欢迎登录材料期刊网

材料期刊网

高级检索

以十二烷基苯磺酸钠(SDBS)为掺杂剂采用乳液聚合法合成了不同掺杂率的聚吡咯.通过元素分析n(S)/n(N)表征了所得聚吡咯的掺杂率,并测试了不同掺杂率的聚吡咯的电导率,发现电导率随掺杂率的增加先增大后下降.以掺杂聚吡咯为吸波荆制备了环氧树脂复合材料,并测试了其在X波段的电磁参数.由单层平行板模型 计算出复合材料的吸波性能,结果表明,当n(SDBS)/n(Py)=0.2(Py为吡咯单体)的掺杂聚吡咯(PPy)在复合材料中的含量为20%时吸波性能最好,即当样品厚度为2.3mm时其反射损耗最小,达到-14.8dB,且在9.5~11.6GHz的频宽范围均低于-10dB.

参考文献

[1] Aldissi M.Intrinsically conducting polymers:An emerging technology[M].Dordrecht:Kluwer Publishing,1993:1.
[2] Nalwa H S.Handbook of organic conducting molecules and polymers[M].Chichester:John Wiley and Sons,Inc,1997:1.
[3] Skotheim T A;Elsenbaumler R L;Reynolds J R.Handbook of conducting polymers[M].New York:Narcel Dekker,Inc,1998:1.
[4] 毛倩瑾,周美玲,陆山,戴瑶.导电高聚物吸波材料的研究进展[J].北京工业大学学报,2004(04):488-493.
[5] Nagai K L;Rendell R W.Handbook of conducting polymers[M].New York,USA:Marcel Dekker,Inc,1986:1.
[6] Feldblum A;Park Y W;Heeger A J et al.Microwave properties of low-density polyacetylene[J].Journal of Polymer Science Part B:Polymer Physics,1981,19(01):173.
[7] Phillips G;Suresh R;Waidman J et al.Dielectric properties of polypyrrole doped with tosylate anion in the far infrared and microwave[J].Journal of Applied Physics,1991,69(15):899.
[8] Unsworth J;Kayak A et al.Microwave transmission,reflection and dielectric properties of conducting and semiconducting polypyrrole films and powders[J].Journal of Materials Science,1993,28(12):3307.
[9] Buckley L J;Dudeck K E .Complex dielectric behavior of polyaniline at microwave and millimeter-wave frequencies[J].Synthetic Metals,1992,52(03):353.
[10] Javadi H H S;Cromack K R;MacDiarmid A G et al.Microwave transport in the emeraldine form of polyaniline[J].Physical Review B,1989,39(06):3579.
[11] 殷敬华;莫志深.现代高分子物理学[M].北京:科学出版社,2001:421.
[12] A. N. Yusoff;M. H. Abdullah;S. H. Ahmad;S. F. Jusoh;A. A. Mansor;S. A. A. Hamid .Electromagnetic and absorption properties of some microwave absorbers[J].Journal of Applied Physics,2002(2):876-882.
[13] Mingjuan Han;Ying Chu;Dongxue Han;Yang Liu .Fabrication and characterizations of oligopyrrole doped with dodecylbenzenesulfonic acid in reverse microemulsion[J].Journal of Colloid and Interface Science,2006(1):110-117.
[14] Shuangxi Xing;Guoku Zhao .Morphology and thermostability of polypyrrole prepared from SDBS aqueous solution[J].Polymer bulletin,2006(6):933-943.
[15] 苏静,王庚超,邓惠山,范晓青.掺杂质子酸的类型对聚苯胺结构和电导率的影响[J].功能高分子学报,2002(02):122-126.
[16] Akif Kaynak;Llew Rintoul;Graeme A. George .Change of mechanical and electrical properties of polypyrrole films with dopant concentration and oxidative aging[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2000(6):813-824.
[17] 刘顺华;刘军民;董星龙.电磁波屏蔽及吸波材料[M].北京:化学工业出版社,2007:211.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%