水钢采用低比例的钒钛矿高炉炼铁,获得含有钒钛等微量元素的铁水,其性质既不同于一般铁水,也不同于高钒钛铁水,为了弄清这些微量元素对转炉炼钢工艺的影响,分析了钒钛钢渣的物相、熔化性,用高频感应炉模拟转炉吹炼过程并结合生产试验得知:1)普通铁水的碳焰温度为1370~1400℃,水钢铁水的碳焰温度为1400~1430℃,比普通铁水高约30℃;2)在较小的供氧速度下,铁水中的钛、硅、锰可与碳分阶段氧化;3)含有TiO2炉渣的发泡能力、储泡能力强于不含TiO2的炉渣,炉渣中的CO反应性气泡使炉渣的发泡更加严重;4)在转炉吹炼前中期,炉渣中过高的FeO、较低的碱度,炉渣中大量的C-FeO反应,以及含有TiO2炉渣的储泡性质,是喷溅的主要原因。
V-Ti-tracing-elements hot metal, which was different from common hot metal and high V-Ti hot metal, was produced using low proportion iron ore involving V-Ti element. In order to know the effect of these trace elements on converter steelmaking process, the phase compositions and melting characters of V-Ti slag were analyzed and the steelmaking process in converter was simulated by high frequency induction furnace. The results show that: 1) carbon flame temperature of general hot metal is 1370-1400℃, carbon flame temperature of Shuigang hot metal is 1400-1430℃ which is 30℃ higher than that of general hot metal; 2) at a small rate of blowing oxygen, Ti,Si,Mn and C in melt can be oxidized one by one; 3) foaming and foam storage capacity of TiO2-bearing slag is larger than that of slag without TiO2, active CO bubbles in slag exacerbate slag foaming; 4) in prior and mid period of converter steelmaking, super high FeO content, relatively low alkalinity and C-FeO reaction in slag and foam storage capacity of TiO2-bearing slag are main reasons for the slopping.
参考文献
[1] | |
[2] | Yang Y, Song B, Jiang J P, et al. Study on Reduction Kinetics of Vanadium in CaO―SiO2―Al2O3―MgO―V2O5. Iron Steel Vanadium Titanium, 2005, 26(4): 1(杨勇,宋波,姜钧普,等. CaO―SiO2―Al2O3―MgO―V2O5渣系中钒还原动力学研究. 钢铁钒钛,2005, 26(4): 1)[2] Wen Y C, Zhou J C, Yang S B, et al. Study of Melting Properties of Converter Slag Containing Vanadium and Titanium Oxides. Iron Steel Vanadium Titanium, 2001, 22(3): 32(文永才,周家琮,杨素波,等. 钒钛转炉钢渣熔化特性的研究. 钢铁钒钛,2001, 22(3): 32)[3] He Y Y, Liu Q C, Yang J, et al. Experimental Investigation on Fluidity of Hot metal Bearing Titanium. Iron Steel Vanadium Titanium, 2010, 31(2): 10(贺媛媛,刘清才,杨剑,等. 含钛铁水流动性能研究. 钢铁钒钛,2010, 31(2): 10) [4] Dong W C, Ge W S, Shi Z. Trail on Vanadium Recovery of Low-vanadium Hot Metal. Iron Steel Vanadium Titanium, 2010, 31(4): 22(董万春,戈文荪,施哲. 低钒铁水提钒试验. 钢铁钒钛,2010, 31(4): 22)[5] Liu S P, Luo X G, Wen G Y. Investigation on Pretreatment of Hot Metal Containing Vanadium and Titanlium by Powder Injection. Iron & Steel, 2002, 37(2): 7(刘守平,罗小刚,文光远. 钒钛铁水喷粉预处理研究. 钢铁,2002, 37(2): 7) [6] Wen G Y. Pretreatment of the Hot Iron Containing Vanadium and Titanium. Journal of Chongqing University (Natural Science Edition), 1999, 22(2): 113(文光远. 含钒钛铁水的预处理. 重庆大学学报(自然科学版),1999, 22(2): 113) [7] Chen X P, Yang S B, Ge W S, et al. Pretreatment of Hot Metal Containing Vanadium and Titanium at PZH Steel. Iron Steel Vanadium Titanium, 2001, 22(3): 52(陈小平,杨素波,戈文荪,等. 攀钢含钒钛铁水预处理工艺实践. 钢铁钒钛,2001, 22(3): 52) [8] Ren Z D, Pong F R. A Study on the Foaming of Basic Slag Containing TiO2. Industrial Heating, 1999, (6): 14(任正德,庞福如. 含TiO2碱性炼钢渣的发泡性能研究. 工业加热,1999, (6): 14)[9] Zhang D D, Li M L, Li Y Z. Future development of Steelmaking Technology and Related Measures at PZH Steel. Iron Steel Vanadium Titanium, 2001, 22(3): 1(张大德,李茂林,李杨洲,等. 攀钢炼钢技术的发展方向及对策. 钢铁钒钛,2001, 22(3): 1) [10] Wang B H, Liu Q D, Practice to Prolong Converter’s Working Life for Vanadium-titanium Molten-iron Smelting. Hebei Metallurgy, 2005, 150(6): 42(王宝华,刘庆栋. 提高钒钛铁水冶炼转炉炉龄的实践. 何北冶金,2005, 150(6): 42)[11] Wen Y C. Study on System of Slag for Slag Splashing on BOF at PZH Steel. Iron Steel Vanadium Titanium, 2002, 23(4): 2(文永才. 攀钢转炉溅渣护炉渣系的研究. 钢铁钒钛,2002, 23(4): 2) [12] Liu Q S, Wen Y C, Tang T Y. Research and Application of Composite Slagging Flux in Steelmaking Process at PZH Steel. Iron Steel Vanadium Titanium, 2000, 21(4): 55(栾秋生,文永才,汤天宇,等. 攀钢炼钢复合造渣剂的研制及应用. 钢铁钒钛,2000, 21(4): 55) |
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