在综合分析无机模板法和有机模板法的基础上,提出矿物模板法和复合模板法是制备中孔炭的有效方法.矿物模板法原料价格低廉、来源广泛.复合模板法综合了软模板和硬模板的优点,能够拓展中孔炭的结构、性能和应用领域.以矿物模板制备的炭材料具有良好的电学、医学性能等,有望获得良好性价比的中孔炭材料.
参考文献
[1] | Patrick J W.Porosity in Carbons:Characterization and Applications[M].London:Edward Aronld,1995 |
[2] | 柳召永,郑经堂.溶胶-凝胶法制备中孔炭材料及其表征[J].炭素技术,2007(03):13-16. |
[3] | Scorgie K A;Phillips G J;Davies J G et al.Potential use of mesoporous activated carbons in CRRT[J].Blood Purification,2002,20(03):310. |
[4] | 李青,曾昌凤,张利雄,徐南平.模板法制备丰富中孔炭材料的研究进展[J].化工进展,2003(12):1269-1273. |
[5] | 宋怀河,李丽霞,陈晓红.有序介孔炭的模板合成进展[J].新型炭材料,2006(04):374-383. |
[6] | 李娜,王先友,易四勇,戴春岭.模板法制备中孔碳材料[J].化学进展,2008(07):1202-1207. |
[7] | 解强,张香兰,李兰廷,金雷.活性炭孔结构调节:理论、方法与实践[J].新型炭材料,2005(02):183-190. |
[8] | 乔文明,宋燕,尹圣昊,持田勲.通过再活化浸渍金属盐的活性炭来发展中孔结构[J].新型炭材料,2005(03):198-204. |
[9] | 孙新,查庆芳,郭燕生,李兆丰.石油焦系超级活性炭的孔结构控制[J].新型炭材料,2005(03):240-244. |
[10] | Ryoo R.;Kruk M.;Jaroniec M.;Joo SH. .Ordered mesoporous carbons[J].Advanced Materials,2001(9):677-681. |
[11] | Fuertes A B;Nevskaia D M .Control of mesoporous structure of carbons synthesized using mesostructured silica as template[J].Microporous and Mesoporous Materials,2003,62:177-190. |
[12] | Lu AH;Li WC;Schmidt W;Kiefer W;Schuth F .Easy synthesis of an ordered mesoporous carbon with a hexagonally packed tubular structure[J].Carbon: An International Journal Sponsored by the American Carbon Society,2004(14):2939-2948. |
[13] | Chengdu Liang;Zuojiang Li;Sheng Dai .Mesoporous Carbon Materials: Synthesis and Modification[J].Angewandte Chemie,2008(20):3696-3717. |
[14] | Kyotani T. .Control of pore structure in carbon[J].Carbon: An International Journal Sponsored by the American Carbon Society,2000(2):269-286. |
[15] | 周颖,姚七妹,孙宗伟,邱介山,郭洪臣.工艺过程及参数对模板法制备多孔炭结构的影响[C].第八届全国新型炭材料学术研讨会论文集,2007:193-197. |
[16] | Ryoo R;Joo S H;Jun S .Synthesis of highly ordered carbon molecular sieves via template-mediated structural transformation[J].Journal of Physical Chemistry B,1999,103:7743-7746. |
[17] | Knox J H;Gilbert M T .Preparation of Porous Carbon[P].US,4263268,1981. |
[18] | Knox J H;Unger K K;Mueller H .Prospects for carbon as packing material in high-performance liquid chromatography[J].Journal of Chromatography B:Analytical Technologies in the Biomedical and Life Sciences,1983,6:1-36. |
[19] | Knox J H;Kaur B;Millward G R .Structure and performance of porous graphitic carbon in liquid chromatograph[J].Journal of Chromatography B:Analytical Technologies in the Biomedical and Life Sciences,1986,352:3-25. |
[20] | Han S;Hyeon T .Novel silica-sol mediated synthesis of high surface area porous carbons[J].CARBO,1999,37:1645-1647. |
[21] | Sangjin Han;Taeghwan Hyeon .Simple silica-particle template synthesis of mesoporous carbons[J].Chemical communications,1999(19):1955-1956. |
[22] | Kawsshirua D;Ahara T;Kyotani T et al.Preparation of mesoporous carbon from organic polymer/silica nanocomposite[J].Chemistry of Materials,2000,12:3397-3401. |
[23] | Spange S.;Muller H.;Jager C.;Bellmann C. .Fabrication of carbon/silica hybrid materials using cationic polymerization and the sol-gel process[J].Macromolecular symposia,2002(0):111-124. |
[24] | Yu JS.;Chai GS.;Yoon SB. .Ordered uniform porous carbon by carbonization of sugars[J].Carbon: An International Journal Sponsored by the American Carbon Society,2001(9):1442-1446. |
[25] | Yu J S;Kang S;Yoon S;et a l .Fabrication ofordered uniform porous carbon networks and their application to a catalyst supporter[J].Journal of the American Chemical Society,2002,24(32):9382-9383. |
[26] | Lee Jinwoo;Yoon Songhun .Synthesis of a new mesoporous carbon and its application to electrochemical double-layer capacitors[J].Chemical communications,1999(21):2177-2178. |
[27] | Zuojiang Li;Wenfu Yan;Sheng Dai .Surface Functionalization of Ordered Mesoporous Carbons-A Comparative Study[J].Langmuir: The ACS Journal of Surfaces and Colloids,2005(25):11999-12006. |
[28] | Kresege C T;Leonowicz M E;Roth W.J et al.Ordered mesoporous molecular sieves synthesized by a liquid crystal tem plate mechanism[J].Nature,1992,359:710-712. |
[29] | Bozhi Tian;Shunai Che;Zheng Liu;Xiaoying Liu;Weibin Fan;Takashi Tatsumi;Osamu Terasaki;Dongyuan Zhao .Novel approaches to synthesize self-supported ultrathin carbon nanowire arrays templated by MCM-41[J].Chemical communications,2003(21):2726-2727. |
[30] | Zhao D Y;Feng J L;Huo Q S et al.Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 angstrom pores[J].Science,1998,279:548-552. |
[31] | Zhao DY.;Feng JL.;Chmelka BF.;Stucky GD.;Huo QS. .Nonionic triblock and star diblock copolymer and oligomeric surfactant syntheses of highly ordered, hydrothermally stable, mesoporous silica structures[J].Journal of the American Chemical Society,1998(24):6024-6036. |
[32] | Jun S.;Ryoo R.;Kruk M.;Jaroniec M.;Liu Z.;Ohsuna T. Terasaki O.;Joo SH. .Synthesis of new, nanoporous carbon with hexagonally ordered mesostructure[J].Journal of the American Chemical Society,2000(43):10712-10713. |
[33] | An-Hui Lu;Wolfgang Schmidt;Bernd Spliethoff;Ferdi Schuth .Synthesis of Ordered Mesoporous Carbon with Bimodal Pore System and High Pore Volume[J].Advanced Materials,2003(19):1602-1606. |
[34] | Seong-Su Kim;Thomas J.Pinnavaia .A low cost route to hexagonal mesostructured carbon molecular sieves[J].Chemical communications,2001(23):2418-2419. |
[35] | Lee J.;Oh SM.;Shin CH.;Hyeon T.;Yoon S. .Development of a new mesoporous carbon using an HMS aluminosilicate template[J].Advanced Materials,2000(5):359-362. |
[36] | Beck J S;Vartuli J C;Roth W J et al.A new family of mesoporous molecular sieves prepared with liquid crystal templates[J].Journal of the American Chemical Society,1992,114:10834-10843. |
[37] | Moriguchi I.;Mikuriya K.;Teraoka Y.;Kagawa S.;Kodama M.;Ozono A. .Micelle-templated mesophases of phenol-formaldehyde polymer[J].Chemistry Letters,1999(11):1171-1172. |
[38] | Zuojiang Li;Wenfu Yan;Sheng Dai .A novel vesicular carbon synthesized using amphiphilic carbonaceous material and micelle templating approach[J].Carbon: An International Journal Sponsored by the American Carbon Society,2004(4):767-770. |
[39] | Meng Y;Gu D;Zhang FQ;Shi YF;Cheng L;Feng D;Wu ZX;Chen ZX;Wan Y;Stein A .A family of highly ordered mesoporous polymer resin and carbon structures from organic-organic self-assembly[J].Chemistry of Materials: A Publication of the American Chemistry Society,2006(18):4447-4464. |
[40] | Chengdu Liang;Kunlun Hong;Jimmy W.Ma .Synthesis of a Large-Scale Highly Ordered Porous Carbon Film by Self-Assembly of Block Copolymers[J].Angewandte Chemie,2004(43):5785-5789. |
[41] | Kosonen H;Yakama S;Nykanen A et al.Functional porous structures based on the pyrolysis of cured templates of block copolymer and phenolic resin[J].Advanced Materials,2006,18:201. |
[42] | Shunsuke Tanaka;Norikazu Nishiyama;Yasuyuki Egashira;Korekazu Ueyama .Synthesis of ordered mesoporous carbons with channel structure from an organic-organic nanocomposite[J].Chemical communications,2005(16):2125-2127. |
[43] | Dai S;Guiochon G A;Liang C D .Robust carbon monolith having hierarchical porosity[P].US Patent 7449165,2008-11 -11. |
[44] | Chengdu Liang;Sheng Dai .Synthesis of Mesoporous Carbon Materials via Enhanced Hydrogen-Bonding Interaction[J].Journal of the American Chemical Society,2006(16):5316-5317. |
[45] | Fuqiang Zhang;Yan Meng;Dong Gu;Yan Yan;Chengzhong Yu;Bo Tu;Dongyuan Zhao .A Facile Aqueous Route to Synthesize Highly Ordered Mesoporous Polymers and Carbon Frameworks with Ia3d Bicontinuous Cubic Structure[J].Journal of the American Chemical Society,2005(39):13508-13509. |
[46] | Yan Meng;Dong Gu;Fuqiang Zhang;Yifeng Shi;Haifeng Yang;Zheng Li;Chengzhong Yu;Bo Tu;Dongyuan Zhao .Ordered Mesoporous Polymers and Homologous Carbon Frameworks:Amphiphilic Surfactant Templating and Direct Transformation[J].Angewandte Chemie,2005(43):7053-7059. |
[47] | Zhang FQ;Meng Y;Gu D;Yan Y;Chen ZX;Tu B;Zhao DY .An aqueous cooperative assembly route to synthesize ordered mesoporous carbons with controlled structures and morphology[J].Chemistry of Materials: A Publication of the American Chemistry Society,2006(22):5279-5288. |
[48] | Lin, HP;Chang-Chien, CY;Tang, CY;Lin, CY .Synthesis of p6mm hexagonal mesoporous carbons and silicas using Pluronic F127-PF resin polymer blends[J].Microporous and Mesoporous Materials,2006(1/3):344-348. |
[49] | Geun Seok Chai;In Sun Shin;Jong-Sung Yu .Synthesis of Ordered, Uniform, Macroporous Carbons with Mesoporous Walls Templated by Aggregates of Polystyrene Spheres and Silica Particles for Use as Catalyst Supports in Direct Methanol Fuel Cells[J].Advanced Materials,2004(22):2057-2061. |
[50] | Deng YH;Yu T;Wan Y;Shi YF;Meng Y;Gu D;Zhang LJ;Huang Y;Liu C;Wu XJ .Ordered mesoporous silicas and carbons with large accessible pores templated from amphiphilic diblock copolymer poly(ethylene oxide)-b-polystyrene[J].Journal of the American Chemical Society,2007(6):1690-1697. |
[51] | Adrian T.Rodriguez;Min Chen;Zhu Chen .Nanoporous Carbon Nanotubes Synthesized through Confined Hydrogen-Bonding Self-Assembly[J].Journal of the American Chemical Society,2006(29):9276-9277. |
[52] | Kyotani T;Tsai L F;Tomita A .Formation of ultrafine carbon tubes by using an anodic aluminum oxide film as a template[J].Chemistry of Materials,1995,7:1427-1428. |
[53] | Takashi Kyotani;Li-fu Tsai;Akira Tomita .Preparation of Ultrafine Carbon Tubes in Nanochannels of an Anodic Aluminum Oxide Film[J].Chemistry of Materials,1996(8):2109-2113. |
[54] | Zheng M B;Cao J M;Ke X F et al.One-step-synthesis of new mesoporous carbon nanofiberrs through an easy template method[J].CARBO,2007,45:1111-1113. |
[55] | Wang K X;Gavels Birjukovs;Donats Erts et al.Synthesis and characterization of ordered arrays of mesoporous carbon nanofibres[J].Chemistry of Materials,2009,19:1331-1338. |
[56] | Martin Steinhart;Chengdu Liang;Gary W. Lynn .Direct Synthesis of Mesoporous Carbon Microwires and Nanowires[J].Chemistry of Materials: A Publication of the American Chemistry Society,2007(10):2383-2385. |
[57] | Rong Kou;Qingyuan Hu;Donghai Wang;Vijay T. John;Zhenzhong Yang;Yunfeng Lu .Direct synthesis of ordered mesoporous polymer/carbon nanofilaments with controlled mesostructures[J].Journal of porous materials,2009(3):315-319. |
[58] | Hai-Jing Liu;Xiao-Ming Wang;Wang-Jun Cui .Highly ordered mesoporous carbon nanofiber arrays from a crab shell biological template and its application in supercapacitors and fuel cells[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2010(20):4223-4230. |
[59] | Kyotani T;Sonobe N;Tomita A .Formation of highly orientated graphite from polyacrylonitrile by using a two-dimensional space between montmorillonite larnellae[J].Nature,1988,331:331-333. |
[60] | Sonobe N;Kyotani T;Tomita A .Carbonization of polyacrylonitrile in a two dimensional space between montmorillonite lamellae[J].CARBO,1988,26:573-578. |
[61] | Sonobe N;Kyotani T;Hishiyama Y et al.Formation of highly oriented graphite from poly (acrylonitrile) prepared between the lamellae of montmorillonite[J].Journal of Physical Chemistry,1988,92:7029-7034. |
[62] | Sandí G;Thiyagarajan P;Carrado K A et al.Small angle neutron scattering characterization of the porous structure of carbons prepared using inorganic templates[J].Chemistry of Materials,1999,11:235-240. |
[63] | Sandí G;Carrado K A;Winans R E et al.Designer carbons templated by pillared clays lithium secondary battery anodes[J].Microporous Macroporous Mater,1996,431:39-44. |
[64] | A.Bakandritsos;Th.Steriotis;D.Petridis .High Surface Area Montmorillonite-Carbon Composites and Derived Carbons[J].Chemistry of Materials,2004(8):1551-1559. |
[65] | Nguyen-Thanh, D;Bandosz, TJ .Metal-loaded carbonaceous adsorbents templated from porous clay heterostructures[J].Microporous and Mesoporous Materials,2006(1/3):47-55. |
[66] | Lingmin Shi;Jianfeng Yao;Jinlong Jiang .Preparation of mesopore-rich carbons using attapulgite as templates and furfuryl alcohol as carbon source through a vapor deposition polymerization method[J].Microporous and mesoporous materials: The offical journal of the International Zeolite Association,2009(1/3):294-300. |
[67] | Sakintuna, B;Yurum, Y .Preparation and characterization of mesoporous carbons using a Turkish natural zeolitic template/furfuryl alcohol system[J].Microporous and Mesoporous Materials,2006(1/3):304-312. |
[68] | Liu GY;Kang FY;Li BH;Huang ZH;Chuan XY .Characterization of the porous carbon prepared by using halloysite as template and its application to EDLC[J].The journal of physics and chemistry of solids,2006(5/6):1186-1189. |
[69] | Ai-ping Wang;Feiyu Kang;Zheng-Hong Huang;Zhancheng Guo .PREPARATION OF POROUS CARBONS FROM HALLOYSITE-SUCROSE MIXTURES[J].Clays and clay minerals,2006(4):485-490. |
[70] | Aiping Wang;Feiyu Kang;Zhenghong Huang .Synthesis of mesoporous carbon nanosheets using tubular halloysite and furfuryl alcohol by a template-like method[J].Microporous and Mesoporous Materials,2008(1/3):318-324. |
[71] | Tong Y;Liu C;Hou P X et al.Field emission from aligned multi-walled carbon nanotubes[J].Physica B:Condensed Matter,2002,323(1-4):156-157. |
[72] | Dresselhaus M S;Dresselhaus G.The Physics of FullereneBased and Fullerene Related Materials[M].Dordrecht,the Netherlands:Kluwer Academic Publishers,2000:331-379. |
[73] | Iijima S .Helical microtubules ofgraphitic carbon[J].Nature,1991,354:56-58. |
[74] | Chuan X Y;Zheng Z;Chen J.Microsttrcture of natural carbon nanotube in diamond mine[A].Spanish carbon so ciety,2003:169. |
[75] | Erik T. Thostenson;Zhifeng Ren;Tsu-Wei Chou .Advances in the science and technology of carbon nanotubes and their composites: a review[J].Composites science and technology,2001(13):1899-1912. |
[76] | Qiu J S;Zhou Y;Zhang H B et al.Preparation and purification of fullerenes from metallurgical coke[J].Huagong Xuebao (Chin Ed ),1997,48(02):252-256. |
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