本文采用高温固相法制备了拉曼光谱强度可控的硼硅锌(ZnO-B2O3-SiO2)玻璃.分别采用X射线衍射仪(XRD)、荧光光谱(RF)和拉曼光谱(Raman)表征了样品的结构和光学性能.结果表明,ZnO-B2O3-SiO2玻璃基质中掺杂微量BaCO3、TjO2,制备出拉曼光谱强度可控的硼硅锌玻璃.硼硅锌玻璃样品配方中SiO2和B2O3含量对玻璃拉曼光谱强度有重要影响,随着SiO2含量的增加和B2O3含量的减少,玻璃样品拉曼光谱强度逐渐降低.当SiO2含量为40％,B2O3含量为36.2％时,在514 nm波长下激发,玻璃样品与参考玻璃的荧光激发光谱最为接近.
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