为了研究LF-VD精炼工艺的脱硫效果,进行了9炉工业试验。通过对BOF-LF-VD和KR-BOF-LF-VD工艺冶炼中厚板钢中硫含量和炉渣成分的分析,研究了炉渣成分和工艺参数对脱硫的影响。结果表明,采用适宜的精炼渣系,通过LF-VD精炼能把钢中硫质量分数从转炉终点200×10-6左右脱至20×10-6以下;炉渣成分w((MgO))=4%~7%、w((SiO2))=7%~11%、w((CaO))/[w((Al2O3))+w((SiO2))]=1.62时,实现最高硫分配比接近500;VD精炼比LF精炼钢液搅拌强烈,能进一步脱硫。研究结果对优化中厚板炉外精炼脱硫工艺具有指导意义。
Nine heats of industrial trials were performed to investigate the desulfurization effectiveness of LF-VD refining process. The influence of slag composition and operating parameters on desulfurization was studied by analysis of sulfur content in steel and slag composition during production of plate steel by BOF-LF-VD and KR-BOF-LF-VD process. The results show that mass percent of sulfur in steel can be decreased to below 20×10-6 from 200×10-6 at the end of BOF re-fining with suitable refining slag. The highest sulfur distribution close to 500 can be achieved with w((MgO))=4%-7%、w((SiO2))=7%-11%,w((CaO))/[w((Al2O3))+w((SiO2))]=1.62 slag. VD refining can realize further desulfurization than LF refining because of better molten steel bath stirring.The present results are considered to be useful in optimizing secondary refining desulfurization process during plate steel production.
参考文献
[1] | Ye G Z;Jonsson P;Lund T .Thermodynamics and Kinetics of the Modification of Al2O3 Inclusions[J].ISIJ International,1996,36(S):S105. |
[2] | Holappa L;Hamalainen M;Liukkonen M et al.Thermodynam-ic Examination on Inclusion Modification and Precipitation From Calcium Treatment to Solidified Steel[J].Ironmaking and Steelmaking,2003,30(02):111. |
[3] | S. K. CHOUDHARY;A. GHOSH .Thermodynamic Evaluation of Formation of Oxide-Sulfide Duplex Inclusions in Steel[J].ISIJ International,2008(11):1552-1559. |
[4] | 王郢,郭佳,杨文,景财良,王新华.齿轮钢20CrMoH脱硫的热力学研究[J].钢铁,2009(01):36-39. |
[5] | 李太全,包燕平,吴华杰,刘建华.高级别管线钢超低硫控制研究[J].钢铁,2009(05):35-38. |
[6] | H. Lachmund;Y. Xie .High purity steels: a challenge to improved steelmaking processes[J].Ironmaking & Steelmaking: Products and applications,2003(2):125-129. |
[7] | Richardson F D;Fincham C J B .Sulphur in Silicate and Alumi-nate Slags[J].J Iron Steel Inst,1954,178(09):4. |
[8] | Nzotta M M;Du S C;Seetharaman M .A Study of the Sulfide Capacities of Iron-Oxide Containing Slags[J].Metall Mater Trans:B,1990,30:909. |
[9] | 郝宁,王新华,刘金刚,王文军.MgO含量对CaO-Al2O3-SiO2-MgO精炼渣脱硫能力的影响[J].炼钢,2009(04):16-19. |
[10] | Ban-Ya S;Hobo M;Kaji T;Itoh T;Hino M .Sulphide capacity and sulphur solubility in CaO-Al2O3 and CaO-Al2O3-CaF2 slags[J].ISIJ International,2004(11):1810-1816. |
[11] | 王郢,王新华,周红霞,郭佳,王万军.超低氧弹簧钢硫容量计算及硫脱除分析[J].北京科技大学学报,2008(09):986-992. |
[12] | 郝宁,王海涛,王新华,李宏,王万军.硫容量和硫分配比的计算及分析[J].北京科技大学学报,2006(01):25-28. |
[13] | 李京社,唐海燕,孙开明,温德松.硫容量模型和在五元渣系CaO-SiO2-MgO-Al2O3-FetO中的应用[J].钢铁研究学报,2009(02):9-12,22. |
[14] | Margareta A.T. .Application of the Sulphide Capacity Concept on High-basicityLadle Slags Used in Bearing-Steel Production[J].ISIJ International,1999(11):1140-1149. |
[15] | Lachmund H;Xie Y K;Harste K .Thermodynamic and Kinetic Aspects of the Desulphurisation Reaction in Secondary Metallur-gy[J].Steel Research,2001,72(11+12):452. |
[16] | Patsiogiannis F;Pal U B;Bogan R S .Kinetic Studies on the Desul-furization of Aluminum Killed Low Carbon Steel Using Synthetic Fluxex[J].Canadian Metallurgical Quarterly,1994,33(04):305. |
[17] | Lachmund H;Xie Y K;Buhles T et al.Slag Emulsification Dur-ing Liquid Steel Desulphurization by Gas Injection Into the La-dle[J].Steel Research,2003,74(02):77. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%