综述了近几年LiMnx Fe1-xPO4/C的研究现状,对其第一性原理和结构进行总结,重点介绍了合成LiMnx Fe1xPO4/C的原料和工艺,分析了材料在电化学方面存在的不足,并提出了一些新的思路和研究方向,同时展望了LiMnx Fe1-xPO4/C的发展.
参考文献
| [1] | Deb A;Bergmann U;Cairns E J et al.Structural investigations of LiFePO4 electrodes by Fe X-ray absorption spectroscopy[J].Journal of Physical Chemistry B,2004,108:7046. |
| [2] | Prosini PP.;Lisi M.;Zane D.;Pasquali M. .Determination of the chemical diffusion coefficient of lithium in LiFePO4[J].Solid state ionics,2002(1/2):45-51. |
| [3] | Liao X Z;He Y S;Ma Z F .Effects offluorine-substitution on the electrochemical behavior of LiFePO4/C cathode material[J].Journal of Power Sources,2007,174(02):720. |
| [4] | Wang L N;Zhang Z G;Zhang K L .A simple,cheap soft synthesis routine for LiFePO4 using iron(Ⅲ) raw material[J].Journal of Power Sources,2007,167:200. |
| [5] | Cui Y;Wang M;Guo R S .High rate performance of LiFePO4 cathode materials co-doped with C and Ti4+ by microwave synthesis[J].Bulletin of Materials Science,2009,32:579. |
| [6] | Wang D;Ouyang C;Drezen T et al.Improving the electrochemical activity of LiMnPO4 via Mn-site substitution[J].Journal of the Electrochemical Society,2010,157(02):A225. |
| [7] | Doi, T;Yatomi, S;Kida, T;Okada, S;Yamaki, J .Liquid-Phase Synthesis of Uniformly Nanosized LiMnPO4 Particles and Their Electrochemical Properties for Lithium-Ion Batteries[J].Crystal growth & design,2009(12):4990-4992. |
| [8] | A. Yamada;S.-C. Chung .Crystal Chemistry of the Olivine-Type Li(Mn_yFe_(1-y))PO_4 and (Mn_yFe_(1-y))PO_4 as Possible 4 V Cathode Materials for Lithium Batteries[J].Journal of the Electrochemical Society,2001(8):A960-A967. |
| [9] | 窦俊青,康雪雅,吐尔迪·吾买尔,华宁,韩英.Mn掺杂LiFeP04的第一性原理研究[J].物理学报,2012(08):341-348. |
| [10] | Wang L;Zhang L W;Li J J et al.First-principles study of doping in LiMnPO4[J].International Journal of Electrochemical Science,2012,7:3362. |
| [11] | Kopeg M;Yamada A et al.Structural and magnetic properties of Lix (Mny Fe1-y) PO4 electrode mat erials for Li-ion batteries[J].Journal of Power Sources,2009,189:1154. |
| [12] | Yarnada A;Takei Y;Koizumi H et al.Electrochemical,magnetic,and structural investigation of the Lix (Mny Fe1-y)-PO4 olivine phases[J].CHEMISTRY OF MATERIALS,2006,18:804. |
| [13] | Delacourt C;Laffont L;Bouchet R;Wurm C;Leriche JB;Morcrette M;Tarascon JM;Masquelier C .Toward understanding of electrical limitations (electronic, ionic) in LiMPO4 (M = Fe, Mn) electrode materials[J].Journal of the Electrochemical Society,2005(5):A913-A921. |
| [14] | Yusuke Asari;Yuji Suwa;Tomoyuki Hamada .Formation and diffusion of vacancy-polaron complex in olivine-type LiMnPO_4 and LiFePO_4[J].Physical review, B. Condensed matter and materials physics,2011(13):134113:1-134113:7. |
| [15] | Gardiner G R;Islam M S .Anti-site defects and ion migration in the LiFe1-x Mnx PO4 mixed-metal cathode material[J].CHEMISTRY OF MATERIALS,2010,22(03):1242. |
| [16] | Tatsuya Nakamura;Kiyotaka Sakumoto;Shiro Seki .Apparent Diffusion Constant and Electrochemical Reaction in LiFe_(1-x)Mn_xPO_4 Olivine Cathodes[J].Journal of the Electrochemical Society,2007(12):A(1118-1123). |
| [17] | Zhang B;Wang X J;Li H .Electrochemical performances of LiFe1-x MnxPO4 with high Mn content[J].Journal of Power Sources,2011,196:6992. |
| [18] | Yang, L;Jiao, LF;Miao, YL;Yuan, HT .Synthesis and characterization of LiFe0.99Mn0.01 (PO4)(2.99/3)F-0.01/C as a cathode material for lithium-ion battery[J].Journal of solid state electrochemistry,2010(6):1001-1005. |
| [19] | Wang Z H;Yuan L X;Zhang W X et al.LiFe0.8Mn0.2-PO4/C cathode material with high energy density for lithiumion batteries[J].Journal of Alloys and Compounds,2012,532:25. |
| [20] | Chen, YC;Chen, JM;Hsu, CH;Lee, JF;Yeh, JW;Shih, HC .In-situ synchrotron X-ray absorption studies of LiMn0.25Fe0.75PO4 as a cathode material for lithium ion batteries[J].Solid state ionics,2009(20/22):1215-1219. |
| [21] | 肖卓炳,麻明友,何则强,吴显明,刘建本.锂离子蓄电池正极材料LiFe0.7Mn0.3PO4的制备与性能[J].电源技术,2005(12):805-807. |
| [22] | Mi C H;Zhang X G;Zhao X B et al.Synthesis and performance of LiMn0.6 Fe0.4 PO4/nano-carbon webs composite cathode[J].Materials Science and Engineering B,2006,129 1:8. |
| [23] | Grahame R. Gardiner;M. Saiful Islam .Anti-Site Defects and Ion Migration in the LiFe_(0.5)Mn_(0.5)PO4 Mixed-Metal Cathode Material[J].Chemistry of Materials: A Publication of the American Chemistry Society,2010(3):1242-1248. |
| [24] | Bin Zhang;Xiaojian Wang;Zhaojun Liu .Enhanced Electrochemical Performances of Carbon Coated Mesoporous LiFe_(0.2)Mn_(0.8)PO_4[J].Journal of the Electrochemical Society,2010(3):A285-A288. |
| [25] | Zou Q Q et al.Preparation of carbon-coated LiFe0.2 Mn0.8-PO4 cathode material and its application in a novel battery with Li4 Ti5 On anode[J].Journal of Power Sources,2012,206:222. |
| [26] | Kyung Tae Lee;Kyung Sub Lee .Electrochemical properties of LiFe_(0.9)Mn_(0.1)PO_4/Fe_2P cathode material by mechanical alloying[J].Journal of Power Sources,2009(1):435-439. |
| [27] | Xu, J;Chen, G;Li, HJ;Lv, ZS .Direct-hydrothermal synthesis of LiFe1-x Mn (x) PO4 cathode materials[J].Journal of Applied Electrochemistry,2010(3):575-580. |
| [28] | Zhao M S;Huang G L;Zhang B et al.Characteristics and electrochemical performance of LiFe0.5 Mn0.5 PO4/C used as cathode for aqueous rechargeable lithium battery[J].Journal of Power Sources,2012,211:202. |
| [29] | Bhuvaneswari D;Gangulibabu et al.Role of iron dopant and carbon additive in improving the ionic transport and electrochemical properties of LiFex Mn1-x PO4 (x =0.25 and 0.75) solid solutions[J].International Journal of Electrochemical Science,2011,6:3714. |
| [30] | Li D;Xia Y N .Electrospinning of nanofibers:Reinventing the wheel[J].Advanced Materials,2004,16:1151. |
| [31] | Hagen R V;Lorrmann H et al.Electrospun LiFe1-y-Mny PO4/C nanofiber composites as self-supporting cathodes in Li-ion batteries[J].Advanced Energy Materials,2012,2:553. |
| [32] | Zaghib K;Trudeau M;Guerfi A et al.New advanced cathode material:LiMnPO4 encapsulated with LiFePO4[J].Journal of Power Sources,2012,204:177. |
| [33] | Chen L et al.Enhanced electrochemical properties of LiFe1-x Mnx PO4/C composites synthesized from FePO4 @2H2 O nanocrystallites[J].Journal of Power Sources,2012,214:344. |
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