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通过氧化-沉淀法合成了具有光催化活性的α-FeO(OH)纳米棒,用TGA、SEM、BET等分析方法进行结构表征和性能测试,并对其降解偶氮类染料的性能进行了研究.结果表明,产物主要成分为针铁矿α-FeO(OH),另含有少量Fe3O4;产物长径比较高,比表面积为32.89m2/g,并具有优良的磁性能.在作为光催化剂降解偶氮类染料甲基橙的实验中,α-FeO(OH)纳米棒表现出较好的催化效果.在21W、50W模拟光源和自然光照下降解3h以上,其脱色率分别为29.8%、43.5%和76.4%.

参考文献

[1] 郭学军,陈甫华.载铁(β-FeOOH)球形棉纤维素吸附剂去除地下水As(Ⅴ)的研究[J].环境科学,2005(03):66-72.
[2] 姜利荣,赵超,黄应平,李瑞萍.可见光照射下α-FeOOH光催化降解有机污染物的研究[J].环境化学,2007(04):434-438.
[3] 周迟骏,任小英.FeO(OH)胶体加载微生物絮凝剂及其脱色特性[J].化工进展,2004(12):1331-1334.
[4] Christensen A N;Jensen T R;Christian R H Bahl et al.Nano size crystals of goethite,α-FeOOH:Synthesis and thermal transformation[J].Journal of Solid State Chemistry,2007,180:1431.
[5] 熊慧欣,周立祥.不同晶型羟基氧化铁(FeOOH)的形成及其在吸附去除Cr(Ⅵ)上的作用[J].岩石矿物学杂志,2008(06):559-566.
[6] Jing Lei;Chengshuai Liu;Fangbai Li;Xiaomin Li;Shungui Zhou;Tongxu Liu;Minghua Gu;Qitang Wu .Photodegradation of orange I in the heterogeneous iron oxide-oxalate complex system under UVA irradiation[J].Journal of hazardous materials,2006(2):1016-1024.
[7] Mariana Neamtu;Ayfer Yediler;Ilie Siminiceanu;Antonius Kettrup .Oxidation of commercial reactive azo dye aqueous solutions by the photo-Fenton and Fenton-like processes[J].Journal of Photochemistry and Photobiology, A. Chemistry,2003(1):87-93.
[8] Krehula S;Popovic S;Music S .Synthesis of acicular α-FeOOH particles at a very high pH[J].Materials Letters,2002,54(2-3):108.
[9] Song L;Zhang S .Formation of α-Fe2O3/FeOOH nanostructures with various morphologies by a hydrothermal route and their photocatalytic properties[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2009,348(1-3):217.
[10] Ou P;Xu G;Ren Z et al.Hydrothermal synthesis and characterization of uniform α-FeOOH nanowires in high yield[J].Materials Letters,2008,62(6-7):914.
[11] 雷静,李芳柏,刘承帅,顾明华,吴启堂.γ-FeOOH-草酸系统中橙黄Ⅰ的光化学脱色[J].环境科学学报,2005(10):1385-1390.
[12] Patrick Mazellier;Barbara Sulzberger .Diuron degradation in irradiated, heterogeneous iron/oxalate systems: the rate-determining step[J].Environmental Science & Technology: ES&T,2001(16):3314-3320.
[13] 吴吉权,孙振亚,蒋蓉,于红,余建洋.自然光下羟基氧化铁处理水溶液中甲基橙的研究[J].矿物岩石地球化学通报,2006(04):299-303.
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