La9.33Si6O26 Oxygen ionic conductor was synthesized by solid state reaction method. Its structure was determined by single-crystal X-ray diffraction analysis at room temperature. The results showed that La9.33Si6O26 oxide has the apatite structure with space group P63/m. AC impedance measurements indicated that the oxides sintered in nitrogen have much higher conductivity than those sintered in air. The effects of grain boundaries on the conductivity were discussed.
参考文献
[1] | R A George;N F Besstte .[J].Journal of Power Sources,1998,71:131. |
[2] | T Kudo;H Obayashi .[J].Journal of the Electrochemical Society,1976,123:415. |
[3] | P O Battle;C R A Catlow;J W Heapand;L.M.Moroney .[J].Journal of Solid State Chemistry,1986,63:8. |
[4] | T Ishihara;T Shibayama;S Ishikawa;K.Hosoi,H.Nishiguchi Y.Takita .[J].Journal of the European Ceramic Society,2004,24:1329. |
[5] | S Nakayama;H Aono;Y Sadaoka .[J].Chemistry Letters,1995,24:431. |
[6] | S Nakayama;T Kageyama;H Aono;Y.Sadaoka .[J].Journal of Materials Chemistry,1995,5:1801. |
[7] | H Arikawa;N Nishiguchi;T Ishiihara;Y.Takita .[J].Solid-State Ionicis,2000,136-137:31. |
[8] | S Tao;J T S Irvine .[J].Materials Research Bulletin,2001,36:1245. |
[9] | S Nakayama;M Sakamoto;M Higuchi;K.Kodaira,M.Sata,S.Kakita,T.Suzuki K.Itoh .[J].Journal of the European Ceramic Society,1999,19:507. |
[10] | J E H Sansom;D Richings;P R Slater .[J].Solid-State Ionicis,2001,139:205. |
[11] | H Okudera;Y Masubuchi;S Kikkawa;A.Yoshiasa .[J].Solid-State Ionicis,2005,176:1473. |
[12] | X-RED 1.08a,STOE Data Reduction Program[M].STOE & Cie GmbH Darmstadt,Germany,1996 |
[13] | X-SHAPE 1.02,Crystal Optimisation for Numerical Absorption Correction[M].STOE & Cie GmbH Darmstadt,Germany,1996 |
[14] | P J Panteix;I Julien;D Bernache-Assollant;P.Abelard .[J].Materials Chemistry and Physics,2006,95:313. |
[15] | S Nakayama;M Sakamoto .[J].Journal of the European Ceramic Society,1998,18:1413. |
[16] | J R Tolchard;M S Islam;P R Slater .[J].Journal of Materials Chemistry,2003,13:1956. |
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