通过激光熔覆不同比例TA15与Cr_3C_2的混和粉末,在TA15钛合金表面制备出原位钛基复合材料涂层,分析了涂层的组织、相组成、硬度及界面结合情况.研究表明,激光熔覆过程中,Cr3 C2颗粒溶解并与Ti发生反应,在涂层中形成弥散分布的TiC;随原始粉末中Cr_3C_2添加量的增加,涂层中TiC含量及涂层硬度增加,TiC有等轴颗粒状及枝晶两种形貌;涂层组织致密,与基体呈完全冶金结合,涂层内TiC与钛合金基体界面结合良好,经弯曲及热震试验后,涂层未出现剥落现象,表明涂层与基体具有很好的相容性.
In-situ titanium matrix composite coatings were prepared on TA15 titanium alloy surface by laser cladding pre-mixed TA15 and Cr_3C_2 powders with different ratio.The microstructure, hardness as well as the interface bonding of the coating were investigated.The results show that during cladding original Cr_3C_2 particulates dissolve, react with Ti and form dispersed TiC in the clad coatings.With increase the ratio of Cr_3C_2 in the pre-mixed powders, the amount of TiC within the coatings and the coatings hardness increase.The formed TiC appears as particulate and dendrite.The coating is dense and metallurgically bonded to the substrate.The interface between the in-situ formed TiC and the titanium alloy matrix is perfect.No de-bonding is obsewed for the composite coatings after bending and thermal shock tests, indicating a good compatibility of the composite coatings with the titanium alloy substrate.
参考文献
[1] | Yan W;Wang X X .Surface hardening of titanium by thermal oxidation[J].Journal of Materials Science,2004,39(16-17):5583-55585. |
[2] | H. Zhou;F. Li;B. He;J. Wang;B. Sun .Effect of Plasma Spraying Process on Microstructure and Microhardness of Titanium Alloy Substrate[J].Journal of Thermal Spray Technology,2008(2):284-288. |
[3] | Aravind Vadiraj;M. Kamaraj;R. Gnanamoorthy .Fretting wear studies on uncoated, plasma nitrided and laser nitrided biomedical titanium alloys[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2007(1/2):446-453. |
[4] | Steffen Nowotny;Siegfried Scharek;Eckhard Beyer;Karl-Hermann Richter .Laser Beam Build-Up Welding: Precision in Repair, Surface Cladding, and Direct 3D Metal Deposition[J].Journal of Thermal Spray Technology,2007(3):344-348. |
[5] | 武万良,李学伟.钛合金激光熔覆技术研究进展[J].稀有金属材料与工程,2006(06):850-854. |
[6] | Mridhn S;Baker T N .Metal matrix composite layer formation with 3 μm SiCp powder on IMI318 titanium alloy surfaces through laser treatment[J].Journal of Materials Processing Technology,1997,63(1-3):432-437. |
[7] | Sun R L;Yang D Z;Guo L X et al.Laser cladding of Ti-6Al-4V alloy with TiC and TiC+NiCrBSi powders[J].Surface and Coatings Technolagy,2001,135(2 -3):307-3312. |
[8] | Jian LN;Wang HM .Microstructure and wear behaviours of laser-clad Cr13Ni5Si2-based metal-silicide coatings on a titanium alloy[J].Surface & Coatings Technology,2005(2/3):305-310. |
[9] | Y. Wang;H.M. Wang .Wear resistance of laser clad Ti_2Ni_3Si reinforced intermetallic composite coatings on titanium alloy[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2004(1/4):81-86. |
[10] | Vreeling J A;Ocelik V;De Hosson J Th M .Ti-6AI-4V strengthened by laser melt injection of WCp particles[J].Acta Materialia,2002,50(19):4913-44924. |
[11] | Man H C;Zhang S;Cheng F T et al.Microstmcture and formation mechanism of in-situ synthesized TiC/Ti surface MMC on Ti-6AI.4V by laser cladding[J].Scripta Materialia,2001,44(12):2801-22807. |
[12] | Kooi B J;Pei Y T;De Hosson J Th M .The evolution of mierostmcture in a laser elad TiB-Ti composite coating[J].Acta Materialia,2003,51(03):831-846. |
[13] | Lifang Cai,Yongzhong Zhang,Likai Shi,Haoqiang Yang,Mingzhe Xi.Research on development of in situ titanium matrix composites and in situ reaction thermodynamics of the reaction systems[J].北京科技大学学报(英文版),2006(06):551-557. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%