使用Ca(NO3)2-P2O5乙醇溶液体系制备纳米羟基磷灰石,研究了在该体系中水浴温度、煅烧温度、陈化时间等因素对粉体的相成分,粒度和结晶度的影响.结果表明:水浴温度低,合成的粉体粒度小(约20nm),颗粒均匀且具有良好的分散性,但是结晶度较低;陈化后导致粉体粒度变大,结晶度增加;随着煅烧温度的升高,粉体的结晶度增加,600℃时可以得到结晶高的单一的羟基磷灰石粉体.在800℃煅烧时,羟基磷灰石发生部分分解.
参考文献
| [1] | Hench L L .[J].Journal of the American Ceramic Society,1991,74(07):1487. |
| [2] | Lim G K et al.[J].Journal of Materials Chemistry,1999,9(07):1635. |
| [3] | Matsumoto T;Okazaki M;Inoue M;Yamaguchi S;Kusunose T;Toyonaga T;Hamada Y;Takahashi J .Hydroxyapatite particles as a controlled release carrier of protein.[J].Biomaterials,2004(17):3807-3812. |
| [4] | Zhu S H et al.[J].J Nanopar Res,2004,6(2-3):307. |
| [5] | 张玉梅,王勤涛,付涛,徐可为.含锶羟基磷灰石的湿法合成与结构稳定性[J].稀有金属材料与工程,2004(10):1049-1051. |
| [6] | Sung YM.;Lee JC.;Yang JW. .Crystallization and sintering characteristics of chemically precipitated hydroxyapatite nanopowder[J].Journal of Crystal Growth,2004(1/4):467-472. |
| [7] | Chu C L et al.[J].Journal of Materials Science Letters,2002,21(22):1793. |
| [8] | Bose S et al.[J].Journal of the American Ceramic Society,2003,86(06):1055. |
| [9] | Andres-Verges M et al.[J].Journal of the European Ceramic Society,1998,18(09):1245. |
| [10] | 刘榕芳,肖秀峰,倪军,黄俊民.羟基磷灰石粉末的水热合成及动力学研究[J].无机化学学报,2003(10):1079-1084. |
| [11] | Yeong K C B et al.[J].Biomaterials,2001,22(20):2705. |
| [12] | Manuel C M et al.[J].Key Engineering Materials,2003,240(02):555. |
| [13] | Bose S.;Saha SK. .Synthesis and characterization of hydroxyapatite nanopowders by emulsion technique[J].Chemistry of Materials,2003(23):4464-4469. |
| [14] | Lim G K et al.[J].Langmuir,1999,15(22):7472. |
| [15] | Kim H W et al.[J].Journal of Biomedical Materials Research,2005,74A(03):294. |
| [16] | Liu DM;Yang Q;Troczynski T .Sol-gel hydroxyapatite coatings on stainless steel substrates.[J].Biomaterials,2002(3):691-698. |
| [17] | Chung R J et al.[J].Journal of Sol-Gel Science and Technology,2005,33(02):229. |
| [18] | Ramanan S R et al.[J].Materials Letters,2004,58(26):3320. |
| [19] | Gan L;Pilliar R .Calcium phosphate sol-gel-derived thin films on porous-surfaced implants for enhanced osteoconductivity. Part I: Synthesis and characterization.[J].Biomaterials,2004(22):5303-5312. |
| [20] | Bezzi G.;Celotti G.;Landi E.;La Torretta TMG.;Sopyan I.;Tampieri A. .A novel sol-gel technique for hydroxyapatite preparation[J].Materials Chemistry and Physics,2003(3):816-824. |
| [21] | Weng W J et al.[J].Materials Chemistry and Physics,2002,77(02):578. |
| [22] | Wang F et al.[J].Materials Letters,2005,59(8-9):916. |
| [23] | Kima I S et al.[J].Materials Science and Engineering B,2004,B111(2-3):232. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%