氢气作为高效、洁净的二次能源将成为未来社会的主要能源之一.甲烷重整是一种被广泛使用的经济、高效的制氢工艺.催化剂是重整工艺中的重要组成部分,其种类、活性和寿命对氢气的产率、纯度和制氢成本具有重要影响.详细论述了甲烷水蒸气重整、二氧化碳重整、部分氧化重整用催化剂的种类、制备方法和催化机理等.
参考文献
| [1] | 王艳辉,吴迪镛,迟建.氢能及制氢的应用技术现状及发展趋势[J].化工进展,2001(01):6-8. |
| [2] | 粟源林;刘树人;唐廷川 .中国天然气发展战略探讨[J].天然气工业,1992,12(02):75. |
| [3] | Sheldon H.D. Lee;Daniel V. Applegate;Shabbir Ahmed;Steven G. Calderone;Todd L. Harvey .Hydrogen from natural gas: part Ⅰ—autothermal reforming in an integrated fuel processor[J].International journal of hydrogen energy,2005(8):829-842. |
| [4] | Roberto Carapellucci;Adriano Milazzo .Thermodynamic optimization of a reheat chemically recuperated gas turbine[J].Energy Conversion & Management,2005(18/19):2936-2953. |
| [5] | 许珊,王晓来,赵睿.甲烷催化制氢气的研究进展[J].化学进展,2003(02):141-150. |
| [6] | Santos D C R M;Lisboa J S;Passos F B et al.Characterization of steam-reforming catalysts[J].Brazilian J Chem Eng,2004,21(02):203. |
| [7] | Young-Sam Oh;Hyun-Seog Roh;Ki-Won Jun;Young-Soon Baek .A highly active catalyst, Ni/Ce-ZrO_2/θ-Al_2O_3, for on-site H_2 generation by steam methane reforming: pretreatment effect[J].International journal of hydrogen energy,2003(12):1387-1392. |
| [8] | Radu Cracium;Wayne Daniell;Helmut Knozinger .The effect of CeO2 structure on the activity of supported Pd catalysts used for methane steam reforming[J].Appl Catalysis A:General,2002,230:153. |
| [9] | 王广建,柳荣展,常俊石.新型催化剂-碳化钼和碳化钨的现状和展望[J].青岛大学学报(工程技术版),2001(03):51-53. |
| [10] | David C LaMont;William J Thomson .Dry reforming kinetics over a bulk molybdenum carbide catalyst[J].Chemical Engineering Science,2005,60:3553. |
| [11] | Andrew P E York;John B Clafidge;Attila J Brungs.Molybdenum and tungsten carbides as catalysts for the conversion of methane to synthesis gas using stoichiometric feedstocks[J].Chemistry Communications,1997:39. |
| [12] | John B Claridge;Andrew P E York;Attila J Brungs et al.New catalysts for the conversion of methane to synthesis gas:molybdenum and tungsten carbide[J].Journal of Catalysis,1998,180:85. |
| [13] | Roh Hyun Seog;Jun Ki Won;Baek Seung Chan et al.Carbon dioxide reforming of methane over Ni/Al2O3 catalysts:effect of Ni content[J].Bulletin of the Korean Chemical Society,2002,23(08):1166. |
| [14] | Teuner S .A new process to make oxo-feed[J].Hydrocarb on Processing,1987,66(07):52. |
| [15] | Ashcroft A T;Cheetham A K;Green M L H et al.Partial oxidation of methane to synthesis gas using carbon dioxide[J].Nature,1991,352:225. |
| [16] | Richardson J T;Paripatyadar S A .Carbon dioxide reforming of methane to produce synthesis gas[J].Appl Catalysis,1990,61:293. |
| [17] | 刘少文,李永丹.甲烷重整制氢气的研究进展[J].武汉化工学院学报,2005(01):20-24,27. |
| [18] | 陈兴权,赵天生.甲烷二氧化碳重整催化剂的研究进展[J].宁夏石油化工,2003(01):15-17. |
| [19] | 李春林,卞国柱,伏义路,刘涛,谢亚宁,胡天斗.三氧化二铝含量对Ni/Zr0.4Ce0.6O2-Al2O3催化剂的 CH4-CO2重整反应性能影响[J].分子催化,2001(05):351-354. |
| [20] | 李春林,伏义路,孟明,卞国柱,谢亚宁,胡天斗,张静.水蒸汽对Ni/CeO2-ZrO2-Al2O3催化剂上CO2+CH4重整反应的影响[J].化学物理学报,2004(01):95-99. |
| [21] | Chen Jixiang;Wang Rijie;Zhang Jiyan et al.Effects of preparation methods on properties of Ni/CeO2-Al2O3 catalysts for methane reforming with carbon dioxide[J].J Molecular Catalysis A:Chem,2005,235:302. |
| [22] | Laosiripojana N;Sutthiripok W;Assabumrungrat S .Synthesis gas production from dry reforming of over CeO2 doped Ni/Al2O3:influence of the doping ceria on the resistance toward carbon formation[J].Chemical Engineering Journal,2005,112:13. |
| [23] | Gustavo Valderrama;Mireya R.Goldwasser;Caribay Urbina de Navarro;Jean M.Tatibouet;Joel Barrault;C.Batiot-Dupeyrat;Fernando Martinez .Dry reforming of methane over Ni perovskite type oxides[J].Catalysis Today,2005(0):785-791. |
| [24] | Halliche D;Cherifi O;Auroux A .Microcalorimetric studies and methane reforming by CO2 on Ni-based zeolite catalysts[J].Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems,2005(1/2):125-131. |
| [25] | 贺黎明;沈召军.甲烷的转化和利用[M].北京:化学工业出版社,2005 |
| [26] | 吴俊荣.甲烷部分氧化制合成气的研究进展[J].广州化工,2003(01):17-20. |
| [27] | 王越,叶季蕾,段华超,刘源.钡改性的Ni/γ-Al2O3催化剂用于甲烷部分氧化的研究[J].燃料化学学报,2005(06):750-754. |
| [28] | 张媛,李增喜,闻学兵,刘源.柠檬酸络合法制备NiO-CeO2-TiO2复合氧化物及其在甲烷部分氧化反应中的应用[J].催化学报,2005(12):1059-1066. |
| [29] | 朱全力,杨建,季生福,王嘉欣,汪汉卿.Mo2C/Al2O3催化剂用于甲烷部分氧化（POM）制合成气的研究[J].分子催化,2003(02):118-123. |
| [30] | Bharadwaj S S;Schmidt L D .Catalytic partial oxidation of natural gas to syngas[J].Fuel Proc Techn,1995,42:109. |
| [31] | Gambini M;Vellini M .Comparative analysis of H2/O2 cycle power plants based on different hydrogen production systerns from fossil fuels[J].International Journal of Hydrogen Energy,2005,30:593. |
| [32] | Esther Ochoa Fernandez;Hans Kristian Rusten;Hugo Atle Jakobsen et al.Sorption enhanced hydrogen production by steam methane reforming using Li2ZrO3 as sorbent:Sorption kinetics and reactor simulation[J].Catalysis Today,2005,106:41. |
| [33] | 吴素芳,T.H.Beum,J.I.Yang,J.N.Kim.采用CO2吸附剂吸附强化的甲烷水蒸汽反应制氢过程特点[J].中国化学工程学报（英文版）,2005(01):43-47. |
| [34] | Wang Y;Chin Y H;Rozmiarek R T et al.Highly active and stable Rh/MgO-Al2O3 catalysts for methane steam reforming[J].Catalysis Today,2004,98:575. |
| [35] | Song Chunshan;Pan Wei .Tri-reforming of methane:a novel concept for catalytic production of industrially useful synthesis gas with desired H2/CO ratios[J].Catalysis Today,2004,98:463. |
| [36] | Tsang S C;Clardge J B;Green M L H .Recent advances in the conversion of methane to synthesis gas[J].Catalysis Today,1995,23:3. |
| [37] | 金荣超,陈燕馨,崔巍,李文钊,于春英,江义.甲烷催化部分氧化制合成气的反应机理[J].物理化学学报,1999(04):313-318. |
| [38] | 张翅远,王华,何方,张兴雪.甲烷部分氧化制氢机理及方法[J].能源工程,2005(06):20-25. |
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