欢迎登录材料期刊网

材料期刊网

高级检索

在供作基膜的聚醚砜微滤膜表面涂覆一交联荷负电聚合物薄层,得到表面荷负电的聚醚砜微滤复合膜,对该膜形态、接触角、表面流动电位和抗活性污泥污染等性质进行了测评.结果表明,该表面荷负电的聚醚砜微滤复合膜较之其基膜,膜的亲水性、表面荷负电性和抗活性污泥污染性质均有明显的改善和提高.孔径约0.1 μm的表面荷负电的聚醚砜复合微滤膜和基膜过滤活性污泥浓度为6 000~10 000 mg/L的污水,滤饼层阻力Rc分别为0.19×1011m-1和3.13×1011 m-1,膜孔阻力Rp分别为1.36×1011m-1和4.24×1011m-1.该荷负电的聚醚砜复合材料可作为应用于膜生物反应器的抗污染膜材料使用.

参考文献

[1] Osada Y;Nakagawa T.Membrane science and Technology[M].New York,USA:Marcel Dekker,Inc,1992:289.
[2] Zeman L Z;Zydney A L.Microfiltration and ultrafiltration[M].New York,USA:Marcel Dekker,Inc,1996
[3] Yamagishi H.;Belfort G.;Crivello JV. .DEVELOPMENT OF A NOVEL PHOTOCHEMICAL TECHNIQUE FOR MODIFYING POLY(ARYLSULFONE) ULTRAFILTRATION MEMBRANES[J].Journal of Membrane Science,1995(3):237-247.
[4] Belfer S;Fainchtain R;Purinson Y et al.Surface characterization by FTIR-ATR spectroscopy of polyethersulfone membranes-unmodified,modified and protein fouled[J].Journal of Membrane Science,2000,172:113-124.
[5] 吴玉亭,施亚钧.辐照接枝丙烯酸改性聚砜超滤膜[J].水处理技术,1995(01):21.
[6] Ulbricht M;Belfort G .Surface modification of ultrafiltration membranes by low temperature plasma(H)Graft polymerization onto polyacrylonitrile and polysulfone[J].Journal of Membrane Science,1996,111:193-215.
[7] Steen M;Hymas L;Havey E D et al.Low temperature plasma treatment of symmetric polysulfone membranes for permanent hydrophilic surface modification[J].Journal of Membrane Science,2001,188:97-114.
[8] 邢丹敏;武冠英;胡家俊 .改性聚氯乙烯超滤膜的研究(Ⅰ)等离子体改性膜结构和性能的研究[J].膜科学与技术,1996,16(01):49-55.
[9] Jakabhazy S Z .Blended polymeric matrix membrane and process of making and using same[P].US Patent:4377481,1983-03-22.
[10] 凌爱莲;焦庆影;鲍世耀 .聚丙烯睛共混超滤膜的研究[J].膜科学与技术,1994,14(02):8-16.
[11] 俞三传,高从堦.多元合金超滤膜研制[J].膜科学与技术,2001(02):10-13.
[12] Bowen WR;Cheng SY;Doneva TA;Oatley DL .Manufacture and characterisation of polyetherimide/sulfonated poly(ether ether ketone) blend membranes[J].Journal of Membrane Science,2005(1/2):1-10.
[13] Millesime L;Amiel C;Chaufer B .Ultrafiltration of lysozyme and bovine serum albumin with polysulfone membranes modified with quaternized polyvinylimidazole[J].Journal of Membrane Science,1994,89:223-234.
[14] Kim I.C.;Chol J.G.;Tak T.M. .Sulfonated Polyethersulfone by Heterogeneous Method and Its Membrane Performances[J].Journal of Applied Polymer Science,1999(8):2046-2055.
[15] Brink L E S;Elbers S J G;Robbertsen T et al.The anti-fouling action of polymers preadsorbed on ultrafiltration and microfiltration membranes[J].Journal of Membrane Science,1993,76:281-291.
[16] Tae-Hyun Bae;In-Chul Kim;Tae-Moon Tak .Preparation and characterization of fouling-resistant TiO_2 self-assembled nanocomposite membranes[J].Journal of Membrane Science,2006(1/2):1-5.
[17] Cao XC;Ma J;Shi XH;Ren ZJ .Effect of TiO2 nanoparticle size on the performance of PVDF membrane[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2006(4):2003-2010.
[18] 王倩,王铎,娄红瑞,马玉新,高从堦.新型聚醚砜超滤膜的制备与表征[J].膜科学与技术,2008(06):9-13.
[19] Herbert H.P. Fang;Xinlong Shi .Pore fouling of microfiltration membranes by activated sludge[J].Journal of Membrane Science,2005(1/2):161-166.
[20] U S Millipore Corporation.Stirred Ultrafiltration Cells Models 8200 User Guide[M].
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%