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We think that the thermally biological effects of millimeter waves are caused by the thermal motions of water molecules in the living systems, according to experimental fact that the millimeter waves can heat water, and the skin effect on the surface of the biological tissues arising from the millimeter waves. For clarifying this idea we studied the states and features of the liquid water and calculated the rotational energy-spectra of water molecules in the living systems by quantum mechanics. In fact, there is a large number of water which are polarized and have certain dipole moments in the living systems. This shows that the millimeter waves can interact with the water molecules. Through calculation of quantum rotational energy-spectra of the water molecules, we can confirm that the water molecules can absorb the millimeter waves with certain wavelength to generate the rotations of water molecules according to the principle of resonant absorption. One mechanism of the thermally biological effect of the millimeter waves is just a result produced by disorderly thermal-motions of the water molecules which are transformed from their rotation energy caused by the millimeter waves. Owing to the fact that water has a lot of biological functions and plays an important role in the living activity. Thus the heating waters by the millimeter waves can cause a lot of biological effects and phenomena in the living systems. Another mechanism of the thermally biological effect of the millimeter waves is caused by the Joule-Lenz heat arising from the skin effect of the millimeter waves in the skin layers of human beings and animals and membranes of cells which can facilitate the blood circulation in them. We finally study this effect.

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