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本文从团聚(clustering)的分子动力学过程出发,研究微尺度沸腾相变的物理机制.通过分析沸腾系统势能变化趋势,指出核化阶段必然伴随团聚体积的增加,从而导致压力扰动的产生.在微尺度条件下,这种压力扰动将可能主导沸腾系统的相变行为,由此导出相变发生的临界尺度判据,在量级上与实验取得很好的一致.

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