通过γ-氨丙基三乙氧基硅烷(KH550)和正硅酸乙酯(TEOS)的水解反应来制备超支化有机硅聚合物,并将制备的超支化有机硅聚合物加入到端羟基聚二甲基硅氧烷(PDMS)中,固化后得到亲水性硅橡胶.采用傅里叶变换红外吸收光谱仪(IR)、接触角测定仪对制备的硅橡胶进行了表征,同时测定了硅橡胶的力学性能.结果表明,超支化有机硅聚合物可以显著改善硅橡胶的亲水性,降低硅橡胶与蒸馏水的接触角,并在一定程度上提高硅橡胶的力学性能.
参考文献
[1] | 石锐,丁涛,刘全勇,刘力,张立群,陈大福,田伟.生物弹性体的研究进展Ⅰ.硅橡胶[J].合成橡胶工业,2006(03):165-169. |
[2] | Erlich M A;Parhiscar A .Surface modification of an experimental silicone rubber maxillofacial material to improve wettability[J].Facial Plastic Surgery Clinics of North America,2003,19(04):325. |
[3] | Maldonado Codina C;Morgan PB;Efron N;Canry JC .Characterization of the surface of conventional hydrogel and silicone hydrogel contact lenses by time-of-flight secondary ion mass spectrometry.[J].Optometry and vision science: official publication of the American Academy of Optometry,2004(6):455-460. |
[4] | Prantl L;Schreml S;Fichtner-Feigl S;Poppl N;Eisenmann-Klein M;Schwarze H;Fuchtmeier B .Clinical and morphological conditions in capsular contracture formed around silicone breast implants.[J].Plastic and reconstructive surgery,2007(1):275-284. |
[5] | Vermeltfoort P B;Van der Mei H C;Busscher H J et al.Physicochemical factors influencing bacterial transfer from contact lenses to surfaces with different roughness and wettability[J].Journal of Biomed Mater Res B:Appl Biomafer,2004,71(02):336. |
[6] | 隋磊,巢永烈,王娉婷,周敏."亲水性"硅橡胶口腔印模材料的润湿性研究[J].国际口腔医学杂志,2009(04):405-408. |
[7] | Kanehira M;Finger W J;Komatsu M .Surface detail reproduction with new elastomeric dental impression materials[J].Quintessence International,2007,38(06):479. |
[8] | 陈晓东,朴东旭,孙瑞焕,胡元洁,王建祺.硅橡胶的等离子体表面亲水改性[J].高分子材料科学与工程,2000(01):153-155. |
[9] | Ko YG;Kim YH;Park KD;Lee HJ;Lee WK;Park HD;Kim SH;Lee GS;Ahn DJ .Immobilization of poly(ethylene glycol) or its sulfonate onto polymer surfaces by ozone oxidation.[J].Biomaterials,2001(15):2115-2123. |
[10] | Sakka S;Tanaka Y;Kokubo T .Hydrolysis and polycondensation of dimethyldiethoxysilane and methyltriethoxysilane as materials for the sol-gel process[J].Journal of Non-Crystalline Solids,1986,82(01):24. |
[11] | Percec V.;Schlueter D. .MECHANISTIC INVESTIGATIONS ON THE FORMATION OF SUPRAMOLECULAR CYLINDRICAL SHAPED OLIGOMERS AND POLYMERS BY LIVING RING OPENING METATHESIS POLYMERIZATION OF A 7-OXANORBORNENE MONOMER SUBSTITUTED WITH TWO TAPERED MONODENDRONS[J].Macromolecules,1997(19):5783-5790. |
[12] | Jiang C Y;Mark J E .The effect of relative humidity on the hydrolytic precipitation of silica into an elastomeric network[J].Colloid and Polymer Science,1984,262(t2):758. |
[13] | Flory P J .Molecular size distribution in three dimensional polymers Ⅵ.Branched polymers containing A-R-Bf-1[J].Journal of the American Chemical Society,1952,74(11):2718. |
[14] | 赵辉,罗运军,宋海香.超支化聚合物研究进展(Ⅱ)超支化聚合物的合成[J].热固性树脂,2004(05):31-34. |
[15] | Shu Ching-Fong;Leu Chi-Meng .Hyperbranched poly(ether ketone) with carboxylic acid terminal groups: Synthesis, characterization, and derivatization[J].Macromolecules,1999(1):100-105. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%