(1):179-190. |
[10] | Karad S K;Jones F R .Moisture absorption by cyanate ester modifièd epoxy resin matrices.Part Ⅱ.The reverse thermal effect[J].POLYMER,2002,43(21):5643-5649. |
[11] | Liang GZ.;Zhang MX. .Enhancement of processability of cyanate ester resin via copolymerization with epoxy resin[J].Journal of Applied Polymer Science,2002(11):2377-2381. |
[12] | Mathew D;Nair C P R;Ninan K N .Bisphenol A dicyanate-novolac epoxy blend:Cure characteristic,physical and mechanical properties,and application in composites[J].Journal of Applied Polymer Science,1999,74(7):1675-1685. |
[13] | Borrajo J.;Williams RJJ.;Cao ZQ.;Pascault JP.;Riccardi CC. .RUBBER-MODIFIED CYANATE ESTERS - THERMODYNAMIC ANALYSIS OF PHASE SEPARATION[J].Polymer: The International Journal for the Science and Technology of Polymers,1995(18):3541-3547. |
[14] | 戴善凯,顾嫒娟,梁国正,袁莉.氰酸酯树脂的固化催化研究新进展[J].材料导报,2009(09):57-60,64. |
[15] | 张俐娜.高分子物理近代研究方法[M].武汉:武汉大学出版社,2006:211-260. |
[16] | 陈镜弘.热分析及其应用[M].北京:科学出版社,1985:326. |
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