通过溶胶-凝胶方法制备了尖晶石结构的La2NiO4/Al2O3催化剂,采用BET,XRD和TG表征了催化剂的孔分布、比表面积、体相组成以及凝胶样品的热失重和热分解过程. 将催化剂应用于CH4/CO2重整反应制合成气,考察了惰性气体和反应温度对转化率、选择性以及积碳的影响. 结果表明,在高空速(GHSV=4.8×104 ml/(g*h))下,CH4和CO2的转化率分别为51%和60%,CO和H2的选择性约为98%和92%,惰性气体He的引入明显地提高了CH4和CO2的转化率.
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