采用扫描电镜(SEM/EDAX)和显微红外光谱对Zn在相对湿度为90%和0.9×10^-6SO2的控制气氛条件下初期腐蚀表面和腐蚀产物进行了研究,10h以后腐蚀表面呈现均匀分布的凹凸形貌特征,直到数日后开始萌生局部腐蚀,测试结果表明局部腐蚀的产物碱式水合硫酸盐。
Laboratory expxure of zinc was carried out under the condition of 0.9 x 902 and 90% relative humidity in order to investigate the characteristics of ded surface and its role in initial stage. Scanning electmn microscope (SIN/EDAX), IR microscope were used for the characterisation of ded surfaces. It was found that wer 10 h exposure resulted in a rather uniformly d l ncduls like mrphology with size about I-, which was not kept until local cornion sprouted wer a week mure. The cornion product on locally coded area with porous appearance, was mnposed of needle-shaped crystals. Based on the IR and EDAX, it was infered that the product was Z&Q(OH)6 .5H20. The mechanism of atnmpheric cornion for zinc under the condition is discussed.
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