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甲基丙烯酸(2,4-二三氟甲基)十二氟戊酯(FA)接枝聚丙烯腈-丁二烯-苯乙烯(ABS)得到一种新型树脂,用红外光谱(FT-IR)和光电子能谱(XPS)证实了产物反应结合的结构。文中同时研究了产物的表面性能和热性能。结果表明,甲基丙烯酸(2,4-二三氟甲基)十二氟戊酯的加入量控制在6phr时,接枝率为11.8%,所得产物的表面能较ABS可以有明显降低,达到20×10-3J/m2左右,有极高的疏水、驱油和抗污染性能,而玻璃化转变温度(Tg)变化不明显。

A resin was prepared by 2,3,4,5,5,5-(2,4-ditrifluoromethyl) dodecafluoroamyl methacrylate(FA) grafted acrylonitrile-butadiene-styrene(ABS) resin.The structure of FA-g-ABS was characterized by Fourier transform infrared spectrum(FT-IR) and X-ray photoelectron spectroscopy(XPS).At the same time,the surface tensile,thermal properties of the grafted composite were studied.It is found that the surface tensile of FA-g-ABS,which reaches around 20×10-3(J/m2),is observably lower than of pure ABS when the FA concentration is controlled within 6phr(grafting degree=11.8%).There are also a great deal merits of the composite such as hydrophobic,oil displacement and antipollution ability. The glass transition temperature of grafted ABS has no obvious changing.

参考文献

[1] Park IJ.;Choi CK.;Kim KJ.;Lee SB. .SURFACE PROPERTIES AND STRUCTURE OF POLY(PERFLUOROALKYLETHYL METHACRYLATE)[J].Journal of Colloid and Interface Science,1996(1):284-288.
[2] Sharma SC;Acharya DP;Garcia-Roman M;Itami Y;Kunieda H .Phase behavior and surface tensions of amphiphilic fluorinated random copolymer aqueous solutions[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2006(1/3):140-145.
[3] Li GH;Shen YD;Ren QH .Effect of fluorinated acrylate on the surf ace properties of cationic fluorinated polyurethane-acrylate hybrid dispersions[J].Journal of Applied Polymer Science,2005(6):2192-2196.
[4] 闻荻江,杨杰.丙烯酸含氟酯改性不饱和聚酯树脂的研究[J].新型建筑材料,2008(04):34-36.
[5] 周乐宁,闻荻江.含氟化合物接枝ABS的研究[J].塑料工业,2008(11):5-7.
[6] 刘华卿,蒋凤池.核磁共振氢谱方法对红外光谱碳氟键伸缩振动变化的研究[J].光谱学与光谱分析,2007(11):2243-2245.
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