利用DSC热分析法研究了Zr基及78Fe-9Si-13B非晶合金的比热容随温度的变化规律,发现Zr基非晶的比热容温度曲线与二级相变热容变化的规律十分相似,因此从热力学上证明了玻璃态与过冷液态之间的转变属于二级相变.78Fe-9Si-13B非晶合金的比热容温度曲线上仅存在一个λ形峰值,这显示居里温度与玻璃转变温度几乎相等,结构有序性与磁矩有序性的变化发生了重叠.
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