中温脆性、回火脆性是困扰材料学界百年的两大晶间脆性难题,其发生机理一直是材料科学与工程学界研究的热点.根据溶质非平衡偏聚恒温动力学特征,总结出了中温脆性的非平衡偏聚机理.另外,依据溶质非平衡偏聚的临界时间现象,综述了回火脆性的非平衡偏聚研究最新进展.通过对以上两种晶间脆性断裂发生机理的分析发现,它们都是由溶质的非平衡偏聚临界时问引起的.
Intermediate temperature embrittlement and temper embrittlement are the problem of intergranular embrittlement which has puzzled the field of materials science and engineering.The mechanisms of these interg-ranular embrittlements have been studied for hundred years.In view of the isothermal kinetics characteristic for NGS,the mechanisms of intermediate temperature embrittlement are discussed.In addition,based on the critical time characteristic,the NGS mechanism of temper embrittlement will be summarized.It is found that intermediate temperature embrittlement and temper embrittlement are indueed by the critical time of NGS for solute.
参考文献
| [1] | Bieber C G;Decker R F .The Melting of Malleable Nickel and Nickel Alloys[J].Transactions AIME,1961,221:629. |
| [2] | Rhines F N;Wray P J .Investigation of the Intermediate Tem-perature Ductility Minimum in Metals[J].Transactions ASM,1961,54(02):117. |
| [3] | Bengough G D .A Study of the Properties of Alloys at High Temperatures[J].Journal of the Institute of Metals,1912,7(01):123. |
| [4] | Lankford W T .Some Consideration of Strength and Ductility in the Continuous-Casting Process[J].Metallurgical and Materials Transactions,1972,3(06):1331. |
| [5] | Mintz B;Yue S;Jonas J J .Hot Ductility of Steels and Its Relationship to the Problem of Transverse Cracking During Continuous Casting[J].International Materials Reviews,1991,36(05):187. |
| [6] | Mintz B .The Influence of Composition on the Hot Ductility of Steels and to the Problem of Transverse Cracking[J].ISIJ International,1999,39(09):833. |
| [7] | Ozgowicz W .The Relationship Between Hot Ductility and In-tergranular Fracture in a CuSn6P Alloy at Elevated Tempera-tures[J].Journal of Materials Processing Technology,2005,162-163(05):392. |
| [8] | Maure E;Hohage R .Mitt Kais Wilh Inst Eisenforschung,1921,2:91 From I Olefjird.Temper Embrittlement[J].International Metals Reviews,1978,4:149. |
| [9] | Seah M P .Grain Boundary Segregation and the T-t Gependence of Temper Brittleness[J].Acta Metallurgica,1977,25(03):345. |
| [10] | Olefiird I .Temper Embrittlement[J].International Metals Reviews,1978,4:149. |
| [11] | Xu Tingdong;Cheng Buyuan .Kinetics of non-equilibrium grain-boundary segregation[J].Progress in materials science,2004(2):109-208. |
| [12] | McLean D.Grain Boundaries in Metals[M].Boston:Oxford Univ Press,1957 |
| [13] | Aust K T;Hanneman R E;Niessen P et al.Solute Induced Harding Near Grain Boundaries in Zone Refined Metals[J].Acta Metallurgy,1968,16(03):291. |
| [14] | Anthony T R .Solute Segregation in Vacancy Gradients Generated by Sintering and Temperature Changes[J].ACTA METALLURGICA,1969,17(05):603. |
| [15] | williams T M .The Segregation and Effects of Boron in Austenitic Stainless Steel[J].Metal Science Journal,1972,6:68. |
| [16] | Williams T M;Stoneham A M;Harries D R .The Segregation of Boron to Grain Boundaries in Solution-Treated Type316 Austenitic Stainless Steel[J].Metal Science Journal,1976,10(01):14. |
| [17] | Xu Tingdong .Non-Equilibrium Grain-Boundary Segregation Kinetics[J].Journal of Materials Science,1987,22(01):337. |
| [18] | Xu Tingdong;Song Shenhua .A Kinetic Model of Non-Equi-librium Grain Boundary Segregation[J].Acta Metallurgica,1989,37(09):2499. |
| [19] | Faulkner R G .Non-Equilibrium Grain-Boundary Segregation in Austenitic Alloys[J].Journal of Materials Science,1981,16(02):373. |
| [20] | R. G. Ding;T. S. Rong;J. F. Knott .Phosphorus segregation in 2.25Cr-1Mo steel[J].Materials Science and Technology: MST: A publication of the Institute of Metals,2005(1):85-92. |
| [21] | Li Qing fen;Li Li;Liu Er-Bao et al.Temper EmbrittlementDynamics Induced by Non-Equilibrium Segregation Segregation of Phosphorus in Steel 12CrlMoV[J].Scripta Materialia,2005,53(03):309. |
| [22] | Zhang Z L;Lin QY;Yu Z S .Grain Boundary Segregation inUltra-Low Carbon Steel[J].Materials Science and Engineering A:Structural Materials Properties Microstructure and Processing,2000,291(1-2):22. |
| [23] | Zhang Z L;Q Y Lin;Z S Yu .Non-Quilibrium Intergrainular Segregation in Ultra Low Carbon Steel[J].Mater Sci Tech-nol,2000,16(03):305. |
| [24] | Xu Tingdong .Critical Time for Mg Grmn-Boundary Segregation in Ni-Cr-Co Alloy[J].Philosophical Magazine Letters,2006,86(08):501. |
| [25] | He X L;Chu Y Y;Jonas J J .The Grain Boundary Segregation of Boron During Isothermal Holding[J].Acts Metallurgica,1989,37(11):2905. |
| [26] | Karlsson L;Norden H;Odelius H .Non-Equilibrium Grain Boundary Segregation of Boron in Austenitic Stainless Steel[J].Acta Metallurgica,1988,36(01):1. |
| [27] | Peter Sevc;Jozef Janovec;Manfred Lucas .Kinetics of phosphorus segregation in 2.7Cr-0.7Mo-0.3V steels with different phosphorus contents[J].Steel Research,1995(12):537-542. |
| [28] | Tan J;Huang W;Chao Y J .Prediction of Fracture Appea-rance Transition Temperature of 2.25Cr-i Mo Steel Used in Hot-Wall Hydrofining Reactors[J].J Press Vess Technol,2006,128(04):566. |
| [29] | W. CHEN;M.C. CHATURVEDI;N.L. RICHARDS .Effect of Boron Segregation at Grain Boundaries on Heat-Affected Zone Cracking in Wrought INCONEL 718[J].Metallurgical and Materials Transactions, A. Physical Metallurgy and Materials Science,2001(4):931-939. |
| [30] | Faulkner R G .Impurity Diffusion Constants and Vacancy-Ira-purity Binding Energies in Solids[J].Mater Sei Technol,1985,1(06):442. |
| [31] | Vorlick V;Flewitt PEJ .Cooling Induced Segregation of Irn-purity Elements to Grain Boundaries in Fe-3wt%Ni Alloys,2.25wt%Cr-1wt%Mo Steel and Submerged Arc Weld Metal[J].Acts Metall Mater,1994,42(10):3309. |
| [32] | Brandes E A;G B Brook.Smithells Metal Referenee Book[M].Oxford:Butterworth-Heinemann,1992 |
| [33] | Wang K;Wang MQ;Si H;Xu TD .Critical time for non-equilibrium grain boundary segregation of phosphorus in 304L stainless steel[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2008(1/2):347-351. |
| [34] | Heo N H .Sulfur Segregation and Intergranular Fracture in a-Iron[J].Seripta Mater,2004,51(04):339. |
| [35] | Liu C M;Abiko K;Tanino M .Relation Between the Interg-ranular Segregation of S and the Hot Ductility in High Purity Fe-S Alloys[J].Acta Metallurgica Sinica,1999,12(04):637. |
| [36] | Karin Hansson;Mikhail Droujevski;Hasse Fredriksson .Hot ductility of an Fe-10 percent Ni alloy during penetration of copper[J].Scandinavian Journal of Metallurgy,2002(4):256-267. |
| [37] | Horikawa K;Kuramoto S;Kanno M .Intergranular Fracture Caused by Trace Impurities in an Al-5.5mol%Mg Alloy[J].Acta mater,2001,49(19):3981. |
| [38] | Hiroshi Okada;Motohiro Kanno .Hot ductility of Al-Mg and Al-Mg-Y alloys impaired by trace sodium[J].Scripta materialia,1997(6):781-786. |
| [39] | Lynch S P .Comments on"Intergranular Fracture Caused by Trace Impurities in an Al-5.5mol%A Mg Alloy"[J].Scripta Materialia,2002,47(02):125. |
| [40] | Powers A E .The Influence of Molybdenum and Tungsten onTemper Embrittlement[J].Transactions ASM,1956,48:149. |
| [41] | Bush S H;Siebert S A .Temper Embrittlement of 5140 Steel[J].Transactions AIME,1954,200:1269. |
| [42] | He LZ;Zheng Q;Sun XF;Hou GC;Guan HR;Hu ZQ .Low ductility at intermediate temperature of Ni-base superalloy M963[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2004(1/2):340-348. |
| [43] | Yasumoto K;Maehara Y;Ura S et al.Effects of Sulphur on Hot Ductility of Low-Carbon Steel Austenite[J].Materials Science and Technology,1985,1(02):111. |
| [44] | T. D. Xu .The critical time in temper embrittlement isotherms of phosphorus in steels[J].Journal of Materials Science,1999(13):3177-3180. |
| [45] | Zhang ZL.;Lin QG.;Yu ZS.;Xu TD. .A new interpretation of temper embrittlement dynamics by non-equilibrium segregation of phosphor in steels[J].Journal of Materials Science,2001(8):2055-2059. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%