欢迎登录材料期刊网

材料期刊网

中国科学院金属研究所 科学出版社
高级检索
  1. 首页
  2. 期刊
  3. 材料导报
  4. 块体金属玻璃由脆变塑的内生复合技术

材料导报, 2013, 27(1): 7-12.

块体金属玻璃由脆变塑的内生复合技术

高度 1, , 陈光 2, , 成家林 3,

1.南京理工大学材料评价与设计教育部工程研究中心,南京210094

2.南京理工大学材料评价与设计教育部工程研究中心,南京210094

3.南京理工大学材料评价与设计教育部工程研究中心,南京210094

基金项目:   国家自然科学基金(50871054)  

关键词： 块体金属玻璃 , 内生复合 , 半固态顺序凝固 , 拉伸塑性

The Development of In Situ Technology for Bulk Metallic Glass from Brittleness to Ductility

针对块体金属玻璃(BMG)的室温脆性问题,结合内生复合技术的发展历程,全面阐述内生相及其形貌、尺寸、制备工艺等因素对力学性能的影响.对块体金属玻璃历经压缩小尺寸试样拉伸－大尺寸试样拉伸,逐步由脆向塑发展.指出半固态顺序凝固(SSPS)是获得大尺度、无缺陷、具有显著拉伸塑性的BMG内生复合材料的有效手段.

参考文献

[1] Klement W;Willens R H;Duwez P .Metallurgy non-crystalline structure in solidified gold-silicon alloys[J].Nature,1960,187(4740):869.
[2] William L. Johnson .Bulk Glass-Forming Metallic alloys: Science and Technology[J].MRS bulletin,1999(10):42-56.
[3] A.Inoue .Stabilization of metallic supercooled liquid and bulk amorphous alloys[J].Acta materialia,2000(1):279-306.
[4] Ashby M F;Greer A L .Metallic glasses as structural materials[J].Scripta Materialia,2006,54(03):321.
[5] Christopher A. Schuh;Todd C. Hufnagel;Upadrasta Ramamurty .Mechanical behavior of amorphous alloys[J].Acta materialia,2007(12):4067-4109.
[6] A. Lindsay Greer .Metallic glasses ... on the threshold[J].Materials Today,2009(1/2):14-22.
[7] Z.F. Zhang;J. Eckert;L. Schultz .Difference in compressive and tensile fracture mechanisms of Zr_(59)Cu_(20)Al_(10)Ni_8Ti_3 bulk metallic glass[J].Acta materialia,2003(4):1167-1179.
[8] J. Eckert;J. Das;S. Pauly .Mechanical properties of bulk metallic glasses and composites[J].Journal of Materials Research,2007(2):285-301.
[9] Wu FF;Zhang ZF;Mao SX;Peker A;Eckert J .Effect of annealing on the mechanical properties and fracture mechanisms of a Zr56.2Ti13.8Nb5.0Cu6.9Ni5.6Be12.5 bulk-metallic-glass composite[J].Physical review, B. Condensed matter and materials physics,2007(13):4201-1-4201-11-0.
[10] G. Chen;H. Bei;Y. Cao;A. Gali;C. T. Liu;E. P. George .Enhanced plasticity in a Zr-based bulk metallic glass composite with in situ formed intermetallic phases[J].Applied physics letters,2009(8):081908-1-081908-3.
[11] J.L. Cheng;G. Chen;F. Xu;Y.L. Du;Y.S. Li;C.T. Liu .Correlation of the microstructure and mechanical properties of Zr-based in-situ bulk metallic glass matrix composites[J].Intermetallics,2010(12):2425-2430.
[12] Jiang F;Chen G;Li W L et al.Thermal stability,glassformation ability,and mechanical properties of (Zr41.2 Ti13.8-Cu12.5Ni10Be22.5)100-xNbx amorphous alloys[J].Metallurgical and Materials Transactions A:Physical Metallurgy and Materials Science,2008,39(08):1812.
[13] J.L. Cheng;G. Chen;P. Gao .The critical cooling rate and microstructure evolution of Zr_(41.2)Ti_(13.8)Cu_(12.5)Ni_(10)Be_(22.5) composites by Bridgman solidification[J].Intermetallics,2010(1):115-118.
[14] 王志华,陈光,姜斐,杜宇雷,陈国良.体积分数对Wf/Zr基非晶复合材料准静态压缩特性的影响[J].稀有金属材料与工程,2006(10):1568-1571.
[15] R.D.Conner;R.B.Dandliker;W.L.Johnson .Mechanical properties of tungsten and steel fiber reinforced Zr-41.25Ti_13.75Cu_12.5Ni_10Be_22.5 metallic glass matrix composites[J].Acta materialia,1998(17):6089-6102.
[16] Y. Sun;H. F. Zhang;A. M. Wang;H. M. Fu;Z. Q. Hu;C. E. Wen;P. D. Hodgson .Mg-based metallic glass/titanium interpenetrating phase composite with high mechanical performance[J].Applied physics letters,2009(17):171910-1-171910-3.
[17] X. Hui;W. Dong;G.L. Chen .Formation, microstructure and properties of long-period order structure reinforced Mg-based bulk metallic glass composites[J].Acta materialia,2007(3):907-920.
[18] Li J Q;Wang L;Zhang H F et al.Synthesis and characterization of particulate reinforced Mg-based bulk metallic glass composites[J].Materials Letters,2007,61(11-12):2217.
[19] Jang JSC;Ciou JY;Hung TH;Huang JC;Du XH .Enhanced mechanical performance of Mg metallic glass with porous Mo particles[J].Applied physics letters,2008(1):11930-1-11930-3-0.
[20] Tan H;Zhang Y;Li Y .Synthesis of La based in situ bulk metallic glass matrix composite[J].Intermetallics,2002,10(11-12):1203.
[21] M.L. Lee;Y. Li;C.A. Schuh .Effect of a controlled volume fraction of dendritic phases on tensile and compressive ductility in La-based metallic glass matrix composites[J].Acta materialia,2004(14):4121-4131.
[22] Y. Zhang;W. Xu;H. Tan .Microstructure control and ductility improvement of La-Al-(Cu, Ni) composites by Bridgman solidification[J].Acta materialia,2005(9):2607-2616.
[23] Shantanu V. Madge;Parmanand Sharma;Dmitri V. Louzguine-Luzgin .New La-based glass-crystal ex situ composites with enhanced toughness[J].Scripta materialia,2010(4):210-213.
[24] Zan Bian;Hidemi Kato;ChunLing Qin .Cu-Hf-Ti-Ag-Ta bulk metallic glass composites and their properties[J].Acta materialia,2005(7):2037-2048.
[25] J.W. Qiao;A.C. Sun;E.W. Huang .Tensile deformation micromechanisms for bulk metallic glass matrix composites: From work-hardening to softening[J].Acta materialia,2011(10):4126-4137.
[26] Hofmann, DC;Suh, JY;Wiest, A;Lind, ML;Demetriou, MD;Johnson, WL .Development of tough, low-density titanium-based bulk metallic glass matrix composites with tensile ductility[J].Proceedings of the National Academy of Sciences of the United States of America,2008(51):20136-20140.
[27] X. Hu;S. C. Ng;Y. P. Feng;Y. li .Glass forming ability and in-situ composite formation in Pd-based bulk metallic glasses[J].Acta materialia,2003(2):561-572.
[28] S.F. Guo;L. Liu;N. Li .Fe-based bulk metallic glass matrix composite with large plasticity[J].Scripta materialia,2010(6):329-332.
[29] Choi-Yim H;Johnson WL .Bulk metallic glass matrix composites[J].Applied physics letters,1997(26):3808-3810.
[30] Kato H;Inoue A .Synthesis and mechanical properties of bulk amorphous Zr-A1-Ni-Cu alloys containing ZrC particles[J].Materials Transactions-Japan Institute of Metals,1997,38(09):793.
[31] H. CHOI-YIM;R. BUSCH;U. KOSTFR;W. L. JOHNSON .SYNTHESIS AND CHARACTERIZATION OF PARTICULATE REINFORCED Zr57Nb5Al10Cu15.4Ni12.6 BULK METALLIC GLASS COMPOSITES[J].Acta materialia,1999(8):2455-2462.
[32] Choi Yim H;Conner R D;Szuecs F et al.Quasistatic and dynamic deformation of tungsten reinforced Zr57Nb5Al10Cu15.1Ni12.6 bulk metallic glass matrix composites[J].Scripta Materialia,2001,45(09):1039.
[33] Haein Choi-Yim;Jan Schroers;William L. Johnson .Microstructures and mechanical properties of tungsten wire/particle reinforced Zr_(57)Nb_(5)Al_(10)Cu_(15.4)Ni_(12.6) metallic glass matrix composites[J].Applied physics letters,2002(11):1906-1908.
[34] Dandliker R B;Conner R D;Johnson W L .Melt infiltration casting of bulk metallic-glass matrix composites[J].Journal of Materials Research,1998,13(10):2896.
[35] C. P. Kim;R. Busch;A. Masuhr;H. Choi-Yim;W. L. Johnson .Processing of carbon-fiber-reinforced Zr_(41.2)Ti_(13.8)Cu_(12.5)Ni_(10.0)Be_(22.5) bulk metallic glass composites[J].Applied physics letters,2001(10):1456-1458.
[36] Bian Z;Pan M X;Zhang Y et al.Carbon-nanotube-reinforced Zr52.5Cu17.9Ni11.6Al10Ti5 bulk metallic glass composites[J].Applied Physics Letters,2002,81(25):4739.
[37] K.Q. Qiu;A.M. Wang;H.F. Zhang .Mechanical properties of tungsten fiber reinforced ZrAlNiCuSi metallic glass matrix composite[J].Intermetallics,2002(11/12):1283-1288.
[38] Wang G;Chen DM;Shen J;Stachurski ZH;Qin QH;Sun JF;Zhou BD .Deformation behaviors of a tungsten-wire/bulk metallic glass matrix composite in a wide strain rate range[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2006(36/37):3872-3878.
[39] Wadhwa P;Heinrich J;Busch R .Synthesis and characterization of copper fiber reinforced Zr41.2Ti13.8Cu12.5Ni10.0Be22.5 bulk metallic glass[J].Journal of Alloys and Compounds,2007,434-435:259.
[40] Zhang H;Zhang ZF;Wang ZG;Zhang HF .Deformation and damage evolution of tungsten fiber reinforced metallic glass matrix composite induced by compression[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2008(0):164-167.
[41] 张兴超;陈晓华;张勇 等.超高强度及塑性的钨丝增强Zr-TiCuNiBeNb金属玻璃复合材料[J].稀有金属材料与工程,2008,37(z4):786.
[42] Lee K;Son C Y;Lee S B et al.Direct observation of microfracture process in metallic-continuous fiber-reinforced amorphous matrix composites fabricated by liquid pressing process[J].Materials Science and Engineering A:Structural Materials Properties Microstructure and Processing,2010,527(4-5):941.
[43] S.T. Deng;H. Diao;Y.L. Chen .Metallic glass fiber-reinforced Zr-based bulk metallic glass[J].Scripta materialia,2011(1):85-88.
[44] 邵长星,才鸿年,王鲁,程焕武,张海峰,王爱民.钨骨架/Zr基非晶复合材料准静态断裂特征研究[J].兵器材料科学与工程,2006(03):1-3.
[45] 兰山,王鲁,程焕武,才鸿年,张海峰,王爱民.W骨架/Zr基非晶合金复合材料动态力学特性研究[J].兵器材料科学与工程,2006(03):7-10.
[46] Li, H;Subhash, G;Kecskes, LJ;Dowding, RJ .Mechanical behavior of tungsten preform reinforced bulk metallic glass composites[J].Materials Science & Engineering. A, Structural Materials: Properties, Microstructure and Processing,2005(1-2):134-143.
[47] Hays CC.;Johnson WL.;Kim CP. .Microstructure controlled shear band pattern formation and enhanced plasticity of bulk metallic glasses containing in situ formed ductile phase dendrite dispersions[J].Physical review letters,2000(13):2901-2904.
[48] F. SZUECS;C.P. KIM;W.L. JOHNSON .MECHANICAL PROPERTIES OF Zr_56.2Ti_13.8Nb_5.0Cu_6.9Ni_5.6Be_12.5 DUCTILE PHASE REINFORCED BULK METALLIC GLASS COMPOSITE[J].Acta materialia,2001(9):1507-1513.
[49] G.Y. Sun;G. Chen;C.T. Liu .Innovative processing and property improvement of metallic glass based composites[J].Scripta materialia,2006(4):375-378.
[50] Hofmann DC;Suh JY;Wiest A;Duan G;Lind ML;Demetriou MD;Johnson WL .Designing metallic glass matrix composites with high toughness and tensile ductility.[J].Nature,2008(7182):1085-1089.
[51] Fan C;Li C F;Inoue A et al.Deformation behavior of Zr-based bulk nanocrystalline amorphous alloys[J].Physical Review B:Condensed Matter,2000,61(06):R3761.
[52] Leonhard A;Xing L Q;Heilmaier M et al.Effect of crys ralline precipitations on the mechanical behavior of bulk glass forming Zr-based alloys[J].Nano-Structured Materials,1998,10(05):805.
[53] Stawovy M T;Aning A O .Processing of amorphous Fe-W reinforced Fe matrix composites[J].Materials Science and Engineering A:Structural Materials Properties Microstructure and Processing,1998,256(1-2):138.
[54] M. H. Lee;J. -H. Kim;J. S. Park;J. C. Kim;W. T. Kim;D. H. Kim .Fabrication of Ni–Nb–Ta metallic glass reinforced Al-based alloy matrix composites by infiltration casting process[J].Scripta materialia,2004(11):1367-1371.
[55] Yu P;Kim KB;Das J;Baier F;Xu W;Eckert J .Fabrication and mechanical properties of Ni-Nb metallic glass particle-reinforced Al-based metal matrix composite[J].Scripta materialia,2006(8):1445-1450.
[56] Zhihui Zhang;Bing Q. Han;David Witkin .Synthesis of Nanocrystalline Aluminum Matrix Composites Reinforced with In Situ Devitrified Al-Ni-La Amorphous Particles[J].Scripta materialia,2006(5):869-874.
[57] M. Calin;J. Eckert;L. Schultz .Improved mechanical behavior of Cu-Ti-based bulk metallic glass by in situ formation of nanoscale precipitates[J].Scripta materialia,2003(6):653-658.
[58] 陈光;成家林 .具有拉伸塑性的大尺寸金属玻璃复合材料及其制备方法[OL].http://211.157.104.87:8080/sipo/zljs/hyjs-jieguo.jsp,2012-03-21.
[59] Xing L Q;Eckert J;L(o)ser W et al.High-strength materials produced by precipitation of icosahedral quasicrystals in bulk Zr-Ti-Cu-Ni-A1 amorphous alloys[J].Applied Physics Letters,1999,74(05):664.
[60] Cang Fan;Akira Takeuchi;Akihisa Inoue .Preparation and mechanical properties of Zr-based bulk nanocrystalline alloys containing compound and amorphous phases[J].Materials transactions,1999(1):42-51.
[61] Cang Fan;Dmitri V. Louzguine;Chunfei Li .Nanocrystalline composites with high strength obtained in Zr-Ti-Ni-Cu-Al bulk amorphous alloys[J].Applied physics letters,1999(3):340-342.
[62] Dong W B;Zhang H F;Cai J et al.Enhanced plasticity in a Zr-based bulk metallic glass containing nanocrystalline pre cipitates[J].Journal of Alloys and Compounds,2006,425(1-2):L1.
[63] J. B. Qiang;W. Zhang;G. Q. Xie;A. Inoue .Unusual room temperature ductility of a Zr-based bulk metallic glass containing nanoparticles[J].Applied physics letters,2007(23):231907-1-231907-3-0.
[64] H. BEI;Z.P. LU;S. SHIM .Specimen Size Effects on Zr-Based Bulk Metallic Glasses Investigated by Uniaxial Compression and Spherical Nanoindentation[J].Metallurgical and Materials Transactions, A. Physical Metallurgy and Materials Science,2010(7):1735-1742.
[65] Bulk Metallic Glass Composites with Transformation-Mediated Work-Hardening and Ductility[J].Advanced Materials,2010(25):2770-773,2725.
[66] J. W. Qiao;S. Wang;Y. Zhang;P. K. Liaw;G. L. Chen .Large plasticity and tensile necking of Zr-based bulk-metallic-glass-matrix composites synthesized by the Bridgman solidification[J].Applied physics letters,2009(15):151905-1-151905-3-0.
[67] Chen G;Cheng J L;Liu C T .Large-sized Zr-based bulk-metallic-glass composite with enhanced tensile properties[J].Intermetallics,2012,28:25.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
作者相关
文章评分
  • 您的评分：
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%

版权所有©2010中国科学院金属研究所中国科技出版传媒股份有限公司

本系统由北京仁和汇智信息技术有限公司设计开发

技术支持：info@rhhz.net