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首先用γ-氨丙基三甲氧基硅烷对SiO2进行接枝改性,再依次与香草醛、Li2PdCl4反应,合成了环钯/SiO2有机-无机杂化材料.采用FT-IR、XRD、XPS和TG-DSC等方法对该杂化材料进行了表征,并研究了其对碘代芳烃与丙烯基衍生物交叉偶联反应的催化活性.结果表明该杂化材料是具有较高催化活性和选择性,并具有良好循环使用性的多相催化剂.

参考文献

[1] Yangjie Wu;Jianjun Hou;Hongying Yun;Xiuling Cui;Ruijuan Yuan .Cyclopalladated ferrocenylimines: highly active catalysts for Heck reactions[J].Journal of Organometallic Chemistry,2001(3):793-795.
[2] Wolfgang A. Herrmann;Volker P. W. Bohm .Heck reaction catalyzed by phospha-palladacycles in non-aqueous ionic liquids[J].Journal of Organometallic Chemistry,1999(1):141-145.
[3] Adriane S.Gruber;Dirce Pozebon;Adriano L.Monteiro;Jairton Dupont .On the use of phosphine-free PdCl_2(SEt_2)_2 complex as catalyst precursor for the Heck reaction[J].Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry,2001(42):7345-7348.
[4] Ping He;Yong Lu;Qiao-Sheng Hu .Phosphinite-and phosphite-based type I palladacycles as highly active catalysts for addition reactions of arylboronic acids with aldehydes,alpha,beta-unsaturated ketones,alpha-ketoesters,and aldimines[J].Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry,2007(30):5283-5288.
[5] Evans P;Hogg P;Grigg R;Nurnabi M;Hinsley J;Sridharan V;Suganthan S;Korn S;Collard S;Muir JE .8-Methylquinoline palladacycles: stable and efficient catalysts for carbon-carbon bond formation[J].Tetrahedron,2005(41):9696-9704.
[6] Lee HM;Lu CY;Chen CY;Chen WL;Lin HC;Chiu PL;Cheng PY .Palladium complexes with ethylene-bridged bis(N-heterocyclic carbene) for C-C coupling reactions[J].Tetrahedron,2004(27):5807-5825.
[7] Tanase AD;Frey GD;Herdtweck E;Hoffmann SD;Herrmann WA .Preparation of NHC-substituted phosphitepalladacycles[J].Journal of Organometallic Chemistry,2007(16):3316-3327.
[8] Ji Ma;Xiuling Cui;Bi Zhang;Maoping Song;Yangjie Wu .Ferrocenylimidazoline palladacycles: efficient phosphine-free catalysts for Suzuki–Miyaura cross-coupling reaction[J].Tetrahedron,2007(25):5529-5538.
[9] Jung IG.;Son SU.;Park KH.;Chung KC.;Lee JW.;Chung YK. .Synthesis of novel Pd-NCN pincer complexes having additional nitrogen coordination sites and their application as catalysts for the Heck reaction[J].Organometallics,2003(23):4715-4720.
[10] Diez-Barra E.;Guerra J.;Hornillos V.;Merino S.;Tejeda J. .1,2,4-Triazole-based palladium pincer complexes. A new type of catalyst for the heck reaction[J].Organometallics,2003(22):4610-4612.
[11] Yu KQ;Sommer W;Weck M;Jones CW .Silica and polymer-tethered Pd-SCS-pincer complexes: evidence for precatalyst decomposition to form soluble catalytic species in Mizoroki-Heck chemistry[J].Journal of Catalysis,2004(1):101-110.
[12] Chih-An Lin;Fen-Fair Luo .Polystyrene-supported recyclable palladacycle catalyst for Heck, Suzuki and Sonogashira reactions[J].Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry,2003(41):7565-7568.
[13] 刘蒲,李三华,王向宇,李利民.壳聚糖亚胺环钯化合物的合成与表征[J].光谱学与光谱分析,2006(04):666-669.
[14] 刘蒲,刘晔,李晶玉,刘一真,卢伟鹏,王向宇,李利民.壳聚糖亚胺环钯化合物的合成及其催化性能研究[J].有机化学,2007(01):87-91.
[15] Xia Xu;Pu Liu;San-hua Li .CHITOSAN-SUPPORTEDIMINE PALLADACYCLE COMPLEX AND Its CATALYTIC PERFORMANCE FOR HECK REACTION[J].Reaction kinetics & catalysis letters,2006(2):217-223.
[16] Robin B. Bedford;Cataerine S.J. Cazin;Michael B. Hursthouse;Mark E. Light;Kevin J. Pike;Stephen Wimperis .Silica-supported imine palladacycles—recyclable catalysts for the Suzuki reaction?[J].Journal of Organometallic Chemistry,2001(1/2):173-181.
[17] Albertus J.Sandee;Dragana Dimitrijevic;Richard J.van Haaren;Joost N.H.Reek;Paul C.J.Kamer;Piet W.N.M.van Leeuwen .Silica immobilised palladium phosphine complexes as recyclable, regioselective catalysts for the allylic alkylation[J].Journal of molecular catalysis, A. Chemical,2002(0):309-317.
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