橄榄石型LiFePO4是近年发展起来的一种锂离子电池正极材料,它的理论容量为170mAh/g.具有价格便宜、环境友好、无毒、无吸湿性、热稳定性好等优点,越来越受到人们的重视.但是由于LiFePO4的室温电导率低,影响了它的实际应用,为改善其电导率低的问题,本文采用固相法掺杂稀土元素Y合成Li0.99Y0.01FePO4,结果表明,掺杂后材料具有良好的电化学性能,其室温初始放电容量为129.9mAh/g,循环15次后几乎没有衰减.
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