为了研究镍氢动力电池正极材料氢氧化镍,收集目前常用的镍氢动力电池用正极材料—普通型及覆钴型氢氧化镍,制备独有技术产品钙镁掺杂型氢氧化镍.通过对该3大类产品进行高温大电流性能的测试表明,适用于镍氢动力电池的氢氧化镍正极材料为覆钴型及钙镁掺杂型氢氧化镍.再考察不同覆钴量的覆钴型氢氧化镍及不同配比的钙镁型氢氧化镍,对覆钴量及钙镁掺杂量进行研究,得出主要用于镍氢动力电池的氢氧化镍产品为覆钴量为Co3.5％的覆钴型氢氧化镍及Ca2 Mg0.5、Ca1.5 Mg0.2、Ca1 Mg0.3等3种成分的钙镁型氢氧化镍.
参考文献
| [1] | 唐有根;李文良.镍氢电池[M].北京:化学工业出版社,2007 |
| [2] | 陈军;陶占良.镍氢二次电池[M].北京:化学工业出版社,2006 |
| [3] | Zfurukawa N .Development and commercialization of nickelmetal hydride secondary batteries[J].Journal of Power Sources,1994,51(1-2):45. |
| [4] | Robert F Nelson .Power requirement for batteries in hybrid electric vehicles[J].Journal of Power Sources,2000,91(01):2. |
| [5] | Akihiro Taniguchi;Noriyuki Fujioka;Munehisa Ikoma et al.Development of nickel/metal-hydride batteries for EVs and HEWS[J].Journal of Power Sources,2001,100(1-2):117. |
| [6] | Takuto Araki;Masato Nakayama;Kenichi Fukuda et al.Thermal behavior of small nickel/metal hydride battery dtring rapid charge and discharge cycles[[J].Journal of the Electrochemical Society,2005,152(06):A1128. |
| [7] | Balej J .Determination of the oxygen and hydrogen overcharge in concentrated alkali hydroxide solutions[J].International Journal of Hydrogen Energy,1985,10(06):365. |
| [8] | Rubin E J;Baboian R .A correlation of the solution properties and the electrochemical behavior of the nickel hydroxide electrode in binary aqueous alkali hydroxides[J].Journal of the Electrochemical Society,1971,118(03):428. |
| [9] | Pauline De Vidts;Javier Delgado;Ralph E Whit .A multiphase mathematical model of a nickel/hydrogen cell[J].Journal of the Electrochemical Society,1996,143(10):3223. |
| [10] | Elumalai P;Vasan H N;Munichadraiah N .Electrochemical studies of cobalt hydroxide an additive for nickel electrodes[[J].Journal of Power Sources,2001,93(1-2):201. |
| [11] | V. Pralong;A. Delahaye-Vidal;B. Beaudoin;J. -B. Leriche;J. -M. Tarascon .Electrochemical behavior of cobalt hydroxide used as additive in the nickel hydroxide electrode[J].Journal of the Electrochemical Society,2000(4):1306-1313. |
| [12] | X. M. He;C. Y. Jiang;W. Li .Co/Yb Hydroxide Coating of Spherical Ni(OH)_2 Cathode Materials for Ni-MH Batteries at Elevated Temperatures[J].Journal of the Electrochemical Society,2006(3):A566-A569. |
| [13] | F. Barde;P.L. Taberna;J.M. Tarascon;M.R. Palacin .Evidence for electronic and ionic limitations at the origin of the second voltage plateau in nickel electrodes, as deduced from impedance spectroscopy measurements[J].Journal of Power Sources,2008(2):830-836. |
| [14] | Prolong V;Delahaye-Vidal A;Beaduin B et al.Oxidation mechanism of cobalt hydroxide to cobalt oxyhydroxide[J].Journal of Materials Chemistry,1999,9:955. |
| [15] | 张文广,蒋文全,于丽敏,傅钟臻,夏雯.氢氧化镍表面包覆Co（OH）2及其大电流充放电性能[J].稀有金属,2007(06):784-789. |
| [16] | 傅钟臻,蒋文全,于丽敏.覆钴型氢氧化镍的制备[J].中国有色金属学报,2005(11):1775-1779. |
| [17] | Masaharu Watada;Masahiko;Oshitani et al.Nickel electrode for alkaline battery:[P].US,5366831,1992. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%