欢迎登录材料期刊网

材料期刊网

高级检索

利用脉冲磁控溅射制备技术,采用单质金属铜靶作为溅射靶,在氧气(O2)和氩气(Ar)的混合气氛下,在石英玻璃衬底上制备了Cu2O薄膜.研究了溅射功率对脉冲反应磁控溅射沉积法在室温下对生长Cu2O薄膜结构、表面形貌及光学性能的影响.结果表明,在O2、Ar流量比(O2/Ar)为30∶80的气氛条件下,在60~90 W的溅射功率范围内可获得< 111>取向的Cu2O薄膜;薄膜的表面粗糙度的均方根值随溅射功率的增加而增大;薄膜的光谱吸收范围为300 ~670 nm,不同溅射功率下制备的薄膜均在430 nm附近出现明显的带边吸收,其光学带隙(Eg)在2.15~2.53 eV之间变化.

参考文献

[1] Georgieva V.;Ristov M. .Electrodeposited cuprous oxide on indium tin oxide for solar applications[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2002(1):67-73.
[2] Lv, P.;Zheng, W.;Lin, L.;Peng, F.;Huang, Z.;Lai, F. .I-V characteristics of ZnO/Cu_2O thin film n-i-p heterojunction[J].Physica, B. Condensed Matter,2011(6/7):1253-1257.
[3] 杨美佳,朱丽萍.Cu2O-ZnO太阳能电池的研究进展及磁控溅射法制备Cu2O-ZnO异质结的研究[J].发光学报,2013(02):202-207.
[4] Li Jun-Qiang,Mei Zeng-Xia,Ye Da-Qian,Hou Yao-Nan,Liu Yao-Ping,A.Yu.Kuznetsov,Du Xiao-Long.Temperature dependence of Cu2O orientations in the oxidation of Cu (111)/ZnO (0001) by oxygen plasma[J].中国物理B(英文版),2012(07):422-430.
[5] K. Akimoto;S. Ishizuka;M. Yanagita;Y. Nawa;Goutam K. Paul;T. Sakurai .Thin film deposition of Cu_2O and application for solar cells[J].Solar Energy,2006(6):715-722.
[6] M. Hari Prasad Reddy;J. F. Pierson;S. Uthanna .Structural, surface morphological, and optical properties of nanocrystalline Cu_2O and CuO films formed by RF magnetron sputtering: Oxygen partial pressure effect[J].Physica status solidi, A. Applications and materials science ePSS,2012(7):1279-1286.
[7] Ogwu AA;Bouquerel E;Ademosu O;Moh S;Crossan E;Placido F .The influence of rf power and oxygen flow rate during deposition on the optical transmittance of copper oxide thin films prepared by reactive magnetron sputtering[J].Journal of Physics, D. Applied Physics: A Europhysics Journal,2005(2):266-271.
[8] 尚通明,关明云,孙建华,周全法,徐正.不同形貌的Cu2O:可控合成及光学性质[J].无机化学学报,2010(07):1294-1298.
[9] Chandra R;Chawla AK;Ayyub P .Optical and structural properties of sputter-deposited nanocrystalline Cu2O films: Effect of sputtering gas[J].Journal of nanoscience and nanotechnology,2006(4):1119-1123.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%