纳米TiO2作为一种功能性半导体材料,在环境保护、光电转换、涂料行业和工业催化等领域有着极为广泛的用途.然而,光谱吸收范围窄、对太阳光的利用率低以及光量子效率低是限制TiO2实际应用的主要原因.掺杂改性可以拓宽光谱响应范围和提高量子效率,是提高光催化剂活性的重要方法.介绍了掺杂前后TiO2的催化原理,综述了稀土元素单一掺杂、稀土元素与其他元素共掺杂TiO2光催化剂的研究进展,并进一步指出了稀土掺杂TiO2中存在的问题和未来的研究方向.
参考文献
[1] | Fujishima A;Honda K .Electrochemical photolysis of water at a semiconductor electrode[J].Nature,1972,37:238. |
[2] | 刘时铸.金属掺杂二氧化钛的研究进展[J].广东化工,2008(06):48-50. |
[3] | Mohamed R M;Mkhalid I A .The effect of rare earth dopants on the structure,surface texture and photocatalytic properties of TiO2-SiO2 prepared by sol gel method[J].Journal of Alloys and Compounds,2010,501:143. |
[4] | 张莹,龚昌杰,燕宁宁,朱忠其,柳清菊.贵金属改性TiO2光催化剂的机理及研究进展[J].材料导报,2011(15):46-49. |
[5] | 于娜娜,代岳,陈珍,高志谨.TiO2光催化剂及其改性方法最新研究进展[J].化工中间体,2011(06):16-20. |
[6] | 高明琦,徐友龙,白杨.用于染料敏化太阳能电池的铌、氟双掺杂二氧化钛微球[J].西安交通大学学报,2011(12):87-91. |
[7] | Michael R. Hoffmann;Scot T. Martin;Wonyong Choi;Detlef W. Bahnemann .Environmental Applications of Semiconductor Photocatalysis[J].Chemical Reviews,1995(1):69-96. |
[8] | 徐松梅,高朋召,石宗利.双元素掺杂改性二氧化钛的研究进展[J].硅酸盐通报,2008(04):777-781,790. |
[9] | 薛寒松,李华基,胡慧芳,陈永盛.镧掺杂二氧化钛纳米管光催化性能[J].中国稀土学报,2008(01):18-23. |
[10] | I. Poulios;E. Micropoulou;R. Panou;E. Kostopoulou .Photooxidation of eosin Y in the presence of semiconducting oxides[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2003(4):345-355. |
[11] | T. Umebayashi;T. Yamaki;H. Itoh;K. Asai .Band gap narrowing of titanium dioxide by sulfur doping[J].Applied physics letters,2002(3):454-456. |
[12] | Uzunova-Bujnova M;Todorovska R;Dimitrov D et al.Lanthanide-doped titanium dioxide layers as photocatalysts[J].Applied Surface Science,2008,254:7296. |
[13] | 谷科成,胡相红,陈勇,张恒,陈逸.La掺杂纳米TiO2的制备及其光催化性能[J].后勤工程学院学报,2009(06):54-58. |
[14] | 敖特根,侯清玉,迎春.La高掺杂对锐钛矿型TiO2电子结构和吸收光谱影响的第一性原理研究[J].钛工业进展,2012(01):13-18. |
[15] | Wen C;Deng H;Tian J Y.Photocatalytic activity enhancing for TiO2 photocatalyst hy doping with La[J].Transactions of Nonferrous Metals Society of China,2006(16):728. |
[16] | 薛寒松,李华基,易于,胡慧芳,孟翠.铈掺杂二氧化钛纳米管的光催化性能[J].机械工程材料,2008(06):36-39,65. |
[17] | 张浩,钱付平.Ce掺杂TiO2催化剂的光催化性能[J].过程工程学报,2011(03):514-518. |
[18] | 吴玉程,宋林云,李云,李勇,李广海,郑治祥.Ce掺杂TiO2纳米粉体的制备及其光催化性能研究[J].人工晶体学报,2008(02):427-430. |
[19] | 赵伟伟,张栋,史强,黄宝旭,王长征.Ce掺杂对纳米TiO2微结构及光催化性能的影响[J].中国科技信息,2011(21):36,44. |
[20] | Fan Caimei,Xue Peng,Sun Yanping.Preparation of Nano-TiO2 Doped with Cerium and Its Photocatalytic Activity[J].稀土学报(英文版),2006(03):309-313. |
[21] | Liu H;Liu G;Zhou Q et al.Preparation and photocatalytic activity of Gd3+ doped trititanate nanotubes[J].Microporous and Mesoporous Materials,2011,142:439. |
[22] | 魏志钢,潘湛昌,徐阁,文梦葵,邹燕娣,钟雪春.Gd掺杂锐钛矿型二氧化钛的第一性原理研究[J].材料科学与工程学报,2011(02):217-220,213. |
[23] | El-Bahy Z M;Ismail A A;Mohamed R M .Enhancement of titania by doping rare earth for photodegradation of organic dye(Direct Blue)[J].Journal of Hazardous Materials,2009,166:138. |
[24] | 刘国敬,胡晓云,潘静,张德恺,韩永举,叶岩溪.Eu3+掺杂二氧化钛纳米粉末的制备及发光性质研究[J].菏泽学院学报,2009(05):70-74. |
[25] | 龙绘锦,王恩君,董江舟,王玲玲,曹永强,杨文胜,曹亚安.In离子掺杂二氧化钛纳米管可见光催化活性的研究[J].化学学报,2009(14):1533-1538. |
[26] | 王理明,姚秉华,裴亮,程刚.钌掺杂TiO2/Ti光电极的制备及光电催化性能[J].稀有金属材料与工程,2010(07):1240-1243. |
[27] | NIU Xinshu,LI Sujuan,CHU Huihui,ZHOU Jianguo.Preparation, characterization of Y3+-doped TiO2 nanoparticles and their photocatalytic activities for methyl orange degradation[J].稀土学报(英文版),2011(03):225-229. |
[28] | Cruz D;Arévalo J C;Torres G et al.TiO2 doped with Sm3+ by sol-gel:Synthesis,characterization and photocata lytic activity of diuron under solar light[J].Catalysis Today,2011,166:152. |
[29] | Liang C H;Li F B;Liu C S et al.The enhancement of adsorption and photocatalytic activity of rare earth ions doped TiO2 for the degradation of orange I[J].Dyes and Pigments,2008,76:477. |
[30] | 陈姣霞,郑经堂.钒镧共掺杂TiO2纳米粉体的制备及光催化性能研究[J].现代化工,2006(z2):255-257,260. |
[31] | 王东升,廖运文,何平,钟成家.双掺杂二氧化钛的制备及其在降解染料废水中的应用[J].西华师范大学学报(自然科学版),2011(02):180-183,200. |
[32] | Ping Yang;Cheng Lu;Nanping Hua;Yukou Du .Titanium dioxide nanoparticles co-doped with Fe~(3+) and Eu~(3+) ions for photocatalysis[J].Materials Letters,2002(4):794-801. |
[33] | 沈佳渊.双组分掺杂纳米TiO2光催化活性的研究[J].湖州师范学院学报,2003(z1):67-71. |
[34] | Wang Q;Xu S;Shen F .Preparation and characterization of TiO2 photocatalysts co-doped with iron and lanthanum for the degradation of organic pollutants[J].Applied Surface Science,2011,257:7671. |
[35] | 王铁,王曰燕,韩志杰.铁和镧共掺杂二氧化钛的光催化活性[J].应用化工,2008(08):913-916. |
[36] | 张念星,徐明霞,李晓雷,刘祥志,李顺.镧铁共掺杂二氧化钛纳米线阵列的可见光催化性能[J].硅酸盐学报,2008(z1):25-28,33. |
[37] | 何开棘,张圣军,丁慧,王开明.双元素共掺杂纳米TiO2的制备及光催化活性[J].辽宁科技大学学报,2008(03):235-239. |
[38] | 许静,林萍,成春颖.双元素金属掺杂纳米TiO2的制备及其光催化性能[J].东华大学学报(自然科学版),2009(03):319-322. |
[39] | 姜聚慧,王林浩,张圣麟,王慧.铋和镧共掺杂二氧化钛半导体的制备与光催化性能研究[J].水处理技术,2011(12):32-35. |
[40] | 萨嘎拉,张宇,张春燕,特日格乐,额日和木,照日格图.钕、氟掺杂二氧化钛光催化剂的制备及其光学性能的研究[J].内蒙古师范大学学报(自然科学汉文版),2012(01):69-73. |
[41] | 吴琛,李越湘,彭绍琴.S、RE共掺杂TiO2的制备及其可见光分解水制氢性能[J].材料导报,2011(20):66-69. |
[42] | 孙红旗,程友萍,金万勤,徐南平.镧、碳共掺杂TiO2的制备及其可见光催化性能[J].化工学报,2006(07):1570-1574. |
[43] | 吴俊明,王亚平,杨汉培,范以宁,许波连.Ce及N共掺杂改性TiO_2光催化性能及Ce组分的作用[J].无机化学学报,2010(02):203-210. |
[44] | Wei HY.;Wu YS.;Lun N.;Zhao F. .Preparation and photocatalysis of TiO2 nanoparticles co-doped with nitrogen and lanthanum[J].Journal of Materials Science,2004(4):1305-1308. |
[45] | Sakatani Y;Nunshuge J;Ando H et al.Photocatalytic decomposition of acetaldehyde under visible lght irradiation over La3+ and N co-doped TiO2[J].Chemistry Letters,2003,32(12):1156. |
[46] | 宋长友,刘大成,魏利滨,罗胜铁.铕、氮掺杂二氧化钛光催化剂的制备及性能研究[J].中山大学学报(自然科学版),2007(z1):35-36. |
[47] | Liu H;Liu G;Xie G et al.Gd3+,N-codoped trititanate nanotubes:Preparation,characterization and photocatalytic activity[J].Applied Surface Science,2011,257:3728. |
[48] | 赵斯琴,郭敏,张梅,王习东,长山.Y~(3+)和Eu~(3+)离子共掺杂TiO_2纳米材料的制备及其光催化性能[J].北京科技大学学报,2010(03):355-359. |
[49] | 郭莉,王丹军,李东升,付峰,蒲勇,闫宏涛.La-Ce-TiO2纳米光催化剂的溶胶-微波法合成、谱学表征及其活性研究[J].光谱学与光谱分析,2009(08):2185-2190. |
[50] | 王剑波,张景来,卢寿慈.金属共掺杂对TiO2光催化性能的影响[J].安徽理工大学学报(自然科学版),2004(03):61-64. |
[51] | 卢维奇,王德清,何肖群,赵黎明.钆及双稀土元素掺杂TiO2可见光催化降解罗丹明B的研究[J].中国稀土学报,2007(04):427-431. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%