提出一种以日云石和菱镁石的混合矿物为原料、以铝粉为还原剂的具空热还原炼镁,然后利用镁还原后的残渣制取氢氧化铝的工艺和技术,并进行实验研究.结果表明:以煅烧后的白云石和菱镁石混合矿物为原料的真空金属热还原炼镁,在还原温度为1 200℃、还原时间为2h、铝粉过量系数为5%的条件下,镁的还原率可达89%以上,还原渣主要物相为CaO·2Al2O3,还原渣中Al2O3的含量为67%左右;该炼镁还原渣经碳酸钠和氢氧化钠的混合碱液浸出后,Al2O3的浸出率达到85%,浸出Al2O3后渣的主要成分为CaCO3;浸出液中的Al2O3以可溶解的铝酸钠存在于浸出液中,后经碳分分解制得氢氧化铝,氢氧化铝的白度达到97%.
参考文献
[1] | 张新明,彭卓凯,陈健美,邓运来.耐热镁合金及其研究进展[J].中国有色金属学报,2004(09):1443-1450. |
[2] | SUJIT D .Pdmary magnesium production costs for automotive applications[J].Journal of the Minerals Metals & Materials Society,2008,60(11):63-69. |
[3] | G. Hanko;H. Antrekowitsch;P. Ebner .Recycling Automotive Magnesium Scrap[J].JOM,2002(2):51-54. |
[4] | 鲍荣华,周进生.注重镁的研发与应用拓宽节约能源新途径[J].资源与产业,2009(05):92-95. |
[5] | Zhou Ningbo,Chen Baizhen,He Xinkuai,Li Yibing.Preparation of anhydrous magnesium chloride in a gas-solid reaction with ammonium carnallite[J].中国高等学校学术文摘·化学,2006(04):384-388. |
[6] | 马鸿文,曹瑛,蒋芸,吴秀文,刘玉芹.中国金属镁工业的环境效应与可持续发展[J].现代地质,2008(05):829-837. |
[7] | 彭建平,冯乃祥,高枫,谭亚菊,陈恒.镁冶金技术的能耗与环境评价[J].有色矿冶,2008(01):40-43. |
[8] | Ze Sun;He-nan Zhang;Ping Li .Modeling and Simulation of the Flow Field in the Electrolysis of Magnesium[J].JOM,2009(5):29-33. |
[9] | O.A.Lebedev;I.Yu.Brusakov;N.P.Shkuryakov .Express Monitoring of MgCl_2 Concentration in the Electrolyte of Magnesium Electrolyzers[J].Russian journal of applied chemistry,2005(8):1276-1279. |
[10] | Minic D;Manasijevic D;Dokic J;Zivkovic D;Zivkovic Z .Silicothermic reduction process in magnesium production - Thermal analysis and characterization of the slag[J].Journal of thermal analysis and calorimetry,2008(2):411-415. |
[11] | 高峰,聂祚仁,王志宏,左铁镛.中国皮江法炼镁的资源消耗和环境影响分析[J].中国有色金属学报,2006(08):1456-1461. |
[12] | 徐日瑶,刘荣义,刘宏专.节能、降耗、减排是硅热法炼镁发展的生命力[J].轻金属,2009(01):45-49. |
[13] | Feng Gao;Zuoren Nie;Zhihong Wang;Xianzheng Gong;Tieyong Zuo .Life cycle assessment of primary magnesium production using the Pidgeon process in China[J].The international journal of life cycle assessment,2009(5):420-428. |
[14] | Minic D;Manasijevic D;Dokic J;Zivkovic D;Zivkovic Z .Silicothermic reduction process in magnesium production - Thermal analysis and characterization of the slag[J].Journal of thermal analysis and calorimetry,2008(2):411-415. |
[15] | 冯乃祥;王耀武;胡文鑫 .以MgO/CaO摩尔比大于1的物料为原料真空还原制取金属镁的方法[P].中国,101942572A,2011-01-12. |
[16] | 冯乃祥;王耀武;胡文鑫 .从以铝或铝合金为还原剂制取金 属镁的副产物中提取氢氧化铝和氧化铝的方法[P].中国,101845550A,2010-09-29. |
[17] | HU Wen-xin;FENG Nai-xiang;WANG Yao-wu.Magnesium production by vacuum aluminothemic reduction of a mixture of calcined dolomite and calcined magnesite[A].SanDiego:The Minerals,Metals & Materials Society,2011:43-47. |
[18] | DAS S K;MITRA A;DAS PODDAR P K .Thermal analysis of hydrated calcium aluminates[J].Journal of Thermal Analysis,1996,47:765-768. |
[19] | 陈肇友,柴俊兰.六铝酸钙材料及其在铝工业炉中的应用[J].耐火材料,2011(02):122-125. |
[20] | Singh VK. .SINTERING STUDY OF CALCIUM ALUMINATE[J].Journal of Materials Science,1996(19):5163-5168. |
[21] | GAWLICKI M;WCZELIK W;PYZALSKI M .Studies on the hydration of calcium aluminates[J].Journal of Thermal Analysis,1984,29:1005-1008. |
[22] | 孙会兰,涂赣峰,毕诗文,王波,于海燕,齐铭,耿红娟.七铝十二钙的合成及其在高碳钠铝酸钠溶液中的溶出性能[J].轻金属,2007(11):17-19. |
[23] | WANG Yao-wu;FENG Nai-xiang;YOU Jing;PENG Jian-ping,DI Yue-zhong.Study on extracting aluminum hydroxide from reduction slag of magnesium smelting by vacuum aluminothennic reduction[A].SanDiego:The Minerals,Metals & Materials Society,2011:205-209. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%