观察并研究了不同Y2O3含量的Cu/Y2O3共掺杂MgB2的体系,样品通过传统的固相烧结法制备。结合扫描电镜和X射线衍射技术的分析发现,只有在5%Y2O3掺杂的样品中获得了层状组织。选择5%Y2O3含量的体系结合热分析曲线对固相反应阶段进行了动力学分析,得出最概然机理函数为Avrami-Erofeev,n=2,表达式为2[-ln(1-α)]1/2。其意义是随机形核和随后的瞬时生长。最后对动力学参数进行了计算,结果表明反应的活化能和指前因子均先趋于稳定后减小。
参考文献
[1] | Nagamatsu J;Nakagawa N;Muranaka T;Zenitani Y;Akimitsu J .Superconductivity at 39 K in magnesium diboride[J].Nature,2001(6824):63-64. |
[2] | Buzea C;Yamashita T .Review of the superconducting properties of MgB2[J].Superconductor Science and Technology,2001,14(11):R115-R146. |
[3] | Larbalestier DC;Cooley LD;Rikel MO;Polyanskii AA;Jiang J;Patnaik .Strongly linked current flow in polycrystalline forms of thesuperconductor MgB2[J].Nature,2001(6825):186-189. |
[4] | Finncmore D K;Ostenson J E;Bud'ko S L;ct al .Thermodynamic and transpo propcies of superconducting( MgB2)-B-10[J].Physical Review Letters,2001,86(11):2420-2422. |
[5] | Tachikawa K;Yamada Y;Suzuki O et al.Effects of metal powder addition on the critical current in MgB2 tapes[J].Physica C,2002,382:108112. |
[6] | T. Masui;S. Lee;S. Tajima .Carbon-substitution effect on the electronic properties of MgB_2 single crystals[J].Physical review, B. Condensed matter and materials physics,2004(2):024504.1-024504.7. |
[7] | A Berenov;A Serquis;X Z Liao .Enhancement of critical current density in low level Al-doped MgB_2[J].Superconductor Science & Technology,2004(10):1093-1096. |
[8] | Tampieri A.;Celotti G.;Sprio S.;Rinaldi D.;Barucca G.;Caciuffo R. .Effects of copper doping in MgB2 superconductor[J].Solid State Communications,2002(9/10):497-500. |
[9] | Feng WJ;Xia TD;Liu TZ;Zhao WJ;Wei ZQ .Synthesis and properties of Mg(1-x)CuxB2 bulk obtained by self-propagating high-temperature synthesis (SHS) method at low temperature[J].Physica, C. Superconductivity and its applications,2005(3/4):144-148. |
[10] | Kimishima Y;Takami S;Uehara M;Kuramoto T .Pinning property of Cu/MgB2 system[J].Physica, C. Superconductivity and its applications,2006(0):224-227. |
[11] | Zongqing Ma;Yongchang Liu;Zhiming Gao .The synthesis and grain connectivity of lamellar MgB_2 grains by Cu-activated sintering at low temperature[J].Scripta materialia,2010(4):399-402. |
[12] | Ma Z Q;Liu Y C;Shi Q Z et al.The mechanism of accelerated phase formation of MgB2 by Cn-doping during low-temperature sintering[J].Materials Research Bulletin,2009,44(03):531-537. |
[13] | Neson Varghese;K. Vinod;S. Rahul;K. M. Devadas;Syju Thomas;S. Pradhan;U. Syamaprasad .Influence of nano-Cu additive on MgB_(2) phase formation, processing temperature, and transport properties[J].Journal of Applied Physics,2011(3):033902-1-033902-4. |
[14] | N. Ojha;G. D. Varma;H. K. Singh;V. P. S. Awana .Effect of rare-earth doping on the superconducting properties of MgB_(2)[J].Journal of Applied Physics,2009(7):07E315-1-07E315-3-0. |
[15] | Katsura Y;Shimoyama J;Yamamoto A;Horii S;Kishio K .Effects of rare earth doping on the superconducting properties of MgB2[J].Physica, C. Superconductivity and its applications,2007(0):225-228. |
[16] | J. Wang;Y. Bugoslavsky;A. Berenov;L. Cowey;A. D. Caplin;L. F. Cohen;J. L. MacManus Driscoll;L. D. Cooley;X. Song;D. C. Larbalestier .High critical current density and improved irreversibility field in bulk MgB_(2) made by a scaleable, nanoparticle addition route[J].Applied physics letters,2002(11):2026-2028. |
[17] | Ozawa T .A new method of analyzing thermogravimetrie data[J].Bulletin of the Chemical Society of Japan,1965,38(11):1881-1886. |
[18] | Flynn J H;Wall L H .General treatment of the thermogravimetry of polymers[J].J Res Bur Stand A,1966,70:487-523. |
[19] | Jager B;Paluch S;Wolfc W et al.Characterization of the electronic properties of YB4 and YB6 using B-11 NMR and first-principles calculations[J].Journal of Alloys and Compounds,2004,383(1 - 2):232-238. |
[20] | Gladman T .On the theory of the effect of precipitate particles on grain growth in metals[J].Proceedings of the Royal Society of London,1966,294(1438):298-309. |
[21] | J.Yamaguchi;H.Inui .High-temperature structural intermetallics[J].Acta materialia,2000(1):307-322. |
[22] | Liu Y C;Shi Q Z;Zhao Q et al.Kinetics analysis for the sintering of bulk MgBz superconductor[J].Journal of Materials Science:Materials in Electronics,2007,18(08):855-861. |
[23] | Lorentz G G .A contribution to the theory of divergent sequences[J].Acta Mathematica,1948,80(01):167-190. |
[24] | Popescu C. .INTEGRAL METHOD TO ANALYZE THE KINETICS OF HETEROGENEOUS REACTIONS UNDER NON-ISOTHERMAL CONDITIONS - A VARIANT ON THE OZAWA-FLYNN-WALL METHOD[J].Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems,1996(2):309-323. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%