综述了锂离子电池正极材料热稳定性的研究现状及其进展.针对正极材料LiCoO2、LiNiO2、LiMn2O4及其衍生物的热稳定性,众多研究者提出了不同的反应机理,认为正极材料的热稳定性与颗粒大小、晶体结构、充/放电状态、脱锂程度及电解质性质等因素有关.可以利用掺杂技术、涂层技术及优化合成条件等手段来改善正极材料的热稳定性.
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