Influence of t-ZrO2 addition on mechanical property and electrical conductivity of YSZ electrolyte

稀有金属（英文版）, 2006, 25(z1): 378-383.

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1.School of Metallurgy and Zoology Engineering, University of Science and Technology Beijing, Beijing 100083, China;Baosteel Iron & Steel Co., Ltd., Shanghai 200941, China

2.Key Laboratory of Advanced Ceramics and Machining Technology of Ministry of Education, Tianjin University, Tianjin 300072, China;Baosteel Iron & Steel Co., Ltd., Shanghai 200941, China

3.Key Laboratory of Advanced Ceramics and Machining Technology of Ministry of Education, Tianjin University, Tianjin 300072, China

4.Key Laboratory of Advanced Ceramics and Machining Technology of Ministry of Education, Tianjin University, Tianjin 300072, China

5.Key Laboratory of Advanced Ceramics and Machining Technology of Ministry of Education, Tianjin University, Tianjin 300072, China

Influence of t-ZrO2 addition on mechanical property and electrical conductivity of YSZ electrolyte

Keywords： YSZ

8YSZ material that has high electrical conductivity is widely used as electrolytes for solid oxide fuel cells (SOFCs). But its low strength and low fracture toughness hampered the development of SOFCs. In order to find a best method to improve the capability of YSZ electrolyte, the effects of 3Y-TZP additive on the density, strength, conductivity and microstructure were studied by means of X-ray diffraction and Vicker's hardness apparatus. The strength and conductivity of YSZ electrolyte doped with different amounts of 3Y-TZP were determined. It is shown that the samples sintered at 1450 ℃ for 2 h are the best in properties. When 3Y-TZP powders are added to the YSZ system, the results demonstrate that strength of the electrolyte increases remarkably, and the fracture toughness is improved. The electrical conductivity is lowered only slightly. The results display that the flexural strength and the fracture toughness of ceramics with 30wt.% TZP reach 300 MPa and 3.7 MPa·m1/2 , respectively, and the conductivity at 1000 ℃ reaches 0.11 S·cm-1 .

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Influence of t-ZrO2 addition on mechanical property and electrical conductivity of YSZ electrolyte

参考文献