利用摩尔比为NaCl:KCl:NaF=2:2:1的碱金属卤化物混合体系做载体,等摩尔比的Na2SiF6和Si粉作渗硅剂,在900 ℃下利用熔融盐法对0Cr18Ni9不锈钢进行了渗硅处理.采用X射线衍射仪(XRD)和附带能量色散谱仪(EDS)附件的扫描电子显微镜(SEM)研究了渗层截面的物相组成、成分,显微形貌及渗硅层的形成机理.结果表明,900 ℃下保温3 h渗层厚度在250 μm以上,渗层物相为富含Cr、Ni合金元素的Fe,Si型金属间化合物,渗层中Si的含量为6.75 wt%,Cr的含量仅为其在基体中含量的50%左右,Ni在基体和渗层中的含量相当,渗层表面致密,硬度在700 HV左右,远高于基体硬度200 HV.
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