Solution-based Chemical Strategies to Purposely Control the Microstructure of Functional Materials

材料科学技术（英文）, 2008, 24(4): 641-648.

^1, , ^2, , ^3, , ^4,

1.State Key Laboratory of Fine Chemicals, Department of Materials Science and Chemical Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116012, China

2.State Key Laboratory of Fine Chemicals, Department of Materials Science and Chemical Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116012, China

3.State Key Laboratory of Fine Chemicals, Department of Materials Science and Chemical Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116012, China

4.State Key Laboratory of Fine Chemicals, Department of Materials Science and Chemical Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116012, China

基金项目: 国家自然科学基金(20471012) 教育部高等学校博士学科点专项科研基金(20040141004) 教育部全国优秀博士学位论文作者专项基金(200322) the program for the New Century Excellent Talents in University(NCET-05-0278)

Solution-based Chemical Strategies to Purposely Control the Microstructure of Functional Materials

Fei LIU ^1, , Congting SUN ^2, , Chenglin YAN ^3, , Dongfeng XUE ^4,

1.State Key Laboratory of Fine Chemicals, Department of Materials Science and Chemical Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116012, China

2.State Key Laboratory of Fine Chemicals, Department of Materials Science and Chemical Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116012, China

3.State Key Laboratory of Fine Chemicals, Department of Materials Science and Chemical Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116012, China

4.State Key Laboratory of Fine Chemicals, Department of Materials Science and Chemical Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116012, China

Keywords： Functional materials

Micro/nanostructured crystals with controlled architectures are desirable for many applications in optics, electronics, biology, medicine, and energy conversions. Low-temperature, aqueous chemical routes have been widely investigated for the synthesis of particles, and arrays of oriented nanorods and nanotubes. In this paper, based on the ideal crystal shapes predicted by the chemical bonding theory, we have developed some potential chemical strategies to tune the microstructure of functional materials, ZnS and Nb2O5 nanotube arrays, MgO wiskers and nestlike spheres, and cubic phase Cu2O microcrystals were synthesized here to elucidate these strategies. We describe their controlled crystallization processes and illustrate the detailed key factors controlling their growth by examining various reaction parameters. Current results demonstrate that our designed chemical strategies for tuning microstructure of functional materials are applicable to several technologically important materials, and therefore may be used as a versatile and effective route to the controllable synthesis of other inorganic functional materials.

参考文献

[1]	J.Xiang;W.Lu;Y.J.Hu;Y.Wu H.Yan C.M.Lieber .[J].Nature,2006,441(7092):489.
[2]	M.Bruchez;M.Mororme;P.Gin;S.Weiss A.P.Alivisatos .[J].Science,1998,281(5385):2013.
[3]	V.Wagner;A.Dullaart;A.K.Bock;A.Zweck .[J].Nature Biotechnology,2006,24(10):1211.
[4]	X.D.Wang;J.H.Song;J.Liu;Z.L.Wang .[J].Science,2007,316(5821):102.
[5]	H.Lee;B.P.Lee;P.B.Messersmith .[J].Nature,2007,448(7151):338.
[6]	Y.Yin;A.P.Alivisatos .[J].NATURE,2005,437(7059):664.
[7]	Z.W.Pan;Z.R.Dai;Z.L.Wang .[J].Science,2001,291(5510):1947.
[8]	Y.G.Sun;Y.N.Xia .[J].Science,2002,298(5601):2176.
[9]	R.D.Robinson;B.Sadtler;D.O.Demchenko;C.K.Erdonmez L.W.Wang A.P.Alivisatos .[J].Science,2007,317(5836):355.
[10]	P.D.Yang;T.Deng;D.Y.Zhao;P.Y.Feng D.Pine B.F.Chmelka G.M.Whitesides G.D.Stueky .[J].Science,1998,282(5397):2244.
[11]	D.J.Milliron;S.M.Hughes;Y.Cui;L.Manna J.B.Li L.W.Wang A.P.Alivisatos .[J].Nature,2004,430(6996):190.
[12]	L.W.Yin;Y.Bando .[J].Nature Materials,2005,4(12):883.
[13]	D.Xu;D.Xue .[J].Journal of Crystal Growth,2006,286(01):108.
[14]	X.Yan;D.Xu;D.Xue .[J].Acta Materials,2007,55(17):5747.
[15]	Y.Zhu;Y.Bando;D.Xue;D.Golberg .[J].Advanced Materials,2004,16(9-10):831.
[16]	Y.Zhu;Y.Bando;D.Xue;D.Golberg .[J].Journal of the American Chemical Society,2003,125(52):16196.
[17]	X.S.Fang;Y.Bando;G.Z.Shen;C.H.Ye U.K.Gautam P.M.F.J.Costa C.Y.Zhi C.C.Tang D.Golberg .[J].Advanced Materials,2007,19(18):2593.
[18]	P.T.Snee;R.C.Somers;G.Nalr;J.P.Zimmer M.G.Bawendi D.G.Nocera .[J].Journal of the American Chemical Society,2006,128(41):13320.
[19]	X.Xu;B.Z.Tian;J.L.Kong;S.Zhang B.H.Liu D.Y.Zhao .[J].Advanced Materials,2003,15(22):1932.
[20]	A.Fielicke;G.Meijer;G.V.Helden .[J].Journal of the American Chemical Society,2003,125(12):3659.
[21]	C G Granqvist.Handbook of Inorganic Electrochromic Materials[M].Amsterdam:Elsevier,1995
[22]	C.Trionfetti;A.Airal;J.G.E.H.Gardeniers;L.Lefferts K.Seshan .[J].Journal of Physical Chemistry C,2008,112(11):4267.
[23]	X.Jiang;R.Wang;R.M.Shelby;R.M.Macfarlane S.R.Bank J.S.Harris S.S.Parkin .[J].Physical Review Letters,2005,94(05):056601.
[24]	C.Yan;D.Xue .[J].Journal of Physical Chemistry B,2005,109(25):12358.
[25]	H.Oguchi;H.Kanai;K.Utani;Y.Matsumura S.Imamura .[J].Applied Catalysis A:General,2005,293:64.
[26]	S. S. Jeong;A. Mittiga;E. Salza;A. Masci;S. Passerini .Electrodeposited ZnO/Cu{sub}2O heterojunction solar cells[J].Electrochimica Acta,2008(5):2226-2231.
[27]	A.Chen;S.Haddad;Y.C.Wu;T.N.Fang S.Kaza Z.Lan .[J].Applied Physics Letters,2008,92(01):013503.
[28]	J.Xu;D.Xue .[J].Acta Materials,2007,55(07):2397.
[29]	C.Yan;D.Xue .[J].Journal of Physical Chemistry B,2006,110(51):25850.
[30]	C.Yan;D.Xue .[J].Advanced Materials,2008,20(05):1055.
[31]	M.Mo;J.Yu;L.Zhang;S.Li .[J].Advanced Materials,2007,17(06):756.
[32]	J.Goldberger;R.R.He;Y.F.Zhang;S.W.Lee Y.H.Qan H.J.Choi P.D.Yang .[J].Nature,2003,422(6932):599.
[33]	R. TENNE .Inorganic nanotubes and fullerene-like nanoparticles[J].Nature nanotechnology,2006(2):103-111.
[34]	Y.D.Yin;R.M.Rioux;C.K.Erdonmez;S.Hughes G.A.Somorjai A.P.Alivisatos .[J].Science,2004,304(5671):711.
[35]	E.O.KirkendaU .[J].Transactions AIME,1942,147:104.
[36]	T.Sun;J.Ying .[J].Nature,1997,389(6652):704.
[37]	H.Saitoh;Y.Okada;S.Ohshio .[J].Journal of Materials Science,2002,37(21):4597.
[38]	G.Kordas .[J].Journal of Materials Chemistry,2000,10(05):1157.
[39]	E.Ben-Jacob;P.Garik .[J].NATURE,1990,343(6258):523.
[40]	Z.R.Tian;J.A.Voigt;J.Liu;B.McKenzie M.J.McDermott M.A.Rodriguez H.Konishi H.F.Xu .[J].Nature Materials,2003,2(12):821.
[41]	M.J.Siegfried;K.S.Choi .[J].Journal of the American Chemical Society,2006,128(32):10356.
[42]	C.H.Lu;L.M.Qi;J.H.Yang;X.Y.Wang D.Y.Zhang J.L.Xie J.M.Ma .[J].Advanced Materials,2005,17(21):2562.

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Solution-based Chemical Strategies to Purposely Control the Microstructure of Functional Materials

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