欢迎登录材料期刊网

材料期刊网

高级检索

采用高浓度氯化锌乙醇溶液为反应体系,高效催化降解环氧树脂基炭纤维( CF/EP)复合材料并回收炭纤维。考察反应温度与氯化锌浓度对树脂基体降解的影响,探讨环氧树脂在氯化锌乙醇溶液中的催化降解机理。结果表明,复合材料中的树脂基体完全降解,炭纤维表面微观结构基本不变,且回收炭纤维的强度最高为原始炭纤维强度的97.1%,但表面含氧官能团有所减少。

Concentrated zinc chloride in ethanol was used to decompose the epoxy in carbon fiber/epoxy ( CF/EP) composites to recover carbon fibers. Factors affecting the degradation rate such as reaction temperature and zinc chloride concentration were inves-tigated. The properties of the products decomposed by epoxy and the recovered carbon fibers were characterized. Results indicated that the molecular weight of the decomposed epoxy decreased and its solubility in ethanol increased with the reaction time. A signifi-cant fraction of the C-O bonds in epoxy is broken down by the degradation. The strength of the recovered fibers is 97. 1% of the original ones and their microstructure was only slightly changed, but the amount of the oxygen-containing functional groups on the surface of the recovered fibers decreased.

参考文献

[1] 陈士杰.炭纤维复合材料的应用[J].精细化工原料及中间体,2012(06):20-21.
[2] 芦长椿.国际碳纤维产能持续增长及其市场现状[J].纺织导报,2009(03):44-48.
[3] Soraia Pimenta;Silvestre T. Pinho .Recycling carbon fibre reinforced polymers for structural applications: Technology review and market outlook[J].Waste Management,2011(2):378-392.
[4] SJ. Pickering .Recycling technologies for thermoset composite materials-current status[J].Composites, Part A. Applied science and manufacturing,2006(8):1206-1215.
[5] Eylem Asmatulu;Janet Twomey;Michael Overcash .Recycling of fiber-reinforced composites and direct structural composite recycling concept[J].Journal of Composite Materials,2014(5):593-608.
[6] Jutte R B;Graham W D.Recycling SMC[A].Composites Insitiute,1991
[7] Adrian M. Cunliffe;Nicola Jones;Paul T. Williams .Recycling of fibre-reinforced polymeric waste by pyrolysis: thermo-gravimetric and bench-scale investigations[J].Journal of analytical & applied pyrolysis,2003(2):315-338.
[8] S. J. Pickering;R. M. Kelly;J. R. Kennerley;C. D. Rudd;N. J. Fenwick .A fluidised-bed process for the recovery of glass fibres from scrap thermoset composites[J].Composites science and technology,2000(4):509-523.
[9] H. L. H. Yip;S. J. Pickering;C. D. Rudd .Characterisation of carbon fibres recycled from scrap composites using fluidised bed process[J].Plastics, Rubber and Composites,2002(6):278-282.
[10] Liu, Y.;Liu, J.;Jiang, Z.;Tang, T. .Chemical recycling of carbon fibre reinforced epoxy resin composites in subcritical water: Synergistic effect of phenol and KOH on the decomposition efficiency[J].Polymer Degradation and Stability,2012(3):214-220.
[11] Raul Pinero-Hernanz;Christopher Dodds;Jason Hyde .Chemical recycling of carbon fibre reinforced composites in nearcritical and supercritical water[J].Composites. Part A, Applied science and manufacturing,2008(3):454-461.
[12] Raul Pinero-Hernanz;Juan Garda-Serna;Christopher Dodds .Chemical recycling of carbon fibre composites using alcohols under subcritical and supercritical conditions[J].The Journal of Supercritical Fluids,2008(1):83-92.
[13] Hua Yan;Chunxiang Lu;Deqi Jing;Xianglin Hou .Chemical degradation of TGDDM/DDS epoxy resin in supercritical 1-propanol: Promotion effect of hydrogenation on thermolysis[J].Polymer Degradation and Stability,2013(12):2571-2582.
[14] Weirong Dang;Masatoshi Kubouchi;Hideki Sembokuya;Ken Tsuda .Chemical recycling of glass fiber reinforced epoxy resin cured with amine using nitric acid[J].Polymer: The International Journal for the Science and Technology of Polymers,2005(6):1905-1912.
[15] Juan Li;Ping-Lai Xu;Ying-Ke Zhu .A promising strategy for chemical recycling of carbon fiber/thermoset composites: self-accelerating decomposition in a mild oxidative system[J].Green chemistry,2012(12):3260-3263.
[16] Pinglai Xu;Juan Li;Jiangping Ding .Chemical recycling of carbon fibre/epoxy composites in a mixed solution of peroxide hydrogen and N,N-dimethylformamide[J].Composites science and technology,2013(Jun.):54-59.
[17] Nakagawa M;Shibata K;Kuriya H.Characterization of CFRP using recovered carbon fibers from waste CFRP[A].The Fiber Recycling,2009
[18] Deng, T.;Cui, X.;Qi, Y.;Wang, Y.;Hou, X.;Zhu, Y. .Conversion of carbohydrates into 5-hydroxymethylfurfural catalyzed by ZnCl _2 in water[J].Chemical communications,2012(44):5494-5496.
[19] 贺福.用拉曼光谱研究碳纤维的结构[J].高科技纤维与应用,2005(06):20-25.
[20] 冀克检;张银生 .炭纤维表面的XPS表征[J].合成纤维工业,1994,17(01):43-47.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%