采用溶胶-凝胶法成功地制备了双钙钛矿结构的Sr2Fe1-xNixMoO6(x=0.0～0.4)化合物.X射线衍射实验表明,Ni的掺入没有改变化合物的晶体结构和空间群,但晶格常数随Ni含量的增加而减小,同时B位阳离子的占位有序度随Ni含量的增多而增大.研究还表明,B位阳离子的占位有序度与样品的烧结温度也有很大的关系,烧结温度升高,有序度增大.扫描电镜分析表明,所制备的样品颗粒度均匀,界面清晰,Ni的掺入使颗粒细化.
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