以正钛酸为原料,通过直接水解法制备纳米TiO2;并对样品分别进行了差热分析、X射线衍射分析和透射电子显微镜分析.结果表明,样品粒子为混晶型纳米TiO2,单分散性良好,粒径分布范围狭窄.当它应用于阴离子表面活性剂十二烷基苯磺酸钠的光催化降解时,与P-25光催化剂相比,具有较好的催化活性.同时,我们用Al2O3陶瓷膜回收纳米TiO2循环再利用;这为纳米TiO2在环保方面的大规模应用创造了条件.
Nanosized TiO2 particles were prepared by using the direct hydrolysis means from metatitanic acid. The specimens were characterized by transmission electron microscopy (TEM), X-ray diffractometry, differential thermal analysis. Nanosized TiO2 of mixing anatase and rutile prepared was found to show good photocatalytic properties in the photodegredation of anionic sodium dodecylbenzensulfonate surfactant, compared with P-25.
参考文献
[1] | Haro-Paniatowski E, et al. J. Mater. Res., l994, 9 (8): 2102--2108. [2] Gamboa J A, Pasquevich D M. J. Am. Ceram. Soc., 1992, 75 (11): 2934--2938. [3] Deo G, Turek A M, Wachs I E, et al. Appl. Cata1. A: 1992, 91: 27--42. [4] Matthews R W. J. Catal., 1988, 113: 549--555. [5] Turchi C S, Ollis D P. J. Catal., 1990, 122: 187--192. [6] Hidaka H, Nohara K, Serpone J, et al. J. Photochem. Phototbiol. A: Chem., 1992, 64, 247--254. [7] Hidaka H, Nakamura T, Ishizaka A, et al. J. Photochem. Phototbiol. A: Chem., 1992, 66: 367--374. [8] 高荣杰, 等. 金属学报, 1996, 32 (10): 1097--1101. [9] Eastman J A. Appl. Phys., 1994, 75 (2): 770--779. [10] Hidaka H, Zhao J, Pelizzetti E, et al. J. Phys. Chem., 1992, 96: 2226--2230. [11] Takamura A, Pelizzetti E, Hidaka H, et al. Langmuir, 1993, 9 (7): 1646--1650. [12] Hoffmann M R, Martin S T, Bahnemann D W. Chem. Rev., 1995, 95 (1): 69--95. |
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