以乙醇、甲醇及液化石油气为碳源,低碳钢及含Ni合金钢等为基板,采用火焰法成功地制备出了一维碳纳米材料,包括碳纳米管(CNTs)和一种新的"实心"碳纳米纤维(CNFs).利用场发射枪高分辨扫描电镜(SEM)、透射电镜(TEM)和激光Raman光谱对碳纳米材料的结构进行了表征.发现基板材料决定燃烧生成物的性质,含Fe元素及其化合物的基板材料倾向于合成"实心"碳纳米纤维,而含Ni元素及其化合物的基板材料倾向于合成"空心"的碳纳米管,认为这是由于碳与Fe的亲和力比Ni大而造成的.不同碳源对一维碳纳米材料的形态也有影响,这与它们的含碳量和燃烧热等不同有关.
参考文献
[1] | Iijima S .Helical Microtubules of Griphitic Carbon[J].Nature,1991,354:56-58. |
[2] | 刘畅,丛洪涛,成会明.氢等离子电弧法半连续制备单壁纳米碳管[J].新型炭材料,2000(02):1-5. |
[3] | Guo T.;Thess A.;Colbert DT.;Smalley RE.;Nikolaev P. .CATALYTIC GROWTH OF SINGLE-WALLED NANOTUBES BY LASER VAPORIZATION[J].Chemical Physics Letters,1995(1/2):49-54. |
[4] | Laplaze D.;Maser WK.;Flamant G.;Guillard T.;Loiseau A.;Bernier P. .Carbon nanotubes: The solar approach[J].Carbon: An International Journal Sponsored by the American Carbon Society,1998(5/6):685-688. |
[5] | 卢怡,朱珍平,刘振宇.催化剂对爆炸法合成碳纳米管的影响[J].新型炭材料,2004(01):1-6. |
[6] | Journet C;Maser W K;Bernier P et al.Large-scale production of single-walled carbon nanotubes by the electric-arc technique[J].Nature,1997,388:756-758. |
[7] | 邱介山,韩红梅,周颖,胡德生,曾适之,P J F Harris.由二种烟煤制备碳纳米管的探索性研究[J].新型炭材料,2001(04):1-6. |
[8] | 曹宗良,王健农,丁冬雁,戴杰华,余帆.化学气相沉积法快速生长定向纳米碳管[J].新型炭材料,2003(01):48-52. |
[9] | 李颖,李轩科,刘朗.不同原料气催化热解法制备碳纳米管的研究[J].新型炭材料,2004(04):298-302. |
[10] | Yacaman M J;Yoshida M M;Rendon L .Catalytic growth of cabon microtubules with fullerene structure[J].Applied Physics Letters,1993,62:202-204. |
[11] | Marangoni R.;Feurer R.;Kihn Y.;Kalck P.;Vahlas C.;Serp P. .Carbon nanotubes produced by substrate free metalorganic chemical vapor deposition of iron catalysts and ethylene[J].Carbon: An International Journal Sponsored by the American Carbon Society,2001(3):443-449. |
[12] | Benito AM.;Munoz E.;Martinez MT.;Maniette Y. .Carbon nanotubes production by catalytic pyrolysis of benzene[J].Carbon: An International Journal Sponsored by the American Carbon Society,1998(5/6):681-683. |
[13] | Kong Jing;Cassell A M;Dai Hongjie et al.Chemiacal vapor deposition of methane for single-walled carbon naotubes[J].Chemical Physics Letters,1998,292:567-574. |
[14] | R. Andrews;D. Jacques;A. M. Rao;F. Derbyshire;D. Qian;X. Fan;E. C. Dickey;J. Chen .Continuous production of aligned carbon nanotubes: a step closer to commercial realization[J].Chemical Physics Letters,1999(5/6):467-474. |
[15] | Dal HJ.;Nikolaev P.;Thess A.;Colbert DT.;Smalley RE.;Rinzler AG. .SINGLE-WALL NANOTUBES PRODUCED BY METAL-CATALYZED DISPROPORTIONATION OF CARBON MONOXIDE[J].Chemical Physics Letters,1996(3-4):471-475. |
[16] | 潘春旭,Liming Yuan,Kozo Saito.扩散火焰合成碳纳米管研究[J].新型炭材料,2001(03):24-27. |
[17] | 王茂章,李峰,杨全红,成会明.由不同碳源合成及制备纳米碳管的进展[J].新型炭材料,2003(04):250-264. |
[18] | Randall L. Vander Wal .Fe-Catalyzed Single-Walled Carbon Nanotube Synthesis within a Flame Environment[J].Combustion and Flame,2002(1/2):37-47. |
[19] | Pan Chunxu;Bao Qiaoliang .Well-Aligned carbon nanotubes from ethanol flame[J].Journal of Materials Science Letters,2002,21:1927-1929. |
[20] | 周家骅;李昌厚;吴德荣.节能燃烧技术[M].北京:机械工业出版社,1989:163-165. |
[21] | 曲作家;张振铎;孙思诚.燃烧理论基础[M].北京:国防工业出版社,1989:151-162. |
[22] | 李颖,李轩科,刘朗.裂解温度对碳纳米管制备的影响[J].新型炭材料,2002(04):53-56,61. |
[23] | Vander Wal R l;Hall L J .Flame synthesis of Fe catalyzed single-walled carbon nanotubes and Ni catalyzed nanofibers:growth mechanisms and consequences[J].Chemical Physics Letters,2001,349:178-184. |
[24] | Liu Yueli;Pan Chunxu;Wang Jianbo .Raman spectra of carbon nanotubes and nanofibers prepared by ethanol flames[J].Journal of Materials Science,2004,39:1091-1094. |
[25] | 姚振华,朱长纯,程敏,刘君华.碳纳米管高温热稳定性与结构的关系[J].液晶与显示,2002(01):49-54. |
[26] | Randall L. Vander Wal;Thomas M. Ticich;Valerie E. Curtis .Substrate-support interactions in metal-catalyzed carbon nanofiber growth[J].Carbon: An International Journal Sponsored by the American Carbon Society,2001(15):2277-2289. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%